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Materials Data on CeAlAu by Materials Project

CeAuAl crystallizes in the hexagonal P6_3/mmc space group. The structure is three-dimensional. Ce is bonded to six equivalent Au and six equivalent Al atoms to form a mixture of face and edge-sharing CeAl6Au6 cuboctahedra. All Ce–Au bond lengths are 3.23 Å. All Ce–Al bond lengths are 3.23 Å. Au is bonded in a 3-coordinate geometry to six equivalent Ce and three equivalent Al atoms. All Au–Al bond lengths are 2.62 Å. Al is bonded in a distorted trigonal planar geometry to six equivalent Ce and three equivalent Au atoms.

36 MATERIALS SCIENCE↗

Materials Data on CeAlAu by Materials Project

CeAuAl crystallizes in the orthorhombic Pnma space group. The structure is three-dimensional. Ce is bonded in a 12-coordinate geometry to six equivalent Au and six equivalent Al atoms. There are a spread of Ce–Au bond distances ranging from 3.13–3.51 Å. There are a spread of Ce–Al bond distances ranging from 3.20–3.40 Å. Au is bonded in a 10-coordinate geometry to six equivalent Ce and four equivalent Al atoms. There are a spread of Au–Al bond distances ranging from 2.67–2.84 Å. Al is bonded in a 4-coordinate geometry to six equivalent Ce and four equivalent Au atoms.

36 MATERIALS SCIENCE↗