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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 19 records

Next-Cycle Optimal Fuel Control for Cycle-to-Cycle Variability Reduction in EGR-Diluted Combustion

In this simulation study, cycle-to-cycle fuel control was used to reduce CCV by injecting additional fuel in operating conditions with sporadic misfires and partial burns. An optimal control policy was proposed that utilizes 1) a physics-based model that tracks in-cylinder gas composition and 2) a one-step-ahead prediction of the combustion efficiency based on a kernel density estimator. The optimal solution, however, presents a tradeoff between the reduction in combustion CCV and the increase in fuel injection quantity required to stabilize the charge. Such a tradeoff can be ad- just by a single parameter embedded in the cost function.

Maldonado, BryanP. [Oak Ridge National Lab. (ORNL)↗

Life-cycle analysis of integrated biorefineries with co-production of biofuels and bio-based chemicals: co-product handling methods and implications: Co-product handling methods and implications of life-cycle analysis of biofuel and bio-chemical co-producing biorefineries

New integrated biorefinery (IBR) concepts are being investigated to co-produce hydrocarbon fuels and high-value bio-based chemicals to improve the economic viability of IBRs, to enhance biomass resource utilization efficiencies, and to maximize potential greenhouse gas (GHG) emission reductions. Unlike fuel-only biorefineries, IBRs may co-produce a significant amount of bio-based chemicals, whose emission implications for specific biorefinery products and the biorefinery as a whole need to be evaluated. We discuss this in principle and apply three sets of co-product handling methods to conduct life-cycle analysis (LCA) of modeled IBRs with co-production of two bioproduct examples - succinic acid and adipic acid - alongside a renewable diesel blendstock fuel product. The LCA results for the specific co-product handling methods that were examined shed light on potential artifacts of product-specific LCA with selected co-product methods. We discuss the advantages and limitations of each method and conclude that (i) a system-level or 'black-box' LCA allocation method is too simplistic to reflect appropriately the GHG burdens of distinctly different processing trains for fuels and chemicals in the IBR context, and (ii) the displacement method is the only co-product handling method that accounts fully for the emission effects of both the fuel product and the non-fuel bio-based co-products in the IBRs within the context of the existing fuel-focused GHG regulatory framework. Alternatively, biorefinery system-level LCA combines benefits of individual products to offer a complete picture. This system-level LCA approach offers a holistic LCA without somewhat arbitrary decisions either on an allocation basis or by the selection of an evaluation metric based on specific products.

09 BIOMASS FUELS↗

Heavy-Duty Vehicle Port Drayage Drive Cycle Characterization and Development

In an effort to better understand the operational requirements of port drayage vehicles and their potential for adoption of advanced technologies, National Renewable Energy Laboratory (NREL) researchers collected over 36,000 miles of in-use duty cycle data from 30 Class 8 drayage trucks operating at the Port of Long Beach and Port of Los Angeles in Southern California. These data include 1-Hz global positioning system location and SAE J1939 high-speed controller area network information. Researchers processed the data through NREL's Drive-Cycle Rapid Investigation, Visualization, and Evaluation tool to examine vehicle kinematic and dynamic patterns across the spectrum of operations. Using the k-medoids clustering method, a repeatable and quantitative process for multi-mode drive cycle segmentation, the analysis led to the creation of multiple drive cycles representing four distinct modes of operation that can be used independently or in combination. These drive cycles are statistically representative of real-world operation of port drayage vehicles. When combined with modeling and simulation tools, these representative test cycles allow advanced vehicle or systems developers to efficiently and accurately evaluate vehicle technology performance requirements to reduce cost and development time while ultimately leading to the commercialization of advanced technologies that meet the performance requirements of the port drayage vocation. The drive cycles, which are suitable for chassis dynamometer testing, were compared to several existing test cycles. This paper presents the clustering methodology, accompanying results of the port drayage duty cycle analysis and custom drive cycle creation.

33 ADVANCED PROPULSION SYSTEMS↗

Predicting Cycle-to-Cycle Variation With Concurrent Cycles in a Gasoline Direct Injected Engine With Large Eddy Simulations

High cycle-to-cycle variation (CCV) is detrimental to engine performance, as it leads to poor combustion and high noise and vibration. In this work, CCV in a gasoline engine is studied using large eddy simulation (LES). The engine chosen as the basis of this work is a single-cylinder gasoline direct injection (GDI) research engine. Two stoichiometric part-load engine operating points (6 BMEP, 2000 RPM) were evaluated: a non-dilute (0% EGR) case and a dilute (18% EGR) case. The experimental data for both operating conditions had 500 cycles. The measured CCV in IMEP was 1.40% for the non-dilute case and 7.78% for the dilute case. To estimate CCV from simulation, perturbed concurrent cycles of engine simulations were compared to consecutively obtained engine cycles. The motivation behind this is that running consecutive cycles to estimate CCV is quite time-consuming. For example, running 100 consecutive cycles requires 2–3 months (on a typical cluster), however, by running concurrently one can potentially run all 100 cycles at the same time and reduce the overall turnaround time for 100 cycles to the time taken for a single cycle (2 days). The goal of this paper is to statistically determine if concurrent cycles, with a perturbation applied to each individual cycle at the start, can be representative of consecutively obtained cycles and accurately estimate CCV. 100 cycles were run for each case to obtain statistically valid results. The concurrent cycles began at different timings before the combustion event, with the motivation to identify the closest time before spark to minimize the run time. Only a single combustion cycle was run for each concurrent case. The calculated standard deviation of peak pressure and coefficient of variance (COV) of indicated mean effective pressure (IMEP) were compared between the consecutive and concurrent methods to quantify CCV. It was found that the concurrent method could be used to predict CCV with either a velocity or numerical perturbation. Here, a large and small velocity perturbation were compared and both produced correct predictions, implying that the type of perturbation is not important to yield a valid realization. Starting the simulation too close to the combustion event, at intake valve close (IVC) or at spark timing, under-predicted the CCV. When concurrent simulations were initiated during or before the intake even, at start of injection (SOI) or earlier, distinct and valid realizations were obtained to accurately predict CCV for both operating points. By simulating CCV with concurrent cycles, the required wall clock time can be reduced from 2–3 months to 1–2 days. Additionally, the required core-hours can be reduced up to 41%, since only a portion of each cycle needs to be simulated.

42 ENGINEERING↗

A novel triple power cycle featuring a gas turbine cycle with supercritical carbon dioxide and organic Rankine cycles: Thermoeconomic analysis and optimization

In this study, a novel triple power cycle is proposed where waste heat from a gas turbine cycle is utilized to drive a supercritical carbon dioxide (s-CO 2 ) recompression cycle and a recuperative organic Rankine cycle (ORC) in sequence. A detailed thermoeconomic model is developed and implemented in MATLAB to evaluate the performance of the proposed cycle under different operating conditions. Optimization using a particle swarm optimization (PSO) algorithm is performed to minimize the levelized cost of electricity (LCOE) and determine the optimum design conditions of the cycle. The optimization results show that for a 100 MW cycle, the overall thermal efficiency and LCOE are 0.521 and $\$52.819$/MWh, respectively. The turbine inlet temperature of the gas turbine and s-CO 2 cycles are found as the most influential parameters on the thermoeconomic performance of the triple cycle. The proposed triple cycle shows an excellent waste energy recovery potential and superiority over a very thermodynamically efficient cycle from the literature, which included a gas turbine topping cycle and a complex cascade s-CO 2 power cycle used a bottoming cycle. As a result, the proposed triple cycle shows up to 0.9% points higher efficiency while it has fewer heat exchangers and turbomachinery than the cycle from the literature.

30 DIRECT ENERGY CONVERSION↗

Cycle-to-Cycle Variations in Multi-Cycle Engine RANS Simulations

Reynolds-averaged Navier-Stokes (RANS) modeling is expected to deliver an ensemble-averaged result for the majority of turbulent flows. This could lead to the conclusion that multi-cycle internal combustion engine (ICE) simulations performed using RANS must exhibit a converging numerical solution after a certain number of consecutive cycles. However, for some engine configurations unsteady RANS simulations are not guaranteed to deliver an ensemble-averaged result. In this paper it is shown that, when using RANS modeling to simulate multiple engine cycles, the cycle-to-cycle variations (CCV) generated from different initial conditions at each cycle are not damped out even after a large number of cycles. A single-cylinder GDI research engine is simulated using RANS modeling and the numerical results for 20 consecutive engine cycles are evaluated for two specific operating conditions. One condition is characterized by stoichiometric operation and stable combustion (COVIMEP < 2%) and the other features dilute combustion resulting in misfire events and much higher COVIMEP. In both cases, multi-cycle RANS simulation results show cyclic variability. An in-depth analysis of the most significant physical and chemical quantities highlights that CCV are caused primarily by the variability of the in-cylinder flow. For stoichiometric combustion this does not greatly affect flame propagation, and the resulting fluctuations of the pressure traces are narrow. However, in the event of dilute combustion, the variability of the flow gains more importance, therefore delivering large cyclic fluctuations of in-cylinder pressure. Even though unsteady RANS simulations are not expected to predict as much variability in engine flows as LES, in particular for stable cases, they can still be used to capture typical combustion stability features in an internal combustion engine. This paper shows that the occurrence of CCV when using multi-cycle RANS modeling is not a numerical artifact or the effect of changes in the computational grid from cycle to cycle. Cold-flow analysis reveals that the variability of the simulated flow is intrinsic for the unsteady RANS approach and can only be damped out by increasing numerical viscosity, either by increasing the cell size or by adding up-winding. This is proved in a simplified non-ICE case such as the simulation of the vortex shredding from a cylinder in cross flow. Also, the effect of numerical viscosity on CCV is shown for multi-cycle engine simulations by using a simplified combustion model. Finally, it is shown that multi-cycle RANS can successfully predict the effect of changing specific engine parameters, such as the properties of the ignition system, on cyclic variability and combustion stability.

Scarcelli, Riccardo↗

Sunspot Activity Near Cycle Minimum and What it Might Suggest for Cycle 24, the Next Sunspot Cycle

In late 2008, 12-month moving averages of sunspot number, number of spotless days, number of groups, area of sunspots, and area per group were reflective of sunspot cycle minimum conditions for cycle 24, these values being of or near record value. The first spotless day occurred in January 2004 and the first new-cycle, high-latitude spot was reported in January 2008, although old-cycle, low-latitude spots have continued to be seen through April 2009, yielding an overlap of old and new cycle spots of at least 16 mo. New-cycle spots first became dominant over old-cycle spots in September 2008. The minimum value of the weighted mean latitude of sunspots occurred in May 2007, measuring 6.6 deg, and the minimum value of the highest-latitude spot followed in June 2007, measuring 11.7 deg. A cycle length of at least 150 mo is inferred for cycle 23, making it the longest cycle of the modern era. Based on both the maximum-minimum and amplitude-period relationships, cycle 24 is expected to be only of average to below-average size, peaking probably in late 2012 to early 2013, unless it proves to be a statistical outlier.

Wilson, Robert M.↗

Techno-economic analysis and life-cycle analysis of two light-duty bio-blendstocks: isobutanol and aromatic rich hydrocarbons

Isobutanol and aromatic-rich hydrocarbons (ARHC) are two biomass-derived high octane blendstocks that could be blended with petroleum gasoline for use in optimized spark-ignition engines in light-duty vehicles, potentially increasing engine efficiency. To evaluate technology readiness, economic viability, and environmental impacts of these technologies, we use detailed techno-economic analysis (TEA) and life-cycle analysis (LCA). We assumed isobutanol is produced via biochemical conversion of an herbaceous feedstock blend while ARHC is produced via thermochemical conversion of a woody feedstock blend.The minimum estimated fuel selling price (MFSP) of isobutanol ranged from $5.57/gasoline gallon equivalent (GGE) based on today’s technology to $4.22/GGE with technology advancements. The MFSP of ARHC could decline from $5.20/GGE based on today’s technology to $4.20/GGE as technology improves. Both isobutanol and ARHC offer about 73% GHG emission reduction relative to petroleum gasoline per LCA of these two bio-blendstocks. On the other hand, water consumption in the production of both bio-blendstocks exceeds that of conventional gasoline although process engineering offers routes to cutting water consumption. Over their life cycles, both isobutanol and ARHC emit more NOx and PM2.5 than petroleum gasoline.Improving the energy efficiency and lowering air emissions from agricultural equipment will reduce the life-cycle air pollutant emissions of these bio-blendstocks.

techno-economic analysis, life-cycle analysis, bio↗

Next-Cycle Optimal Dilute Combustion Control via Online Learning of Cycle-to-Cycle Variability Using Kernel Density Estimators

Dilute combustion using exhaust gas recirculation (EGR) presents a cost-effective method for increasing the efficiency of spark-ignition (SI) engines. However, the maximum amount of EGR that can be used at a given condition is limited by a rapid increment of cycle-to-cycle variability (CCV). This study describes a methodology to design a model-based stochastic optimal controller to adjust the cycle-to-cycle fuel injection quantity in order to reduce CCV and further extend the dilute limit. Given the complexity and chaotic nature of combustion events, the controller was enhanced with online learning in order to identify the statistical properties of combustion efficiency, which are needed to generate predictions for next-cycle events. This study showed that a kernel density estimator (KDE) can be used to learn the combustion properties in real time and can be incorporated into the feedback policy in order to calculate the optimal control command. Experimental results suggested that the dilute limit can be extended from 18.5% to 21% EGR fraction at an operating condition relevant for highway cruising. Additionally, the proposed controller can achieve a large CCV reduction with less fuel enrichment compared to previous methods, overall contributing to an increase in 0.2% indicated fuel conversion efficiency.

33 ADVANCED PROPULSION SYSTEMS↗

Genomic expansion of domain archaea highlights roles for organisms from new phyla in anaerobic carbon cycling.

Archaea represent a significant fraction of Earth's biodiversity, yet they remain much less well understood than Bacteria. Gene surveys, a few metagenomic studies, and some single-cell sequencing projects have revealed numerous little-studied archaeal phyla. Certain lineages appear to branch deeply and may be part of a major phylum radiation. The structure of this radiation and the physiology of the organisms remain almost unknown.We used genome-resolved metagenomic analyses to investigate the diversity, genomes sizes, metabolic capacities, and potential roles of Archaea in terrestrial subsurface biogeochemical cycles. We sequenced DNA from complex sediment and planktonic consortia from an aquifer adjacent to the Colorado River (USA) and reconstructed the first complete genomes for Archaea using cultivation-independent methods. To provide taxonomic context, we analyzed an additional 151 newly sampled archaeal sequences. We resolved two new phyla within a major, apparently deep-branching group of phyla (a superphylum). The organisms have small genomes, and metabolic predictions indicate that their primary contributions to Earth's biogeochemical cycles involve carbon and hydrogen metabolism, probably associated with symbiotic and/or fermentation-based lifestyles.The results dramatically expand genomic sampling of the domain Archaea and clarify taxonomic designations within a major superphylum. This study, in combination with recently published work on bacterial phyla lacking cultivated representatives, reveals a fascinating phenomenon of major radiations of organisms with small genomes, novel proteome composition, and strong interdependence in both domains.

Castelle, Cindy J↗

Cycle-to-cycle variability in spark-assisted compression ignition engines near optimal mean combustion phasing

Stoichiometric spark-assisted compression ignition (SACI) combustion with exhaust gas recirculation (EGR) dilution has demonstrated higher part-load thermal efficiencies compared to spark-ignited engines, while maintaining ultra-low tailpipe emissions. However, SACI is often characterized by high cyclic variability in heat release or torque output, which poses a challenge to its implementation in light-duty vehicles. This paper presents an experimental investigation of cyclic variability in stoichiometric SACI combustion under EGR-dilute conditions, while maintaining mean combustion phasing (θ 50 ) near optimal timing for thermal efficiency. The present work focuses on SACI conditions where the flame-based heat release fraction is between approximately 10% and 40% of the overall heat release, and therefore contributes significantly to the combustion process. For the SACI conditions examined, the variability in θ 50 was driven by variability in autoignition timing, which in turn correlated with the start of measurable heat release (θ 02 ). High variability in θ 50 caused unstable work output due to very late combustion with poor or no end-gas autoignition. The use of a high ignition energy dual-coil offset ignition system had negligible impact in reducing θ 50 variability. Analysis of experimental data from close to 1000 operating conditions showed that the magnitude of θ 50 variability correlates with the flame-based heat release fraction ([Formula: see text]), for a large range of intake pressures, spark timings and exhaust gas recirculation levels. For the SACI conditions examined, combustion phasing variability was largely determined by flame-based combustion and particularly the initial flame formation (θ IGN-02 ), and minimally by the end-gas autoignition heat release. The analysis also demonstrated that θ 50 variability is amplified as the contribution of the flame to the overall heat release increases.

Engineering↗

A lithium–oxygen battery with a long cycle life in an air-like atmosphere [Lithium-oxygen batteries with long cycle life in a realistic air atmosphere]

Lithium-air batteries are considered to be a potential alternative to lithium-ion batteries for transportation applications, owing to their high theoretical specific energy. So far, however, such systems have been largely restricted to pure oxygen environments (lithium oxygen batteries) and have a limited cycle life owing to side reactions involving the cathode, anode and electrolyte. In the presence of nitrogen, carbon dioxide and water vapour, these side reactions can become even more complex. Moreover, because of the need to store oxygen, the volumetric energy densities of lithium-oxygen systems may be too small for practical applications. Here we report a system comprising a lithium carbonate-based protected anode, a molybdenum disulfide cathode and an ionic liquid/di methyl sulfoxide electrolyte that operates as a lithium-air battery in a simulated air atmosphere with a long cycle life of up to 700 cycles. We perform computational studies to provide insight into the operation of the system in this environment. Furthermore this demonstration of a lithium-oxygen battery with a long cycle life in an air-like atmosphere is an important step towards the development of this field beyond lithium-ion technology, with a possibility to obtain much higher specific energy densities than for conventional lithium ion batteries.

25 ENERGY STORAGE↗

Predicting Cycle-to-cycle Variations in a Spark-ignition Engine using Multi-cycle Large Eddy Simulation

Multi-cycle large eddy simulation (LES) of a spark-ignition engine has been performed to predict cycle-to-cycle variations (CCV). To describe spark-ignited premixed flame propagation, the front propagation formulation (FPF) method is combined with a laminar-to-turbulent flame transition model that describes the non-equilibrium flame development processes during the initial stage of the kernel growth. In the laminar-to-turbulent flame transition model, the effects of turbulence on the variations in the laminar-to-turbulent flame transition time are modeled based on the Kolmogorov energy cascade. 15 consecutive cycle LES of in-cylinder processes in a spark-ignition four-valve single cylinder engine is conducted. The predicted in-cylinder pressure is compared with the experimental measurements. The range of CCV observed in the experiment is reproduced to an acceptable degree. The predicted CCV is found to be closely related to the difference in the turbu- lence field near the spark plug around the time of spark discharging, which is consistent with the previous LES studies. The current results also suggest the importance of capturing the variations of the laminar-to-turbulent flame transition in predicting CCV.

Su, Yunde↗

Predicting Cycle-to-cycle Variations in a Spark-ignition Engine using Multi-cycle Large Eddy Simulation

Multi-cycle large eddy simulation (LES) of a spark-ignition engine has been performed to predict cycle-to-cycle variations (CCV). To describe spark-ignited premixed flame propagation, the front propagation formulation (FPF) method is combined with a laminar-to-turbulent flame transition model that describes the non-equilibrium flame development processes during the initial stage of the kernel growth. In the laminar-to-turbulent flame transition model, the effects of turbulence on the variations in the laminar-to-turbulent flame transition time are modeled based on the Kolmogorov energy cascade. 15 consecutive cycle LES of in-cylinder processes in a spark-ignition four-valve single cylinder engine is conducted. The predicted in-cylinder pressure is compared with the experimental measurements. The range of CCV observed in the experiment is reproduced to an acceptable degree. The predicted CCV is found to be closely related to the difference in the turbulence field near the spark plug around the time of spark discharging, which is consistent with the previous LES studies. The current results also suggest the importance of capturing the variations of the laminar-to-turbulent flame transition in predicting CCV.

Yu, Yunde↗

An investigation of strain cycling behavior of 7075-T6 aluminum under combined state of strain: The effects of out-of-phase, biaxial strain cycling on low cycle fatigue

The effect of out-of-phase strain cycling on the low cycle fatigue of biaxially loaded specimens is discussed. A method to apply phase angles between two strains imposed in two different directions was developed. The data and the proposed theoretical analysis are part of a research program on biaxial strain cycling effect on fatigue life of structural materials.

Zamrik, S. Y.↗