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Materials Data on Rb3TeH6(ClO2)3 by Materials Project

Rb3H6Te(O2Cl)3 crystallizes in the trigonal R-3c space group. The structure is three-dimensional. Rb1+ is bonded in a 5-coordinate geometry to two equivalent O2- and three equivalent Cl1- atoms. Both Rb–O bond lengths are 3.04 Å. There are two shorter (3.25 Å) and one longer (3.28 Å) Rb–Cl bond lengths. H1+ is bonded in a single-bond geometry to one O2- atom. The H–O bond length is 1.00 Å. Te6+ is bonded in an octahedral geometry to six equivalent O2- atoms. All Te–O bond lengths are 1.96 Å. O2- is bonded in a 1-coordinate geometry to one Rb1+, one H1+, and one Te6+ atom. Cl1- is bonded in a distorted T-shaped geometry to three equivalent Rb1+ atoms.

36 MATERIALS SCIENCE↗