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PtCl4(SCl2)2 crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two platinum(iv) chloride molecules and four sulfur dichloride molecules.
PtCl2(SCl2)2 is Cyanogen Chloride-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one platinum(ii) chloride molecule and two sulfur dichloride molecules.