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6 records
All sourcesNASA NTRSDOE OSTI
DOE OSTI2020

Materials Data on PtCl2 by Materials Project

PtCl2 is Tungsten structured and crystallizes in the trigonal R-3m space group. The structure is zero-dimensional and consists of three PtCl2 clusters. Pt2+ is bonded in a rectangular see-saw-like geometry to four Cl1- atoms. All Pt–Cl bond lengths are 2.33 Å. There are two inequivalent Cl1- sites. In the first Cl1- site, Cl1- is bonded in an L-shaped geometry to two equivalent Pt2+ atoms. In the second Cl1- site, Cl1- is bonded in an L-shaped geometry to two equivalent Pt2+ atoms.

36 MATERIALS SCIENCE↗
DOE OSTI2020

Materials Data on PtCl2 by Materials Project

PtCl2 crystallizes in the orthorhombic Pnnm space group. The structure is one-dimensional and consists of two PtCl2 ribbons oriented in the (1, 0, 0) direction. Pt2+ is bonded in a square co-planar geometry to four equivalent Cl1- atoms. All Pt–Cl bond lengths are 2.32 Å. Cl1- is bonded in an L-shaped geometry to two equivalent Pt2+ atoms.

36 MATERIALS SCIENCE↗
DOE OSTI2020

Materials Data on PtCl4 by Materials Project

PtCl4 is Silicon tetrafluoride-like structured and crystallizes in the trigonal R-3 space group. The structure is zero-dimensional and consists of twenty-four platinum(iv) chloride molecules. Pt4+ is bonded in a tetrahedral geometry to four Cl1- atoms. All Pt–Cl bond lengths are 2.27 Å. There are two inequivalent Cl1- sites. In the first Cl1- site, Cl1- is bonded in a single-bond geometry to one Pt4+ atom. In the second Cl1- site, Cl1- is bonded in a single-bond geometry to one Pt4+ atom.

36 MATERIALS SCIENCE↗
DOE OSTI2020

Materials Data on PtCl2 by Materials Project

PtCl2 crystallizes in the triclinic P-1 space group. The structure is one-dimensional and consists of one PtCl2 ribbon oriented in the (1, 0, 0) direction. Pt2+ is bonded in a rectangular see-saw-like geometry to four Cl1- atoms. There are a spread of Pt–Cl bond distances ranging from 2.27–2.52 Å. There are two inequivalent Cl1- sites. In the first Cl1- site, Cl1- is bonded in a single-bond geometry to one Pt2+ atom. In the second Cl1- site, Cl1- is bonded in a distorted T-shaped geometry to three equivalent Pt2+ atoms.

36 MATERIALS SCIENCE↗
DOE OSTI2020

Materials Data on PtCl2 by Materials Project

PtCl2 crystallizes in the monoclinic C2/m space group. The structure is one-dimensional and consists of four PtCl2 ribbons oriented in the (0, 1, 0) direction. Pt2+ is bonded in a square co-planar geometry to four Cl1- atoms. All Pt–Cl bond lengths are 2.32 Å. There are two inequivalent Cl1- sites. In the first Cl1- site, Cl1- is bonded in an L-shaped geometry to two equivalent Pt2+ atoms. In the second Cl1- site, Cl1- is bonded in an L-shaped geometry to two equivalent Pt2+ atoms.

36 MATERIALS SCIENCE↗
DOE OSTI2020

Materials Data on Pt3Cl by Materials Project

Pt3Cl is alpha bismuth trifluoride structured and crystallizes in the tetragonal I4/mmm space group. The structure is three-dimensional. there are two inequivalent Pt+0.33+ sites. In the first Pt+0.33+ site, Pt+0.33+ is bonded to four Cl1- atoms to form PtCl4 tetrahedra that share corners with twelve equivalent PtCl6 octahedra, corners with sixteen equivalent PtCl4 tetrahedra, edges with six equivalent PtCl4 tetrahedra, and faces with four equivalent PtCl6 octahedra. The corner-sharing octahedral tilt angles are 55°. All Pt–Cl bond lengths are 2.77 Å. In the second Pt+0.33+ site, Pt+0.33+ is bonded to six Cl1- atoms to form distorted PtCl6 octahedra that share corners with six equivalent PtCl6 octahedra, corners with twenty-four equivalent PtCl4 tetrahedra, edges with twelve equivalent PtCl6 octahedra, and faces with eight equivalent PtCl4 tetrahedra. The corner-sharing octahedral tilt angles are 0°. There are four shorter (3.19 Å) and two longer (3.21 Å) Pt–Cl bond lengths. There are two inequivalent Cl1- sites. In the first Cl1- site, Cl1- is bonded in a body-centered cubic geometry to fourteen Pt+0.33+ atoms. In the second Cl1- site, Cl1- is bonded in a body-centered cubic geometry to fourteen Pt+0.33+ atoms.

36 MATERIALS SCIENCE↗