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PtCl2(NO)2 crystallizes in the tetragonal P4_2/nmc space group. The structure is zero-dimensional and consists of four 1,3,2,4-dioxadiazetidine molecules and four platinum(ii) chloride molecules.
PtN2(OCl)2 crystallizes in the tetragonal P4_2/nmc space group. The structure is one-dimensional and consists of four PtN2(OCl)2 ribbons oriented in the (1, 0, 0) direction. Pt4+ is bonded in a distorted trigonal pyramidal geometry to two equivalent O2- and two equivalent Cl1- atoms. Both Pt–O bond lengths are 2.01 Å. Both Pt–Cl bond lengths are 2.30 Å. N1+ is bonded in an L-shaped geometry to two equivalent O2- atoms. Both N–O bond lengths are 1.54 Å. O2- is bonded in a distorted trigonal planar geometry to one Pt4+ and two equivalent N1+ atoms. Cl1- is bonded in a single-bond geometry to one Pt4+ atom.
(PtNOCl3)2N2(NCl)4 crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four ammonia molecules, eight chloramine molecules, and four PtNOCl3 clusters. In each PtNOCl3 cluster, Pt5+ is bonded in a T-shaped geometry to three Cl1- atoms. There are two shorter (2.34 Å) and one longer (2.38 Å) Pt–Cl bond lengths. N+0.50+ is bonded in a single-bond geometry to one O2- and one Cl1- atom. The N–O bond length is 1.14 Å. The N–Cl bond length is 2.50 Å. O2- is bonded in a single-bond geometry to one N+0.50+ atom. There are three inequivalent Cl1- sites. In the first Cl1- site, Cl1- is bonded in a single-bond geometry to one Pt5+ atom. In the second Cl1- site, Cl1- is bonded in a single-bond geometry to one Pt5+ atom. In the third Cl1- site, Cl1- is bonded in a distorted water-like geometry to one Pt5+ and one N+0.50+ atom.
PtN4OCl2 crystallizes in the tetragonal P4/mmm space group. The structure is three-dimensional. Pt2+ is bonded in a square co-planar geometry to four equivalent N+0.50+ atoms. All Pt–N bond lengths are 1.96 Å. N+0.50+ is bonded in a 5-coordinate geometry to one Pt2+ and four equivalent Cl1- atoms. All N–Cl bond lengths are 2.53 Å. O2- is bonded in a 4-coordinate geometry to four equivalent Cl1- atoms. All O–Cl bond lengths are 2.88 Å. Cl1- is bonded in a 8-coordinate geometry to eight equivalent N+0.50+ and two equivalent O2- atoms.
Pt(N2OCl)2 crystallizes in the monoclinic C2/m space group. The structure is one-dimensional and consists of two platinum molecules and four N2OCl ribbons oriented in the (0, 1, 0) direction. In each N2OCl ribbon, N1+ is bonded in a distorted single-bond geometry to one O2- and one Cl1- atom. The N–O bond length is 1.39 Å. The N–Cl bond length is 2.13 Å. O2- is bonded in a water-like geometry to two equivalent N1+ atoms. Cl1- is bonded in a 2-coordinate geometry to two equivalent N1+ atoms.
PtCl2(N2)2(ClO)2 crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four hypochlorous acid molecules, four nitrogen molecules, and two platinum(ii) chloride molecules.
PtN2(OCl)2 crystallizes in the tetragonal P4_2/n space group. The structure is one-dimensional and consists of four PtN2(OCl)2 ribbons oriented in the (0, 1, 0) direction. Pt4+ is bonded in a distorted trigonal pyramidal geometry to two equivalent O2- and two equivalent Cl1- atoms. Both Pt–O bond lengths are 2.02 Å. Both Pt–Cl bond lengths are 2.29 Å. N1+ is bonded in an L-shaped geometry to two equivalent O2- atoms. Both N–O bond lengths are 1.55 Å. O2- is bonded in a distorted trigonal planar geometry to one Pt4+ and two equivalent N1+ atoms. Cl1- is bonded in a single-bond geometry to one Pt4+ atom.
(PtCl3)2N2(NO)2(NCl)4 crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four ammonia molecules, eight chloramine molecules, four nitroxyl molecules, and four trichloroplatinum molecules.