Materials Data on HI(ClO)4 by Materials Project
O2HO2ICl4 crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two hydrogen peroxide molecules and two ICl4 clusters. In each ICl4 cluster, I is bonded in a square co-planar geometry to four equivalent Cl atoms. There are two shorter (2.48 Å) and two longer (2.49 Å) I–Cl bond lengths. Cl is bonded in a single-bond geometry to one I atom.
36 MATERIALS SCIENCE↗