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Materials Data on Ca(PRh)2 by Materials Project

CaRh2P2 crystallizes in the tetragonal I4/mmm space group. The structure is three-dimensional. Ca is bonded in a 8-coordinate geometry to eight equivalent Rh and eight equivalent P atoms. All Ca–Rh bond lengths are 3.16 Å. All Ca–P bond lengths are 3.09 Å. Rh is bonded in a 12-coordinate geometry to four equivalent Ca and four equivalent P atoms. All Rh–P bond lengths are 2.41 Å. P is bonded in a 9-coordinate geometry to four equivalent Ca, four equivalent Rh, and one P atom. The P–P bond length is 2.26 Å.

36 MATERIALS SCIENCE↗