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At least 19 records
All sourcesNASA NTRSDOE OSTI
NASA NTRS1990

Thermal and electric properties of Nd(1.85)Ce(0.15)CuO(4-y) and Pr(1.85)Ce(0.15)CuO(4-y)

Electric resistivity, magnetic susceptibility, thermoelectric power, and Hall coefficient of Nd(1.85)Ce(0.15)CuO(4-y) and Pr(1.85)Ce(0.15)CuO(4-y) whose onset temperature of the superconductivity are 24 K and 23 K were measured. Experimental results show many interesting features. In particular, the Hall coefficients are negative and relatively flat as a function of temperature. However, the temperature dependence of the thermoelectric power (TEP) for these two samples shows the positive sign for both samples in contrast to the previous results. Moreover TEP for both samples remains flat in the normal state below 250 K, but decreases rapidly above 250 K. TEP of only Pr(1.85)Ce(0.15)CuO(4-y) shows a peak near 50 K. Finally onset temperatures of sudden drop of TEP are higher than those of resistance drop. The physical properties of these samples produced at different conditions such as different heat treatment temperatures, atmospheres were also measured. TEP and resistance measurement show that oxygen deficiency is essential to produce better superconducting samples. Correlation between TEP and superconductivity for these different samples will be discussed.

Lim, Z. S.↗
NASA NTRS1991

Thermal and electric properties of Nd(1.85)Ce(0.15)CuO(4-y) and Pr(1.85)Ce(0.15)CuO(4-y)

Electric resistivity, magnetic susceptibility, thermoelectric power, and Hall coefficient of Nd(1.85)Ce(0.15)CuO(4-y) and Pr(1.85)Ce(0.15)CuO(4-y) whose onset temperature of the superconductivity are 24 and 23 K were measured. Experimental results show many interesting features. In particular, the Hall coefficients are negative and relatively flat as a function of temperature. However, the temperature dependence of the thermoelectric power (TEP) for these two samples shows the positive sign for both samples in contrast to the previous results. Moreover, TEP for both samples remains flat in the normal state below 250 K, but decreases rapidly above 250 K. TEP of only Pr(1.85)Ce(0.15)CuO(4-y) shows a peak near 50 K. Finally, onset temperatures of sudden drop of TEP are higher than those of resistance drop. The physical properties of these samples produced at different conditions such as different heat treatment temperatures, atmospheres were also measured. TEP and resistance measurement show that oxygen deficiency is essential to produce better superconducting samples. Correlation between TEP and superconductivity for these different samples are discussed.

Lim, Z. S.↗
NASA NTRS1973

Neutron emission following muon capture in Ce-142, Ce-140, Ba-138, and Sn-120.

Branching ratios to excited nuclear states formed after muon capture have been measured with Ge(Li) detectors. The delayed gamma rays were observed in studies of muonic Ce-142, Ce-140, Ba-138, and Sn-120, using separated isotopes. The resulting isotopes formed indicate at least a 60% probability of neutron emission upon muon capture, with the most likely product resulting from single-neutron emission. No evidence for delayed proton emission with a probability higher than 2% was found. Using our more precise energies for the observed nuclear transitions, we present revised energy levels schemes for La-141, La-139, Cs-137, and In-119.

Lucas, G. R., Jr.↗
NASA NTRS1993

Earth's partial pressure of CO2 over the past 100-500 Ma; evidence from Ce anomalies in mostly shallow seas (less than 200 m) as recorded in carbonate sediments, 2

We reported the direct relationship of Ce anomalies recorded in 0.2-119 Ma CaCO3 sediments (Ce(sup A*)) to the Ce anomalies in the parental Pacific deep seawater (Ce(sup A)) and their relationship to atmospheric P(CO2) relative to present P(CO2). We have analyzed continental CaCO3 samples that were deposited in ancient oceans and shallow sea platforms less than 200 m over central USA, central Europe, China, and Saudi-Arabia/Oman. We have plotted Ce(sup A*) over the 75-470 Ma interval. For P(CO2) calculations, we assumed as a reference standard the less than 200 m mixed Pacific Ocean with a Ce(sup A) geometric mean of 0.22 and a range of 0.10-0.43. Because P(CO2) values obtained from reliable deep Pacific Ocean carbonates in the 67-119 Ma interval were similar to the present P(CO2) values, we have drawn a 1.0 ratio for that interval. Although there is considerable scatter among the approximately 150 Ma carbonates, the average Ce(sup A*) value suggests that P(CO2) increased during the early Cretaceous, from 1.0X at approximately 120 Ma to about 1.4X at approximately 150 Ma. At approximately 250 Ma, the average Ce(sup A*) in 13 shallow sea China carbonates agrees well with the single and more reliable approximately 250 Ma China carbonate deposited in deeper open platform. We suggest that P(CO2) ranged from 1.4-1.7X over the Jurassic and Triassic periods. At approximately 280 Ma, three China carbonates deposited in deeper open platforms and therefore considered more reliable are consistent with a European carbonate, which indicate Ce(sup A) and P(CO2) values similar to the present. The minimum at this time corresponds to the great Permo-Carboniferous glaciation. From 280 Ma to 470 Ma, the trend favors increasing Ce(sup A*) and corresponding P(CO2) values between 1.9-2.7X, with a more reliable value closer to 2.7X at 430 Ma because of the unknown higher temperature in the less than 100 m seawater over continental USA which was located just south of the equator at approximately 430 Ma.

Liu, Y.-G.↗
NASA NTRS1993

Earth's partial pressure of CO2 over the past 120 Ma; evidence from Ce anomalies in the deep (greater than 600 m) Pacific Ocean, 1

It was found that Ce serves as a chemical tracer of paleo-oceanic redox conditions. It was shown that the unoxidized and soluble Ce(3+) in modern seawater exhibits a negative anomaly relative to the other soluble REE(3+). An expression of soluble Ce(3+) in seawater that was approximately 1900X greater than the average observed in Ce in 600-5000 m Pacific seawater was derived. Since Ce(CO3)(+) and Ce(CO3)2(-) complexes greatly exceed the Ce(PO4) complexes in seawater, the formulations of using carbonate complexes were followed and it was found that the calculated Ce and observed concentrations in the deep 600-5000 m Pacific Ocean agree within the uncertainties of the thermodynamic data. As expected, the calculated Ce concentrations are a strong function of pH and found to be lesser functions of CO3(2-) activities.

Liu, Y.-G↗
NASA NTRS1984

Applicability of La-Ce systematics to planetary samples

Cesium isotopic compositions in several terrestrial and extraterrestrial materials were determined in order to investigate the applicability of using Ce as an isotropic tracer to geological processes. A tenuous anticorrelation was observed between (epsilon)Ce and (epsilon)Nd for terrestrial basalts and granites, indicating that with some improvement in analytical techniques the Ce isotopic composition may prove useful as tracer for geological processes. A very low (epsilon)Ce predicted from the Ce anomaly in the REE pattern of the Kholar L3 chondrite was not observed, indicating that the anomaly may be caused by terrestrial contamination or alteration.

Nakamura, N.↗
NASA NTRS1990

Preparation and characteristics of superconducting cuprate thin films: Nd(2-x)Ce(x)CuO4 and substituted Bi-system

Characteristics of the electron-doped-type Nd(2-x)Ce(x)CuO4 systems and substituted Bi2(Sr,Ln)3Cu2Oy system were systematically studied using the high quality thin-film samples. The Nd(2-x)Ce(x)CuO4 thin films with various Ce concentrations, x, were prepared by RF magnetron sputtering on SrTiO3 heated at around 500 C. After subsequent annealing at 1100 C in air, the films showed the c-axis orientation normal to the substrates. By means of the reducing treatment (annealing in a vacuum), superconductivity was induced for the films with 0.14 is less than or equal to x is less than or equal to 0.18. The superconductivity and transport properties of the films were strongly affected by the reducing treatment. The x = 0.15 film exhibited a sharp superconducting transition with zero resistivity at 22 K, in consistent with the diamagnetic properties. The resistivity of the films was fairly low with metallic characteristics, and the sight of the Hall coefficient was negative in the normal state. On the other hand, the normal-state optical measurements showed that the undoped Nd2CuO4 is a semiconductor with a charge transfer gap of 1.3 eV, and that, when Ce ions were doped, a plasma reflection due to the free-carriers came to be seen with the plasma frequency of 1.07 eV for 0.14 is less than or equal to x is less than or equal to 0.18. Moreover, x ray photoemission study revealed that the Cu valence of the film decreased for 2(+) for x = 0 to 1(+) for x = 0.15. These physical properties are in contrast with those of hole-doped-type cuprate superconductors. Bi2(Sr,Ln)3Cu2Oy thin films were also prepared on MgO substrates heated at 600 to 700 C by similar methods. It was found that the growth conditions for Bi-systems with two CuO2 planes were different for each composition and species of lanthanoid in the films. Moreover, preparation of Bi-system with three CuO2 planes was very difficult when lanthanoid atoms were doped in the system. Their electric transport properties and x ray photoemission spectroscopy were investigated. Carrier concentration and Cu valence were discussed with regard to the superconductivity.

Adachi, H.↗
NASA NTRS2015

Drought Variability in the Eastern Australia and New Zealand Summer Drought Atlas (ANZDA, CE 1500-2012) Modulated by the Interdecadal Pacific Oscillation

Agricultural production across eastern Australia and New Zealand is highly vulnerable to drought, but there is a dearth of observational drought information prior to CE (Christian Era) 1850. Using a comprehensive network of 176 drought-sensitive tree-ring chronologies and one coral series, we report the first Southern Hemisphere gridded drought atlas extending back to CE 1500. The austral summer (December-February) Palmer drought sensitivity index reconstruction accurately reproduces historically documented drought events associated with the first European settlement of Australia in CE 1788, and the leading principal component explains over 50 percent of the underlying variance. This leading mode of variability is strongly related to the Interdecadal Pacific Oscillation tripole index (IPO), with a strong and robust antiphase correlation between (1) eastern Australia and the New Zealand North Island and (2) the South Island. Reported positive, negative, and neutral phases of the IPO are consistently reconstructed by the drought atlas although the relationship since CE 1976 appears to have weakened.

Palmer, Jonathan G.↗
NASA NTRS1991

Preparation and characteristics of superconducting cuprate thin films: Nd(2-x)Ce(x)CuO4 and substrated Bi-system

Characteristics of the electron-doped-type Nd(sub 2-x)Ce(sub x)CuO4 system and substituted Bi-system were studied using the high quality thin film samples grown by rf magnetron sputtering and/or subsequent heat treatment. The Nd(sub 2-x)Ce(sub x)CuO4 samples with excellent superconducting properties were obtained in thin films and their optical and X-ray photoelectron spectroscopy (XPS) studies were performed with regard to the Ce content and reducing treatment. Substituted BiSr-Ln-Cu-O thin films were prepared and growth conditions for Bi-system with 2-2-1-2 and 2-2-2-2 phases were found. Moreover, a new 2-2-1-2 phase in the simple Bi-Sr-Cu-O system was fabricated by thin film processing and 80 K superconductivity was obtained.

Adachi, H.↗
NASA NTRS1993

Photometric investigation of a very short period W UMa-type binary - Does CE Leonis have a large superluminous area?

A complete photometric analysis of BVRI Johnson-Cousins photometry of the high northern latitude galactic variable, CE Leo is presented. These observations were taken at Kitt Peak National Observatory on May 31, 1989-June 7, 1989. Three new precise epochs of minimum light were determined and a linear and a quadratic ephemeris were computed from these and previous data covering 28 years of observation. The light curves reveal that the system undergoes a brief 20 min totality in the primary eclipse, indicating that CE Leo is a W UMa W-type binary. A systemic velocity of about -40 km/s was determined. Standard magnitudes were found and a simultaneous solution of the B, V, R, I light curves was computed using the new Wilson-Devinney synthetic light curve code which has the capability of automatically adjusting star spots. The solution indicates that the system consists of two early K-type dwarfs in marginal contact with a fill-out factor less than 3 percent. Evidence for the presence of a large (45 deg radius) superluminous area on the cooler component is given.

Samec, Ronald G.↗
NASA NTRS1995

Laser-Induced Photochromic Centers in Ce(3+):La2Be2O5

Intense 355-nm excitation of the lowest 4f to 5d transition of Ce(3+):La2Be2O5 leads to a brownish coloration of the crystal due to the formation of stable photochromic centers. These centers are characterized by a broadband absorption spectrum that spans the 220-840 nm spectral range. Since they can be readily bleached by optical excitation into their absorption band, the centers are photochromic. They are produced by a two-step photoionization of Ce(3+) ions followed by attachment of the detached electrons at trapping sites in the crystal. The dependence of the number of centers on laser intensity and length of exposure have been measured, and the kinetics of growth have been studied.

Cheung, Y. M.↗
NASA NTRS2020

The European Russia Drought Atlas (1400-2016 CE)

We present the European Russia Drought Atlas (ERDA) that covers the East European Plain to the Ural Mountains from 1400–2016 CE. Like the Old World Drought Atlas (OWDA) for the Euro-Mediterranean region, the ERDA is a one-half degree gridded reconstruction of summer Palmer Drought Severity Indices estimated from a network of annual tree-ring chronologies. Ensemble point-by-point regression is used to generate the ERDA with the identical protocols used for developing the OWDA. Split calibration/validation tests of the ERDA indicate that it has significant skill over most of its domain and is much more skillful than the OWDA where they overlap in the western part of ERDA domain. Comparisons to historical droughts over European Russia additionally support the ERDA’s overall validity. The ERDA has been spatially smoothed and infilled using a local regression method to yield a spatially complete drought atlas back to 1400 CE. EOF analysis indicates that there are three principal modes of hydroclimatic variability in the ERDA. After Varimax rotation, these modes correlate significantly with independent climate data sets extending back to the late nineteenth century in a physically interpretable way and relate to atmospheric circulation dynamics of droughts and heatwaves over European Russia based on more recent instrumental data.

Cook, Edward R.↗
NASA NTRS2022

2020 I.F._Wickizer_New CE Tool for MDC_Final Report

Our team surveyed available products and found no readily-available/U.S. commercial or Agency products which supported our envisioned workflow for the Mission Design Center and the concurrent engineering (CE) process we use. Therefore, we sought to create our own CE tool. Changes in agency policy during the performance period allowed us to shift direction and instead adapt our previous legacy tool (Atlas) to include the collaboration features we sorely needed. Atlas relied upon databases for its back-end data management. Poseidon, the work proposed under this effort, was also intended to leverage from that previous back end (in part). However, in May 2021, EUSO announced that “SBU/CUI Information Can Now Be Shared/Stored Within O365 Without Encryption.” Consequently, we made the decision to use O365 in place of our back end. This change provides for version history, collaborative simultaneous editing, and other collaboration tools agency-wide that were previously unavailable with the old database architecture. The new Atlas O365 has more flexibility and capability for users. It’s now easier for users to switch between using the tool for concurrent engineering and individual subsystem engineering. A version was delivered for concurrent engineering of small satellite missions; so far, it has been used successfully on the Aeolus MDC study. Atlas O365 will facilitate the design and assessment of Small Satellite Missions at low Concept Maturity Level at Ames. Feasibility assessments on mission concepts still at a low CML permit strategic planning and decision-making efforts at the center level about which concepts should be pursued and proposed.

concurrent engineering↗
NASA NTRS2019

Uncertainty Analysis of the CE-22 Advanced Nozzle Test Facility

This paper presents methods and results of a detailed measurement uncertainty analysis that was performed for the Advanced Nozzle Test Facility, CE-22, located at the NASA Glenn Research Center. Results for the uncertainty in thrust and flow coefficients, in addition to other variables of interest, are provided. Results are presented separately as random uncertainty (characterizing errors inherent to instrument or measurement environment, impacting repeatability), systematic uncertainty (capturing inaccuracies due to measurement process, calibration, installation effects or other sources which may introduce bias), and total combined uncertainty. The statistical methods and engineering judgments used to estimate elemental uncertainties are described. The analysis tool MANTUS (Measurement Analysis Tool for Uncertainty in Systems) was used to quantify instrumentation system uncertainty, and statistical analysis and engineering judgment were used to quantify other random and systematic uncertainty sources. The Monte Carlo method was used to propagate systematic and random elemental uncertainties to determine the uncertainties of various calculated variables of interest.

data quality↗
NASA NTRS2021

Uncertainty Analysis of the CE-12 Free-Jet Probe Calibration Facility

This paper presents methods and results of a detailed measurement uncertainty analysis thf at was performed for the Free Jet Calibration Facility (CE-12) located at the NASA Glenn Research Center. Results for systematic uncertainty estimates in a number of fluid properties of the free jet flow are presented. Systematic uncertainty captures inaccuracies due to measurement process, calibration, installation effects or other similar sources which may introduce bias. MANTUS (Measurement Analysis Tool for Uncertainty in Systems) was used to quantify instrumentation uncertainty and engineering judgment was used to quantify other systematic uncertainty sources. The Monte Carlo method was used to propagate systematic uncertainties to determine the uncertainties of various calculated variables of interest.

CE-12↗
NASA NTRSDate not supplied

Thermal Recovery Testing & Investigations in CE-12 Free Jet Calibration Facility

This presentation reviews thermal recovery testing practices in the CE-12 Free Jet Probe Calibration Facility at the NASA Glenn Research Center. Investigations were conducted to diagnose errors identified in test results, as compared to theory. Proposed solutions and future monitoring of the facility conditions are also discussed. Information in this presentation is intended for discussion with the AETC-supported Wind Tunnel Characterization Working Group during the 2023 Face-to-Face Meetings July 25-27 at NASA Glenn Research Center.

WTCWG↗
NASA NTRS1971

Excited states of Ce-138

Ce 138 excited states identification in beta decay spectra of Pr 138m and Pr 138 sources, using proton target bombardment

Fessler, T. E.↗
NASA NTRS1977

Studies of hydride formation and superconductivity in hydrides of alloys Th-M /M = La, Y, Ce, Zr and Bi/

In order to gain a better insight into both the unusual composition of ThH15 and its superconductivity, an experimental study was conducted to assess the influence of partial replacement of Th in Th4H15 by elements which allow for a systematic alteration of spatial and electronic effects. For this purpose, substituent elements with the same number of valence electrons (4) but of smaller size (Zr) as well as elements with a smaller number of valence electrons (3) and either larger (La) or smaller size (Y) were selected. A few data with Ce and Bi as substituent atoms are also included. The matrix alloys for hydriding were obtained by induction melting under Ar in water-cooled Cu boats. Superconducting transition temperatures are found to decrease on substitution for Th in Th4H15. Hydrides derived from LaH3 by substitution for La by Th do not become superconducting. It is suggested that superconductivity in Th4H15 is connected with a deviation from the exact stoichiometry of Th4H15. A model of unsatisfied valencies may be of more general validity in predicting superconductivity.

Oesterreicher, H.↗