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All sourcesNASA NTRSDOE OSTI
DOE OSTI2020

Materials Data on ClO3 by Materials Project

ClO3 crystallizes in the monoclinic Cc space group. The structure is zero-dimensional and consists of four hypochlorous acid;hydrate molecules and four ClO4 clusters. In each ClO4 cluster, there are four inequivalent O sites. In the first O site, O is bonded in a single-bond geometry to one Cl atom. The O–Cl bond length is 1.45 Å. In the second O site, O is bonded in a single-bond geometry to one Cl atom. The O–Cl bond length is 1.49 Å. In the third O site, O is bonded in a single-bond geometry to one Cl atom. The O–Cl bond length is 1.48 Å. In the fourth O site, O is bonded in a single-bond geometry to one Cl atom. The O–Cl bond length is 1.44 Å. Cl is bonded in a tetrahedral geometry to four O atoms.

36 MATERIALS SCIENCE↗
DOE OSTI2020

Materials Data on ClO2 by Materials Project

ClO2 crystallizes in the orthorhombic Pbca space group. The structure is zero-dimensional and consists of eight hypochlorous acid;hydrate molecules. there are two inequivalent O sites. In the first O site, O is bonded in a single-bond geometry to one Cl atom. The O–Cl bond length is 1.50 Å. In the second O site, O is bonded in a single-bond geometry to one Cl atom. The O–Cl bond length is 1.48 Å. Cl is bonded in a bent 120 degrees geometry to two O atoms.

36 MATERIALS SCIENCE↗
DOE OSTI2020

Materials Data on Cl2O by Materials Project

Cl2O crystallizes in the tetragonal I4_1/amd space group. The structure is zero-dimensional and consists of eight chlorine monoxide molecules. O is bonded in a bent 120 degrees geometry to two equivalent Cl atoms. Both O–Cl bond lengths are 1.73 Å. Cl is bonded in a single-bond geometry to one O atom.

36 MATERIALS SCIENCE↗