Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “Catalyst environment interactions”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

6 records
All sourcesNASA NTRSDOE OSTI
NASA NTRS1987

The oxidation of carbon monoxide using a tin oxide catalyst

This paper outlines some of the steps involved in the development by the United Kingdom Atomic Energy Authority (UKAEA) of a catalytic device for the recombination of carbon monoxide and oxygen in a CO2 laser system. It contrasts the differences between CO oxidation for air purification and for laser environmental control, but indicates that there are similarities between the physical specifications. The principal features of catalytic devices are outlined and some experimental work described. This includes measurements concerning the structure and mechanical properties of the artifact, the preparation of the catalyst coating and its interaction with the gaseous environment. The paper concludes with some speculation about the method by which the reaction actually occurs.

Sampson, Christopher F.↗
NASA NTRS1991

Structure and functions of water-membrane interfaces and their role in proto-biological evolution

Among the most important developments in proto-biological evolution was the emergence of membrane-like structures. These are formed by spontaneous association of relatively simple amphiphilic molecules that would have been readily available in the primordial environment. The resulting interfacial regions between water and nonpolar interior of the membrane have several properties which made them uniquely suitable for promoting subsequent evolution. They can (1) selectively attract organic material and mediate its transport, (2) serve as simple catalysts for chemical reactions, and (3) promote the formation of trans-membrane electrical and chemical gradients which could provide energy sources for proto-cells. Understanding the structure of interfaces, their interactions with organic molecules and molecular mechanisms of their functions is an essential step to understanding proto-biological evolution. In our computer simulation studies, we showed that the structure of water at interfaces with nonpolar media is significantly different from that in the bulk. In particular, the average surface dipole density points from the vapor to the liquid. As a result, negative ions can approach the interface more easily than positive ions. Amphiphilic molecules composed of hydrocarbon conjugated rings and polar substituents (e.g., phenol) assume at the interface rigid orientations in which polar groups are buried in water while hydrocarbon parts are located in the nonpolar environment. These orientational differences are of special interest in connection with the ability of some of these molecules to efficiently absorb photons. Flexible molecules with polar substituents often adopt at interfaces conformations different from those in the bulk aquaeous solution and in the gas phase. As a result, in many instances both specificity and kinetics of chemical reactions in which these molecules can participate is modified by the presence of surfaces. Of special interest is the mechanism by which polar molecules are transferred across interface between water and a nonpolar medium. Our recent study showed that simple ionophores bind ions by the same mechanisms as ion channels and carriers from modern cells.

Pohorille, A.↗
NASA NTRS2001

Exobiochemistry

Exobiochemistry is the putative biochemistry of extraterrestrial life. It suggests the possible energy and material bases of extraterrestrial life and could help detect it. The diverse biochemistry of Earth indicates that a wide range of exobiochemistry is possible on other planets. An exobiochemistry will probably use the same energy sources as Earths ecology, light, biological organic material, and more rarely abiotic chemicals. Extraterrestrial life will be based on familiar chemical principles and probably capture, store, and release energy using oxidation-reduction reactions. Extraterrestrial life will give chemical indications of its existence. Key elements will be concentrated, stored, and recycled, altering their availability and isotopic composition. Any significant departure from chemical equilibrium would be good evidence for exobiochemistry, but an integrated system of departures from the expected equilibrium would be better. Exobiochemistry can be expected to include closed biogeochemical cycles of the major life supporting elements and may well show the complex dynamic close-coupled interactions that characterize the terrestrial biosphere. Terrestrial biochemistry provides a basis for generalization and extrapolation but it does not set bounds on exobiochemistry. In exobiochemistry we can expect: 1. closed chemical cycles that recycle materials, nutrients, and catalysts, 2. organisms with complementary metabolisms that cooperate to close the chemical cycles, 3. a high probability of a carbon and water chemistry, but some possibility of a non-carbon or non-water chemistry in extreme environments, and, 4. life similar to bacteria more prevalent than higher plants and animals.

Jones, Harry↗
NASA NTRS2014

Correlation of ISS Electric Potential Variations with Mission Operations

Orbiting approximately 400 km above the Earth, the International Space Station (ISS) is a unique research laboratory used to conduct ground-breaking science experiments in space. The ISS has eight Solar Array Wings (SAW), and each wing is 11.7 meters wide and 35.1 meters long. The SAWs are controlled individually to maximize power output, minimize stress to the ISS structure, and minimize interference with other ISS operations such as vehicle dockings and Extra-Vehicular Activities (EVA). The Solar Arrays are designed to operate at 160 Volts. These large, high power solar arrays are negatively grounded to the ISS and collect charged particles (predominately electrons) as they travel through the space plasma in the Earth's ionosphere. If not controlled, this collected charge causes floating potential variations which can result in arcing, causing injury to the crew during an EVA or damage to hardware [1]. The environmental catalysts for ISS floating potential variations include plasma density and temperature fluctuations and magnetic induction from the Earth's magnetic field. These alone are not enough to cause concern for ISS, but when they are coupled with the large positive potential on the solar arrays, floating potentials up to negative 95 Volts have been observed. Our goal is to differentiate the operationally induced fluctuations in floating potentials from the environmental causes. Differentiating will help to determine what charging can be controlled, and we can then design the proper operations controls for charge collection mitigation. Additionally, the knowledge of how high power solar arrays interact with the environment and what regulations or design techniques can be employed to minimize charging impacts can be applied to future programs.

Willis, Emily M.↗
NASA NTRS1987

Arcjet thruster research and technology. Phase 1: Executive summary

The principal objective of this two phase program is to conduct the development research required to make the low power arcjet a flight ready technology. Many important results were obtained during Phase 1 to move closer to this objective. Fundamental analyses were performed of the arcjet nozzle, the gas kinetic reaction effects, the thermal environment, and the arc stabilizing vortex. These aided the conceptual understanding of the arcjet and guided design work. A hydrazine (N2H4) arcjet was designed that combined a flight qualified catalyst bed with a modular arcjet. Extensive testing was performed which demonstrated the feasibility of using this propellant in an arcjet for the first time. Startup techniques were developed, stability maintained, material compatibility tests conducted, and performance mapping tests performed. Specific impulse values from 400 to 730 seconds were produced with a non-optimized design. These levels are higher than were originally thought possible and proved that extremely high enthalpy values can be obtained with constricted arc technology. Erosion rate data are promising for lifetime extensions to meet flight application requirements. Power control unit (PCU) development was started with the design and fabrication of a laboratory high switching frequency supply. Valuable data were obtained on PCU operation and on the interaction with the dynamic arc. Phase 2 efforts presently underway are resolving key issues for multi-hundred hour lifetimes, are continuing to investigate arcjet/PCU interactions, and will demonstrate duty cycle N2H4 arcjet/PCU operation in a simulated flight mode for lifetimes consistent with initial applications.

Source record↗
NASA NTRS1995

SPARTNIK: Engineering catalyst for government and industry

Industrial demands for highly motivated and competent technical personnel to carry forward with the technological goals of the US has posed a significant challenge to graduating engineers. While curricula has improved and diversified over time to meet these industry demands, relevant industry experience is not always available to undergraduates. The microsatellite development program at San Jose State University (SJSU) has allowed an entire undergraduate senior class to utilize a broad range of training and education to refine their engineering skills, bringing them closer to becoming engineering professionals. Close interaction with industry mentors and manufacturers on a real world project provides a significant advantage to educators and students alike. With support from companies and government agencies, the students have designed and manufactured a microsatellite, designed to be launched into a low Earth orbit. This satellite will gather telemetry for characterizing the state of the spacecraft. This will enable the students to have a physical check on their predicted value of spacecraft subsystem performance. Additional experiments will also be undertaken during the two year lifetime, including micro-meteorite impact sensing and capturing digital color images of the Earth. This paper will detail the process whereby students designed, prototype and manufactured a small satellite in a large team environment, along with the experiments that will be performed on board. With the project's limited funds, it needed the support of many industry companies to help with technical issues and hardware acquisition. Among the many supporting companies, NASA's space shuttle small payloads program could be used for an affordable launch vehicle for the student project. The paper address these collaborations between the student project and industry support, as well as explaining the benefits to both. The paper draws conclusion on how these types of student projects can be used by industry as a feasible resource for developing small platforms for space based experiments, as well as increasing the practical experience and engineering knowledge of graduating students. These benefits to industry and universities, can lead to a close working relationship between the two. These types of projects can facilitate the development of low-cost space rated parts to be used by the industry and university projects. It can also help with the understanding and use of acceptable risk non-space rated parts reducing the cost of the spacecraft. This will lead to the development of low cost platforms for space based experiments, providing research companies an inexpensive, long duration platform to conduct their in-space experiments, while better preparing engineering undergraduates for their transition into the work force.

Prass, James D.↗