Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “Cl-O-Re”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

11 records
All sourcesNASA NTRSDOE OSTI
DOE OSTI2020

Materials Data on ReCl4O by Materials Project

ReOCl4 crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of eight ReOCl4 clusters. Re6+ is bonded in a 5-coordinate geometry to one O2- and four Cl1- atoms. The Re–O bond length is 1.69 Å. There are two shorter (2.28 Å) and two longer (2.29 Å) Re–Cl bond lengths. O2- is bonded in a single-bond geometry to one Re6+ atom. There are four inequivalent Cl1- sites. In the first Cl1- site, Cl1- is bonded in a single-bond geometry to one Re6+ atom. In the second Cl1- site, Cl1- is bonded in a single-bond geometry to one Re6+ atom. In the third Cl1- site, Cl1- is bonded in a single-bond geometry to one Re6+ atom. In the fourth Cl1- site, Cl1- is bonded in a single-bond geometry to one Re6+ atom.

36 MATERIALS SCIENCE↗
DOE OSTI2020

Materials Data on Re4Cl8O9 by Materials Project

Re2(OCl2)3(ReO3Cl)2 crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one Re2(OCl2)3 cluster and two ReO3Cl clusters. In the Re2(OCl2)3 cluster, Re+6.50+ is bonded in a 2-coordinate geometry to two O2- and three Cl1- atoms. There is one shorter (1.69 Å) and one longer (1.87 Å) Re–O bond length. There are two shorter (2.31 Å) and one longer (2.32 Å) Re–Cl bond lengths. There are two inequivalent O2- sites. In the first O2- site, O2- is bonded in a linear geometry to two equivalent Re+6.50+ atoms. In the second O2- site, O2- is bonded in a single-bond geometry to one Re+6.50+ atom. There are three inequivalent Cl1- sites. In the first Cl1- site, Cl1- is bonded in a single-bond geometry to one Re+6.50+ atom. In the second Cl1- site, Cl1- is bonded in a single-bond geometry to one Re+6.50+ atom. In the third Cl1- site, Cl1- is bonded in a single-bond geometry to one Re+6.50+ atom. In each ReO3Cl cluster, Re+6.50+ is bonded in a tetrahedral geometry to three O2- and one Cl1- atom. There is two shorter (1.72 Å) and one longer (1.74 Å) Re–O bond length. The Re–Cl bond length is 2.22 Å. There are three inequivalent O2- sites. In the first O2- site, O2- is bonded in a single-bond geometry to one Re+6.50+ atom. In the second O2- site, O2- is bonded in a single-bond geometry to one Re+6.50+ atom. In the third O2- site, O2- is bonded in a single-bond geometry to one Re+6.50+ atom. Cl1- is bonded in a single-bond geometry to one Re+6.50+ atom.

36 MATERIALS SCIENCE↗
DOE OSTI2020

Materials Data on ReCl3O2 by Materials Project

ReO2Cl3 is Tungsten structured and crystallizes in the orthorhombic Pnnm space group. The structure is zero-dimensional and consists of two ReO2Cl3 clusters. Re7+ is bonded in a 2-coordinate geometry to two equivalent O2- and four Cl1- atoms. Both Re–O bond lengths are 1.71 Å. There are two shorter (2.29 Å) and two longer (2.62 Å) Re–Cl bond lengths. O2- is bonded in a single-bond geometry to one Re7+ atom. There are three inequivalent Cl1- sites. In the first Cl1- site, Cl1- is bonded in a single-bond geometry to one Re7+ atom. In the second Cl1- site, Cl1- is bonded in a single-bond geometry to one Re7+ atom. In the third Cl1- site, Cl1- is bonded in a water-like geometry to two equivalent Re7+ atoms.

36 MATERIALS SCIENCE↗
DOE OSTI2020

Materials Data on Re2Cl5O4 by Materials Project

Re2O4Cl5 crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two Re2O4Cl5 clusters. there are two inequivalent Re+6.50+ sites. In the first Re+6.50+ site, Re+6.50+ is bonded in a tetrahedral geometry to three O2- and one Cl1- atom. There is two shorter (1.72 Å) and one longer (1.75 Å) Re–O bond length. The Re–Cl bond length is 2.22 Å. In the second Re+6.50+ site, Re+6.50+ is bonded in a 1-coordinate geometry to two O2- and four Cl1- atoms. There are one shorter (1.69 Å) and one longer (2.57 Å) Re–O bond lengths. There are two shorter (2.29 Å) and two longer (2.30 Å) Re–Cl bond lengths. There are four inequivalent O2- sites. In the first O2- site, O2- is bonded in a single-bond geometry to one Re+6.50+ atom. In the second O2- site, O2- is bonded in a distorted single-bond geometry to two Re+6.50+ atoms. In the third O2- site, O2- is bonded in a single-bond geometry to one Re+6.50+ atom. In the fourth O2- site, O2- is bonded in a single-bond geometry to one Re+6.50+ atom. There are five inequivalent Cl1- sites. In the first Cl1- site, Cl1- is bonded in a single-bond geometry to one Re+6.50+ atom. In the second Cl1- site, Cl1- is bonded in a single-bond geometry to one Re+6.50+ atom. In the third Cl1- site, Cl1- is bonded in a single-bond geometry to one Re+6.50+ atom. In the fourth Cl1- site, Cl1- is bonded in a single-bond geometry to one Re+6.50+ atom. In the fifth Cl1- site, Cl1- is bonded in a single-bond geometry to one Re+6.50+ atom.

36 MATERIALS SCIENCE↗
DOE OSTI2020

Materials Data on Re2Cl7O3 by Materials Project

Re2O3Cl7 crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two Re2O3Cl7 clusters. there are two inequivalent Re+6.50+ sites. In the first Re+6.50+ site, Re+6.50+ is bonded in a 1-coordinate geometry to two O2- and four Cl1- atoms. There are one shorter (1.69 Å) and one longer (2.46 Å) Re–O bond lengths. There are three shorter (2.30 Å) and one longer (2.31 Å) Re–Cl bond lengths. In the second Re+6.50+ site, Re+6.50+ is bonded in a 2-coordinate geometry to two O2- and four Cl1- atoms. There is one shorter (1.71 Å) and one longer (1.75 Å) Re–O bond length. There are a spread of Re–Cl bond distances ranging from 2.28–2.72 Å. There are three inequivalent O2- sites. In the first O2- site, O2- is bonded in a distorted single-bond geometry to two Re+6.50+ atoms. In the second O2- site, O2- is bonded in a single-bond geometry to one Re+6.50+ atom. In the third O2- site, O2- is bonded in a single-bond geometry to one Re+6.50+ atom. There are seven inequivalent Cl1- sites. In the first Cl1- site, Cl1- is bonded in a distorted water-like geometry to two equivalent Re+6.50+ atoms. In the second Cl1- site, Cl1- is bonded in a single-bond geometry to one Re+6.50+ atom. In the third Cl1- site, Cl1- is bonded in a single-bond geometry to one Re+6.50+ atom. In the fourth Cl1- site, Cl1- is bonded in a single-bond geometry to one Re+6.50+ atom. In the fifth Cl1- site, Cl1- is bonded in a single-bond geometry to one Re+6.50+ atom. In the sixth Cl1- site, Cl1- is bonded in a single-bond geometry to one Re+6.50+ atom. In the seventh Cl1- site, Cl1- is bonded in a single-bond geometry to one Re+6.50+ atom.

36 MATERIALS SCIENCE↗
DOE OSTI2020

Materials Data on ReClO3 by Materials Project

ReO3Cl is Iron carbide-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four ReO3Cl clusters. Re7+ is bonded in a tetrahedral geometry to three O2- and one Cl1- atom. There is one shorter (1.72 Å) and two longer (1.73 Å) Re–O bond length. The Re–Cl bond length is 2.23 Å. There are three inequivalent O2- sites. In the first O2- site, O2- is bonded in a single-bond geometry to one Re7+ atom. In the second O2- site, O2- is bonded in a single-bond geometry to one Re7+ atom. In the third O2- site, O2- is bonded in a single-bond geometry to one Re7+ atom. Cl1- is bonded in a single-bond geometry to one Re7+ atom.

36 MATERIALS SCIENCE↗
DOE OSTI2020

Materials Data on Re(Cl2O)2 by Materials Project

Re(OCl2)2 crystallizes in the orthorhombic Pna2_1 space group. The structure is zero-dimensional and consists of four Re(OCl2)2 clusters. Re is bonded in a 6-coordinate geometry to two O and four Cl atoms. There is one shorter (1.74 Å) and one longer (1.83 Å) Re–O bond length. There are a spread of Re–Cl bond distances ranging from 2.24–2.54 Å. There are two inequivalent O sites. In the first O site, O is bonded in a single-bond geometry to one Re and one Cl atom. The O–Cl bond length is 2.33 Å. In the second O site, O is bonded in a single-bond geometry to one Re atom. There are four inequivalent Cl sites. In the first Cl site, Cl is bonded in a 1-coordinate geometry to one Re and one O atom. In the second Cl site, Cl is bonded in a single-bond geometry to one Re atom. In the third Cl site, Cl is bonded in a single-bond geometry to one Re atom. In the fourth Cl site, Cl is bonded in a single-bond geometry to one Re atom.

36 MATERIALS SCIENCE↗
DOE OSTI2020

Materials Data on Re3(Cl5O4)2 by Materials Project

Re3(O2Cl5)2(O2)2 crystallizes in the tetragonal P4_12_12 space group. The structure is zero-dimensional and consists of eight hydrogen peroxide molecules and four Re3(O2Cl5)2 clusters. In each Re3(O2Cl5)2 cluster, there are two inequivalent Re sites. In the first Re site, Re is bonded to five Cl atoms to form corner-sharing ReCl5 trigonal bipyramids. There are a spread of Re–Cl bond distances ranging from 2.23–2.47 Å. In the second Re site, Re is bonded to one O and four Cl atoms to form distorted corner-sharing ReCl4O trigonal bipyramids. The Re–O bond length is 1.70 Å. There are a spread of Re–Cl bond distances ranging from 2.30–2.51 Å. There are two inequivalent O sites. In the first O site, O is bonded in a single-bond geometry to one Cl atom. The O–Cl bond length is 1.57 Å. In the second O site, O is bonded in a single-bond geometry to one Re atom. There are six inequivalent Cl sites. In the first Cl site, Cl is bonded in a single-bond geometry to one Re atom. In the second Cl site, Cl is bonded in a bent 120 degrees geometry to two equivalent Re atoms. In the third Cl site, Cl is bonded in a water-like geometry to two Re atoms. In the fourth Cl site, Cl is bonded in a bent 120 degrees geometry to one Re and one O atom. In the fifth Cl site, Cl is bonded in a single-bond geometry to one Re atom. In the sixth Cl site, Cl is bonded in a single-bond geometry to one Re atom.

36 MATERIALS SCIENCE↗
DOE OSTI2020

Materials Data on Re(ClO)3 by Materials Project

Re(OCl)3 crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two Re(OCl)3 clusters. Re is bonded in a 5-coordinate geometry to three O and three Cl atoms. There are a spread of Re–O bond distances ranging from 1.71–1.99 Å. There are a spread of Re–Cl bond distances ranging from 2.26–2.77 Å. There are three inequivalent O sites. In the first O site, O is bonded in a single-bond geometry to one Re atom. In the second O site, O is bonded in a single-bond geometry to one Re atom. In the third O site, O is bonded in a distorted single-bond geometry to one Re and one Cl atom. The O–Cl bond length is 2.33 Å. There are three inequivalent Cl sites. In the first Cl site, Cl is bonded in a 1-coordinate geometry to one Re and one O atom. In the second Cl site, Cl is bonded in a single-bond geometry to one Re atom. In the third Cl site, Cl is bonded in a single-bond geometry to one Re atom.

36 MATERIALS SCIENCE↗
DOE OSTI2020

Materials Data on Re3Cl9O5 by Materials Project

Re3O5Cl9 crystallizes in the orthorhombic Ama2 space group. The structure is two-dimensional and consists of two Re3O5Cl9 sheets oriented in the (0, 0, 1) direction. there are three inequivalent Re+6.33+ sites. In the first Re+6.33+ site, Re+6.33+ is bonded in a 5-coordinate geometry to one O2- and four Cl1- atoms. The Re–O bond length is 1.68 Å. There are a spread of Re–Cl bond distances ranging from 2.27–2.55 Å. In the second Re+6.33+ site, Re+6.33+ is bonded in a 5-coordinate geometry to one O2- and four Cl1- atoms. The Re–O bond length is 1.69 Å. There are a spread of Re–Cl bond distances ranging from 2.27–2.50 Å. In the third Re+6.33+ site, Re+6.33+ is bonded in a distorted trigonal bipyramidal geometry to one O2- and four Cl1- atoms. The Re–O bond length is 1.69 Å. There are a spread of Re–Cl bond distances ranging from 2.28–2.47 Å. There are four inequivalent O2- sites. In the first O2- site, O2- is bonded in a single-bond geometry to one Re+6.33+ and two equivalent O2- atoms. Both O–O bond lengths are 3.10 Å. In the second O2- site, O2- is bonded in a single-bond geometry to one Re+6.33+ and two equivalent O2- atoms. Both O–O bond lengths are 3.02 Å. In the third O2- site, O2- is bonded in a single-bond geometry to one Re+6.33+ and two equivalent O2- atoms. Both O–O bond lengths are 2.96 Å. In the fourth O2- site, O2- is bonded in a 3-coordinate geometry to three O2- atoms. There are six inequivalent Cl1- sites. In the first Cl1- site, Cl1- is bonded in a single-bond geometry to one Re+6.33+ atom. In the second Cl1- site, Cl1- is bonded in a single-bond geometry to one Re+6.33+ atom. In the third Cl1- site, Cl1- is bonded in a single-bond geometry to one Re+6.33+ atom. In the fourth Cl1- site, Cl1- is bonded in a bent 120 degrees geometry to two Re+6.33+ atoms. In the fifth Cl1- site, Cl1- is bonded in a bent 120 degrees geometry to two Re+6.33+ atoms. In the sixth Cl1- site, Cl1- is bonded in a bent 120 degrees geometry to two Re+6.33+ atoms.

36 MATERIALS SCIENCE↗
DOE OSTI2020

Materials Data on Re2Cl5O4 by Materials Project

ReO3ClReOCl4 crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one ReO3Cl cluster and one ReOCl4 cluster. In the ReO3Cl cluster, Re+6.50+ is bonded in a tetrahedral geometry to three O2- and one Cl1- atom. There is two shorter (1.72 Å) and one longer (1.73 Å) Re–O bond length. The Re–Cl bond length is 2.22 Å. There are three inequivalent O2- sites. In the first O2- site, O2- is bonded in a single-bond geometry to one Re+6.50+ atom. In the second O2- site, O2- is bonded in a single-bond geometry to one Re+6.50+ atom. In the third O2- site, O2- is bonded in a single-bond geometry to one Re+6.50+ atom. Cl1- is bonded in a single-bond geometry to one Re+6.50+ atom. In the ReOCl4 cluster, Re+6.50+ is bonded in a 5-coordinate geometry to one O2- and four Cl1- atoms. The Re–O bond length is 1.69 Å. All Re–Cl bond lengths are 2.29 Å. O2- is bonded in a single-bond geometry to one Re+6.50+ atom. There are four inequivalent Cl1- sites. In the first Cl1- site, Cl1- is bonded in a single-bond geometry to one Re+6.50+ atom. In the second Cl1- site, Cl1- is bonded in a single-bond geometry to one Re+6.50+ atom. In the third Cl1- site, Cl1- is bonded in a single-bond geometry to one Re+6.50+ atom. In the fourth Cl1- site, Cl1- is bonded in a single-bond geometry to one Re+6.50+ atom.

36 MATERIALS SCIENCE↗