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La2CdZn crystallizes in the orthorhombic Immm space group. The structure is one-dimensional and consists of two La2CdZn ribbons oriented in the (0, 1, 0) direction. La is bonded in a linear geometry to one Cd and one Zn atom. The La–Cd bond length is 3.19 Å. The La–Zn bond length is 2.96 Å. Cd is bonded in a linear geometry to two equivalent La atoms. Zn is bonded in a linear geometry to two equivalent La atoms.
LaCdZn2 crystallizes in the orthorhombic Immm space group. The structure is one-dimensional and consists of two LaCdZn2 ribbons oriented in the (1, 0, 0) direction. La is bonded in a linear geometry to two equivalent Zn atoms. Both La–Zn bond lengths are 3.01 Å. Cd is bonded in a linear geometry to two equivalent Zn atoms. Both Cd–Zn bond lengths are 2.85 Å. Zn is bonded in a linear geometry to one La and one Cd atom.