Materials Data on CeVO2 by Materials Project
CeVO2 crystallizes in the tetragonal I4_1/amd space group. The structure is three-dimensional. Ce is bonded to six equivalent O atoms to form edge-sharing CeO6 octahedra. There are two shorter (2.43 Å) and four longer (2.45 Å) Ce–O bond lengths. V is bonded in a square co-planar geometry to four equivalent O atoms. All V–O bond lengths are 2.19 Å. O is bonded to three equivalent Ce and two equivalent V atoms to form a mixture of distorted edge and corner-sharing OCe3V2 trigonal bipyramids.
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