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CoCl2 is trigonal omega-like structured and crystallizes in the trigonal R-3m space group. The structure is two-dimensional and consists of three CoCl2 sheets oriented in the (0, 0, 1) direction. Co2+ is bonded to six equivalent Cl1- atoms to form edge-sharing CoCl6 octahedra. All Co–Cl bond lengths are 2.43 Å. Cl1- is bonded in a distorted T-shaped geometry to three equivalent Co2+ atoms.
CoCl2 is trigonal omega structured and crystallizes in the monoclinic C2/m space group. The structure is two-dimensional and consists of one CoCl2 sheet oriented in the (0, 0, 1) direction. Co2+ is bonded to six equivalent Cl1- atoms to form edge-sharing CoCl6 octahedra. There are two shorter (2.40 Å) and four longer (2.46 Å) Co–Cl bond lengths. Cl1- is bonded in a distorted T-shaped geometry to three equivalent Co2+ atoms.
CoCl2 is trigonal omega structured and crystallizes in the monoclinic C2/m space group. The structure is two-dimensional and consists of one CoCl2 sheet oriented in the (0, 0, 1) direction. Co2+ is bonded to six equivalent Cl1- atoms to form edge-sharing CoCl6 octahedra. There are two shorter (2.42 Å) and four longer (2.44 Å) Co–Cl bond lengths. Cl1- is bonded in a distorted T-shaped geometry to three equivalent Co2+ atoms.