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Materials Data on CdPd3O4 by Materials Project

CdPd3O4 crystallizes in the cubic Pm-3n space group. The structure is three-dimensional. Pd2+ is bonded in a square co-planar geometry to four equivalent O2- atoms. All Pd–O bond lengths are 2.07 Å. Cd2+ is bonded in a body-centered cubic geometry to eight equivalent O2- atoms. All Cd–O bond lengths are 2.53 Å. O2- is bonded to three equivalent Pd2+ and two equivalent Cd2+ atoms to form a mixture of corner and edge-sharing OCd2Pd3 trigonal bipyramids.

36 MATERIALS SCIENCE↗

Materials Data on CdPd2O3 by Materials Project

Pd2CdO3 crystallizes in the tetragonal P4/mmm space group. The structure is three-dimensional. Pd2+ is bonded in a square co-planar geometry to four O2- atoms. There are two shorter (2.11 Å) and two longer (2.31 Å) Pd–O bond lengths. Cd2+ is bonded to six O2- atoms to form corner-sharing CdO6 octahedra. The corner-sharing octahedral tilt angles are 0°. There are two shorter (2.11 Å) and four longer (2.31 Å) Cd–O bond lengths. There are two inequivalent O2- sites. In the first O2- site, O2- is bonded in a square co-planar geometry to two equivalent Pd2+ and two equivalent Cd2+ atoms. In the second O2- site, O2- is bonded to four equivalent Pd2+ and two equivalent Cd2+ atoms to form corner-sharing OCd2Pd4 octahedra. The corner-sharing octahedral tilt angles are 0°.

36 MATERIALS SCIENCE↗