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EPR measurement of the effect of glass composition on the oxidation states of europium

An investigation was conducted concerning the dependence of the concentration ratio of Eu(2+) to Eu(3+) on composition for silicate liquids whose compositional end members are CaAl2Si2O8 and MgSiO3, MG2SiO4, CaMgSi2O6, CaMgSiO4, CaSiO3, or Ca2SiO4. The liquids were quenched to produce glasses. An electron paramagnetic resonance spectrometer was used to determine the concentration ratios of Eu(2+) to Eu(3+) in the glasses.

Morris, R. V.↗

Ceramic thermal barrier coatings for gas turbine engines

The results of studies concerning the high temperature corrosion resistance of ZrO2-Y2O3, ZrO2-MgO, and Ca2SiO4 plasma-sprayed coatings, which may be used as gas turbine engine thermal barriers, are reported. The coatings were evaluated in atmospheric burner rig and pressurized passage tests, using GT No. 2 fuel in pure form and with sodium, sulfur and vanadium corrosive impurities doping. It is found that, while the coatings performed well in both pressurized passage and burner rig tests with pure fuel chemical reactions between the ceramic coatings and combustion gases/condensates resulted in coating degradation with impure fuels. Chemical reactions between the ceramic coatings and vanadium compounds played a critical role in coating degradation.

Bratton, R. J.↗

Thermal-barrier coatings for utility gas turbines

The potential of thermal barrier coatings for use in utility gas turbines was assessed. Pressurized passage and ambient pressure doped fuel burner rig tests revealed that thermal barrier coatings are not resistant to dirty combustion environments. However, present thermal barrier coatings, such as duplex partially stabilized zirconia and duplex Ca2SiO4 have ample resistance to the thermo-mechanical stress and temperature levels anticipated for heavy duty gas turbines firing clean fuel as revealed by clean fuel pressurized passage and ambient pressure burner rig tests. Thus, it is appropriate to evaluate such coatings on blades, vanes and combustors in the field. However, such field tests should be backed up with adequate effort in the areas of coating application technology and design analysis so that the field tests yield unequivocal results.

Levine, S. R.↗