Materials Data on CsCd13 by Materials Project
CsCd13 crystallizes in the cubic Fm-3c space group. The structure is three-dimensional. Cs is bonded in a 1-coordinate geometry to twenty-four equivalent Cd atoms. All Cs–Cd bond lengths are 4.12 Å. There are two inequivalent Cd sites. In the first Cd site, Cd is bonded in a cuboctahedral geometry to twelve equivalent Cd atoms. All Cd–Cd bond lengths are 3.08 Å. In the second Cd site, Cd is bonded in a 12-coordinate geometry to two equivalent Cs and ten Cd atoms. There are a spread of Cd–Cd bond distances ranging from 2.95–3.44 Å.
36 MATERIALS SCIENCE↗