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6 records
All sourcesNASA NTRSDOE OSTI
DOE OSTI2020

Materials Data on CeAlSi by Materials Project

CeAlSi is hexagonal omega structure-derived structured and crystallizes in the tetragonal I4_1md space group. The structure is three-dimensional. Ce is bonded to six equivalent Al and six equivalent Si atoms to form a mixture of face and edge-sharing CeAl6Si6 cuboctahedra. There are two shorter (3.21 Å) and four longer (3.22 Å) Ce–Al bond lengths. There are four shorter (3.21 Å) and two longer (3.23 Å) Ce–Si bond lengths. There are three inequivalent Al sites. In the first Al site, Al is bonded in a distorted trigonal planar geometry to six equivalent Ce and three equivalent Si atoms. There are two shorter (2.43 Å) and one longer (2.44 Å) Al–Si bond lengths. In the second Al site, Al is bonded in a distorted trigonal planar geometry to six equivalent Ce and three equivalent Si atoms. There are two shorter (3.21 Å) and four longer (3.22 Å) Al–Ce bond lengths. There are two shorter (2.43 Å) and one longer (2.44 Å) Al–Si bond lengths. In the third Al site, Al is bonded in a distorted trigonal planar geometry to six equivalent Ce and three equivalent Si atoms. There are two shorter (3.21 Å) and four longer (3.22 Å) Al–Ce bond lengths. There are two shorter (2.43 Å) and one longer (2.44 Å) Al–Si bond lengths. Si is bonded in a distorted trigonal planar geometry to six equivalent Ce and three Al atoms.

36 MATERIALS SCIENCE↗
DOE OSTI2023

Topological features in the ferromagnetic Weyl semimetal CeAlSi: Role of domain walls

In the ferromagnetic (FM) Weyl semimetal CeAlSi both space-inversion and time-reversal symmetries are broken. Our quantum oscillation (QO) data indicate that the FM ordering modifies the Fermi-surface topology and also leads to an unusual drop in the QO amplitude. In the FM phase, we find a pressure-induced suppression of the anomalous and the loop Hall effects. This cannot be explained based on the electronic band structure or magnetic structure, both of which are nearly pressure independent. Instead, we show that a simplified model describing the scattering of Weyl fermions off FM domain walls can potentially explain the observed topological features. Our study highlights the importance of domain walls for understanding transport in FM Weyl semimetals.

36 MATERIALS SCIENCE↗
DOE OSTI2023

Observation of Fermi arcs and Weyl nodes in a noncentrosymmetric magnetic Weyl semimetal

Weyl semimetal (WSM), a novel state of quantum matter, hosts Weyl fermions as emergent quasiparticles resulting from the breaking of either inversion or time-reversal symmetry. Magnetic WSMs that arise from broken time-reversal symmetry provide an exceptional platform to understand the interplay between magnetic order and Weyl physics, but only a few WSMs have been realized. Here, in this study, we identify CeAlSi as a new noncentrosymmetric magnetic WSM via angle-resolved photoemission spectroscopy (ARPES) and first-principles, density-functional theory based calculations. Our surface-sensitive vacuum ultraviolet ARPES data confirm the presence of surface Fermi arcs as the conclusive evidence for the existence of the Weyl semimetallic state in CeAlSi. We also observe bulk Weyl cones at the Fermi arc terminations in CeAlSi using bulk-sensitive soft-x-ray ARPES measurements. These results implicate CeAlSi as a unique platform for investigating exotic quantum phenomena resulting from the interaction of topology and magnetism.

36 MATERIALS SCIENCE↗
DOE OSTI2026

Incommensurate Magnetism Drives Singular Angular Magnetoresistance in the Magnetic Weyl Semimetal CeAlGe

Here, we demonstrate that a multi-𝐤 incommensurate magnetic state in the Weyl semimetal CeAlGe gives rise to a singular angular magnetoresistance (SAMR), which is an electrical transport signature capable of detecting magnetic field direction with exceptional precision. In contrast, its sister compound CeAlSi is devoid of both multi-𝐤 order and SAMR. We reveal that both phenomena appear upon 57% Ge substitution in CeAlSi 1−𝑥⁢ Ge 𝑥 and coincide with electronic structure changes that soften the single-ion in-plane anisotropy and enhance Weyl-mediated magnetic interactions. These results unveil a remarkable connection between band topology, electronic transport, and collective magnetism in Weyl semimetals.

Yao, Xiaohan [Boston College, Chestnut Hill, MA (U↗
DOE OSTI2021

Noncollinear ferromagnetic Weyl semimetal with anisotropic anomalous Hall effect

An emerging frontier in condensed matter physics involves novel electromagnetic responses, such as the anomalous Hall effect (AHE), in ferromagnetic Weyl semimetals (FM-WSMs). Candidate FM-WSMs have been limited to materials that preserve inversion symmetry and generate Weyl crossings by breaking the time-reversal symmetry. These materials share three common features: a centrosymmetric lattice, a collinear FM ordering, and a large AHE observed when the field is parallel to the magnetic easy axis. Here, we present CeAlSi as a new type of FM-WSM in which the Weyl nodes are stabilized by breaking the inversion symmetry, but their positions are tuned by breaking the time-reversal symmetry. Unlike the other FM-WSMs, CeAlSi has a noncentrosymmetric lattice, a noncollinear FM ordering, and a novel AHE that is anisotropic between the easy and hard magnetic axes. It also exhibits large FM domains that are promising for exploring both device applications and the interplay between the Weyl nodes and FM domain walls.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2024

Nonlinear optical diode effect in a magnetic Weyl semimetal

Diode effects are of great interest for both fundamental physics and modern technologies. Electrical diode effects (nonreciprocal transport) have been observed in Weyl systems. Optical diode effects arising from the Weyl fermions have been theoretically considered but not probed experimentally. Here, we report the observation of a nonlinear optical diode effect (NODE) in the magnetic Weyl semimetal CeAlSi, where the magnetization introduces a pronounced directionality in the nonlinear optical second-harmonic generation (SHG). We demonstrate a six-fold change of the measured SHG intensity between opposite propagation directions over a bandwidth exceeding 250 meV. Supported by density-functional theory, we establish the linearly dispersive bands emerging from Weyl nodes as the origin of this broadband effect. We further demonstrate current-induced magnetization switching and thus electrical control of the NODE. Our results advance ongoing research to identify novel nonlinear optical/transport phenomena in magnetic topological materials and further opens new pathways for the unidirectional manipulation of light.

36 MATERIALS SCIENCE↗