Materials Data on CdH16C4(Br2N)2 by Materials Project
CdBr4((CH3)2NH2)2 is Silicon tetrafluoride-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of eight dimethylazanium molecules and four CdBr4 clusters. In each CdBr4 cluster, Cd2+ is bonded in a tetrahedral geometry to four Br1- atoms. There are a spread of Cd–Br bond distances ranging from 2.62–2.66 Å. There are four inequivalent Br1- sites. In the first Br1- site, Br1- is bonded in a single-bond geometry to one Cd2+ atom. In the second Br1- site, Br1- is bonded in a single-bond geometry to one Cd2+ atom. In the third Br1- site, Br1- is bonded in a single-bond geometry to one Cd2+ atom. In the fourth Br1- site, Br1- is bonded in a single-bond geometry to one Cd2+ atom.