Materials Data on CeB2Ir2C by Materials Project
CeIr2B2C crystallizes in the tetragonal I4/mmm space group. The structure is three-dimensional. Ce3+ is bonded in a square co-planar geometry to four equivalent C4- atoms. All Ce–C bond lengths are 2.73 Å. Ir+3.50+ is bonded to four equivalent B3- atoms to form a mixture of corner and edge-sharing IrB4 tetrahedra. All Ir–B bond lengths are 2.21 Å. B3- is bonded in a distorted single-bond geometry to four equivalent Ir+3.50+ and one C4- atom. The B–C bond length is 1.52 Å. C4- is bonded in a distorted linear geometry to four equivalent Ce3+ and two equivalent B3- atoms.
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