Materials Data on CS2N by Materials Project
NS2C crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four NS2C clusters. there are two inequivalent C3+ sites. In the first C3+ site, C3+ is bonded in a distorted linear geometry to one N1+ and one S2- atom. The C–N bond length is 1.17 Å. The C–S bond length is 1.68 Å. In the second C3+ site, C3+ is bonded in a linear geometry to one N1+ and one S2- atom. The C–N bond length is 1.17 Å. The C–S bond length is 1.68 Å. There are two inequivalent N1+ sites. In the first N1+ site, N1+ is bonded in a single-bond geometry to one C3+ atom. In the second N1+ site, N1+ is bonded in a single-bond geometry to one C3+ atom. There are four inequivalent S2- sites. In the first S2- site, S2- is bonded in a distorted water-like geometry to one C3+ and one S2- atom. The S–S bond length is 2.12 Å. In the second S2- site, S2- is bonded in a water-like geometry to two S2- atoms. The S–S bond length is 2.02 Å. In the third S2- site, S2- is bonded in a water-like geometry to two S2- atoms. The S–S bond length is 2.11 Å. In the fourth S2- site, S2- is bonded in a water-like geometry to one C3+ and one S2- atom.