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At least 19 records

A new insight into neutrino energy loss by electron capture of iron group nuclei in magnetar surfaces

Based on the relativistic mean-field effective interactions theory, and the Lai dong model, we discuss the influences of superstrong magnetic fields (SMFs) on electron Fermi energy, nuclear blinding energy, and single-particle level structure in magnetar surfaces. Using the Shell-Model Monte Carlo method and the Random Phase Approximation theory, we analyze the neutrino energy loss rates (NELRs) by electron capture for iron group nuclei in SMFs. First, when B {sub 12} < 100, we find that the SMFs have a slight influence on the NELRs for most nuclides at relativistic low temperatures (e.g., T {sub 9} = 0.233); nevertheless, the NELRs increase by more than four orders of magnitude at relativistic high temperatures (e.g., T {sub 9} = 15.53). When B {sub 12} > 100, the NELRs decrease by more than three orders of magnitude (e.g., at T {sub 9} = 15.53 for {sup 52–61}Fe, {sup 55–60}Co, and {sup 56–63}Ni). Second, for a certain value of magnetic field and temperature, the NELRs increase by more than four orders of magnitude when ρ{sub 7}⩽10{sup 3}, but as the density increases (i.e., when ρ{sub 7}>10{sup 3}), there is almost no influence on the density of NELRs. For the density around ρ{sub 7}=10{sup 2}, there is an abrupt increase in NELRs when B {sub 12} ≥ 10{sup 3.5}. Such jumps are an indication that the underlying shell structure has changed due to single-particle behavior by SMFs. Finally, we compare our NELRs with those of Fuller et al. (FFN) and Nabi and Klapdor-Kleingrothaus (NKK). For the case without SMFs, one finds that our rates for certain nuclei are close to about five orders of magnitude lower than FFN and NKK at relativistic low temperatures (e.g., T {sub 9} = 1). However, at a relativistic high temperature (e.g., T {sub 9} = 3), our results are in good agreement with NKK, but about one order of magnitude lower than FFN. For the case with SMFs, our NELRs for some iron group nuclei can be about five orders of magnitude higher than those of FFN and NKK. (Note that B {sub 12}, T {sub 9}, and ρ {sub 7} are in units of 10{sup 12} G, 10{sup 9} K, and 10{sup 7} g cm{sup −3}, respectively.)

79 ASTRONOMY AND ASTROPHYSICS↗

Nuclear Data Sheets for A=59☆

-- Abstract: Evaluated spectroscopic data and level schemes from radioactive decay and nuclear reaction studies are presented for {sup 59}Sc, {sup 59}Ti, {sup 59}V, {sup 59}Cr, {sup 59}Mn, {sup 59}Fe, {sup 59}Co, {sup 59}Ni, {sup 59}Cu, {sup 59}Zn, {sup 59}Ga, and {sup 59}Ge. This evaluation for A=59 supersedes the earlier one by C. M. Baglin (2002Ba42) and updates for some nuclides in the ENSDF database. Highlights: of this evaluation are the following: In {sup 59}Fe, a new level at 568.45 keV (3/2{sup −}) has been added. This resolves a doublet at 570 keV, which was reflected in earlier evaluations (1983An22, 1993Ba85, 2002Ba42) and literature as well. Conflicting spin assignments for 2153.62 keV level of {sup 59}Co [9/2,13/2 in (α,pγ); (13/2) in ({sup 15}N,4nγ); 15/2 in (p,p′γ), (7/2{sup −}) in (n,n′γ)] exist in the literature and additional experimental work is needed to resolve the issue.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Determination of Phase Composition of Cobalt Nanoparticles Using {sup 59}Co Internal Field Nuclear Magnetic Resonance

It is well known that cobalt exhibits polymorphism, i.e., the co-existence of both the hcp and fcc phases. In particular, the method of synthesis and other thermodynamic conditions is known to play a crucial role in determining the particular phase of cobalt. In this work, we have compared the phase composition of the cobalt nanoparticles synthesized using two different solvents (water) and ethanol (Co@C). XRD measurements confirm the existence of fcc phase in commercial cobalt nanoparticles (Co@A), co-existence of fcc and hcp phases in Co@B, while the existence of the hcp phase in Co@C. We have studied these cobalt nanoparticles using {sup 59}Co internal field nuclear magnetic resonance (IFNMR) for verification of phase composition. Our studies reveal that the Co@A has fcc as a major phase with minor quantity hcp phase. Co@B exhibits approximately equal amount of fcc and hcp phase while Co@C exhibits hcp as a major phase with minor fcc phase. Our SEM micrograph studies confirm that the cobalt particles have spherical shape in the fcc phase. The cobalt particles exhibit both spherical and dendrite morphology confirming the co-existence of fcc and hcp phases, while the sample with pure hcp phase exhibits the dendrite morphology. Our studies also throw light on understanding the effect of solvent in the phase formation of the cobalt nanoparticles.

77 NANOSCIENCE AND NANOTECHNOLOGY↗

Mesoporous Co{sub 3}O{sub 4} nanostructured material synthesized by one-step soft-templating: A magnetic study

A combined magnetization and zero-field {sup 59}Co spin-echo nuclear magnetic resonance (NMR) study has been carried out on one member of a recently developed class of highly ordered mesoporous nanostructured materials, mesoporous Co{sub 3}O{sub 4} (designated UCT-8, University of Connecticut, mesoporous materials). The material was synthesized using one-step soft-templating by an inverse micelles packing approach. Characterization of UCT-8 by powder x-ray diffraction and electron microscopy reveals that the mesostructure consists of random close-packed Co{sub 3}O{sub 4} nanoparticles ≈ 12 nm in diameter. The N{sub 2} sorption isotherm for UCT-8, which is type IV with a type H1 hysteresis loop, yields a 134 m{sup 2}/g BET surface area and a 7.7 nm BJH desorption pore diameter. The effect of heat treatment on the structure is discussed. The antiferromagnetic Co{sub 3}O{sub 4} nanoparticles have a Néel temperature T{sub N} = 27 K, somewhat lower than the bulk. A fit to the Curie-Weiss law over the temperature range 75 K ≤ T ≤ 300 K yields an effective magnetic moment of μ{sub eff} = 4.36 μ{sub B} for the Co{sup 2+} ions, indicative of some orbital contribution, and a Curie-Weiss temperature Θ = −93.5 K, consistent with antiferromagnetic ordering. The inter-sublattice and intra-sublattice exchange constants for the Co{sup 2+} ions are J{sub 1}/k{sub B} = (−)4.75 K and J{sub 2}/k{sub B} = (−)0.87 K, respectively, both corresponding to antiferromagnetic coupling. The presence of uncompensated surface spins is observed below T{sub N} with shifts in the hysteresis loops, i.e., an exchange-bias effect. The {sup 59}Co NMR spectrum for UCT-8, which is attributed to Co{sup 2+} ions at the tetrahedral A sites, is asymmetrically broadened with a peak at ≈55 MHz (T = 4.2 K). Since there is cubic symmetry at the A-sites, the broadening is indicative of a magnetic field distribution due to the uncompensated surface spins. The spectrum is consistent with antiferromagnetically ordered particles that are nanometer in size and single domain.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Statistical properties of excited nuclei in the mass range 47 Less-Than-Or-Slanted-Equal-To A Less-Than-Or-Slanted-Equal-To 59

Level densities and their energy dependences for nuclei in the mass range of 47 {<=} A {<=} 59 were determined from the results obtained by measuring neutron-evaporation spectra in respective (p, n) reactions. The spectra of neutrons originating from the (p, n) reactions on {sup 47}Ti, {sup 48}Ti, {sup 49}Ti, {sup 53}Cr, {sup 54}Cr, {sup 57}Fe, and {sup 59}Co nuclei were measured in the proton-energy range of 7-11 MeV. These measurements were performed with the aid of a fast-neutron spectrometer by the time-of-flight method over the base of the EGP-15 pulsed tandem accelerator installed at the Institute for Physics and Power Engineering (Obninsk, Russia). A high resolution of the spectrometer and its stability in the time of flight made it possible to identify reliably discrete low-lying levels along with the continuum part of neutron spectra. Our measured data were analyzed within the statistical equilibrium and preequilibrium models of nuclear reactions. The respective calculations were performed with the aid of the Hauser-Feshbach formalismof statistical theory supplemented with the generalized model of a superfluid nucleus, the back-shifted Fermi gas model, and the Gilbert-Cameron composite formula for nuclear level densities. Nuclear level densities for {sup 47}V, {sup 48}V, {sup 49}V, {sup 53}Mn, {sup 54}Mn, {sup 57}Co, and {sup 59}Ni and their energy dependences were determined. The results are discussed and compared with available experimental data and with recommendations of model-based systematics.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

The Influence of Relative Content of a Metal Component in a Dielectric Matrix on the Formation and Dimensions of Cobalt Nanocrystallites in Co{sub x}(MgF{sub 2}){sub 100 –} {sub x} Film Composites

The influence of relative content of a metal component on the phase composition and substructure of Co{sub x}(MgF{sub 2}){sub 100 –} {sub x} in a wide range of x = 16–63 at % is studied by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS) and infrared (IR) spectroscopy. The layers of nanocomposite with a micron thickness have been obtained by the ion-beam sputtering of the target in the argon environment. The results reveal that the relative metal cobalt content in the MgF{sub 2} dielectric matrix strongly affects the phase composition and substructure of nanocomposites. With a lower content of cobalt, it is in the amorphous state in the form of clusters in the MgF{sub 2} nanocrystalline matrix. An increase of cobalt content to x = 29 at % on a sitall substrate and to x = 42 at % on a glass substrate in the X-ray amorphous MgF{sub 2} dielectric matrix leads to the formation of cobalt nanocrystals with a hexagonal crystallographic system, whose sizes are on the order of 10 nm. These are predominately oriented in the basis plane of the (001) hexagonal lattice of α-Со. A further increase of cobalt content to c = 59 at % enlarges the α-Со nanocrystals to ~20 nm with retaining the same orientation. In accordance with a fine structure analysis of XPS spectra of Со 2p and О 1s, cobalt is strongly oxidized on the surface of all the composites; only on the surface of samples with a low content of Co is X‑ray amorphous cobalt found in a metallic state along with cobalt oxide. The IR spectra of these samples with the lowest metal phase content exhibit the pronounced modes from the nanocrystalline MgF{sub 2} dielectric phase.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Thermal Cross Sections and Resonance Integrals for Ag{sup 109}(n,{gamma})Ag{sup 110m} and Several Other Reactions

In this paper measurements reported from the Rikkyo Research Reactor are reanalysed using a least squares adjustment procedure in which the adjustable parameters were the thermal and epithermal neutron fluences, the epithermal shape parameter and the thermal neutron cross sections and resonance integrals of all the dosimeters, including the gold and cobalt standards. The methodology and the results are described. Nuclear data including cross sections, recommended in ASTM Standard Test Method E 481, for the {sup 59}Co(n,{gamma}){sup 60}Co and Ag{sup 109}(n,{gamma})Ag{sup 110m} reactions were changed in a recent revision of the standard. The change for the silver thermal neutron cross section was very large compared to the previously cited uncertainties. The reference cited in the standard is the only new measurement that has been reported in many years. The value reported there for the 2200 m/s cross section is 4.12 {+-} 0.10 barn. This reevaluation adjusts that value to 3.87 {+-} 0.08 barn. The value in the previous edition of E481, however, was 4.7 barns {+-} 4%. Such a large change greatly affects the neutron fluence values that will be calculated. (author)

07 ISOTOPE AND RADIATION SOURCES↗

59 Co(p,X) spallation reaction cross sections for 250 MeV to 2 GeV protons

Cobalt is an advantageous target for probing the physics of nuclear spallation, because it is a naturally mono-isotopic element ( 59 Co), and its per-nucleon binding energy (BE/A = 8.768 MeV) is near the maximum value for all nuclei. We measured nuclear spallation cross sections for the 59 Co(p,X) reaction at five kinetic energies ranging from 250 MeV to 2 GeV. Cross sections for the production of 58 Co, 57 Co, 57 Mn, 56 Co, 56 Mn, 56 Cr, 55 Fe, 53 Fe, 54 Mn, 52 Mn, 51 Cr, 49 Cr, 48 V, 47 Sc, 46 Sc, 44 Sc, and 44 Scm are reported. Where comparable data exist in the EXFOR reaction database, we find that our measured cross sections generally agree. In many cases, we provide data for reactions or energies not currently reported in EXFOR. Our cross sections also provide evidence for the presence of α-clusters within the 59 Co nucleus, a surprising result given the asymmetry in Z (27) and N (32) for this nucleus. Finally, we use our measurements to evaluate the accuracy of spallation cross section simulations from GEANT4-based radiation transport toolkit, performed with the INCLXX-, Bertini-, and Binary-ion-cascade (BIC) based physics lists. This benchmarking activity revealed that the simulations overestimated the cross sections by a factor of ∼2–4 on average, and that the INCL-XX physics list provides the most reliable results. This evaluation informs the selection of the GEANT4 physics lists used for the analysis of data from NASA’s Psyche mission, which will measure γ rays and neutrons resulting from spallation reactions occurring on the surface of an asteroid whose surface is thought to be rich in iron-nickel metal.

43 PARTICLE ACCELERATORS↗

Proton Radiotherapy for Parameningeal Rhabdomyosarcoma: Clinical Outcomes and Late Effects

Purpose: To report the clinical outcome and late side effect profile of proton radiotherapy in the treatment of children with parameningeal rhabdomyosarcoma (PM-RMS). Methods and Materials: Seventeen consecutive children with PM-RMS were treated with proton radiotherapy at Massachusetts General Hospital between 1996 and 2005. We reviewed the medical records of all patients and asked referring physicians to report specific side effects of interest. Results: Median patient age at diagnosis was 3.4 years (range, 0.4-17.6). Embryonal (n = 11), alveolar (n = 4), and undifferentiated (n = 2) histologies were represented. Ten patients (59%) had intracranial extension. Median prescribed dose was 50.4 cobalt gray equivalents (GyRBE) (range, 50.4-56.0 GyRBE) delivered in 1.8-2.0-GyRBE daily fractions. Median follow-up was 5.0 years for survivors. The 5-year failure-free survival estimate was 59% (95% confidence interval, 33-79%), and overall survival estimate was 64% (95% confidence interval, 37-82%). Among the 7 patients who failed, sites of first recurrence were local only (n = 2), regional only (n = 2), distant only (n = 2), and local and distant (n = 1). Late effects related to proton radiotherapy in the 10 recurrence-free patients (median follow-up, 5 years) include failure to maintain height velocity (n = 3), endocrinopathies (n = 2), mild facial hypoplasia (n = 7), failure of permanent tooth eruption (n = 3), dental caries (n = 5), and chronic nasal/sinus congestion (n = 2). Conclusions: Proton radiotherapy for patients with PM-RMS yields tumor control and survival comparable to that in historical controls with similar poor prognostic factors. Furthermore, rates of late effects from proton radiotherapy compare favorably to published reports of photon-treated cohorts.

62 RADIOLOGY AND NUCLEAR MEDICINE↗

A bioinspired cobalt catalyst based on a tripodal imidazole/pyridine platform capable of water reduction and oxidation

The prototypical drug carrier [Co II (L 1 )Cl]PF 6 (1), where L 1 is a tripodal amine bound to pyridine and methyl-imidazoles, had its electrocatalytic water splitting activity studied under different pH conditions. This species contains a high-spin 3d 7 Co II metal center, and is capable of generating both H 2 from water reduction and O 2 from water oxidation. Turnover numbers reach 390 after 3 h for water reduction. Initial water oxidation activity is molecular, with TONs of 71 at pH 7 and 103 at pH 11.5. The results reveal that species 1 can undergo several redox transformations, including reduction to the 3d 8 Co I species that precedes a LS 3d 6 hydride for water reduction, as well as nominal Co IV $=$O and Co III -OOH species required for water oxidation. Finally, post-catalytic analyses confirm the molecular nature of reduction and support initial molecular activity for oxidation.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Possible quadrupole-order-driven commensurate-incommensurate phase transition in B20 CoGe

For this study, the B20-type cobalt germanide CoGe was investigated by measuring the specific heat, resistivity, and 59 Co nuclear magnetic resonance (NMR). We observed a phase transition at T Q = 13.7 K, evidenced by a very narrow peak of the specific heat and sharp changes of the nuclear spin-spin (T 2 –1 ) and spin-lattice ( T 1 – 1 ) relaxation rates. The fact that the entropy release is extremely small and the Knight shift is almost independent of temperature down to low temperatures as anticipated in a paramagnetic metal indicates that the T Q transition is of nonmagnetic origin. In addition, we detected a crossover scale T 0 ~ 30 K below which the resistivity and the NMR linewidth increase, and T 1 –1 is progressively distributed in space, that is, a static and dynamical spatial inhomogeneity develops. While the order parameter for the T Q transition remains an open question, a group-theoretical analysis suggests that the finite electric quadrupole density arising from the low local site symmetry at cobalt sites could drive the crystal symmetry lowering from the P2 1 3 symmetry that is commensurate to the R3 symmetry with an incommensurate wave vector, which fairly well accounts for the T Q transition. The quadrupole-order-driven commensurate-incommensurate phase transition may be another remarkable phenomenon arising from the structural chirality inherent in the noncentrosymmetric B20 family.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Reduced Cu–Co–Al Mixed Metal Oxides for the Ring-Opening of Furfuryl Alcohol to Produce Renewable Diols

In this study, the ring-opening of furfuryl alcohol to diol products, including 1,2-pentanediol and 1,5- pentanediol, is investigated over reduced Cu-Co-Al mixed metal oxides in a liquid phase batch reactor under H 2 pressure. These catalysts are synthesized through the calcination of layered double hydroxides (LDH) to yield well-dispersed, porous mixed metal oxides, which upon reduction displayed activity towards diols, mainly the valuable monomer 1,5-pentanediol. The addition of Cu facilitated the reduction of Co oxide species at lower temperatures, and under optimized conditions a yield towards 1,5-pentanediol of 44% (total diol yield of 62%) was achieved. Various characterization techniques including TPR, XPS, and XAS are employed to elucidate the structure of the catalysts, suggesting the formation of both metallic (Co and Cu) and oxide (CoO) species after reduction and passivation. Finally, this study demonstrates the promising characteristics that non-precious multi-metal catalysts have for the conversion of biomass derived platform molecules to plastic precursors

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

A cobalt mimochrome for photochemical hydrogen evolution from neutral water

Here, a system for visible light-driven hydrogen production from water is reported. This system makes use of a synthetic mini-enzyme known as a mimochrome (CoMC6*a) consisting of a cobalt deuteroporphyrin and two attached peptides as a catalyst, [Ru(bpy) 3 ] 2+ (bpy = 2,2'-bipyridine) as a photosensitizer, and ascorbic acid as a sacrificial electron donor. The system achieves turnover numbers (TONs) up to 10,000 with respect to catalyst and optimal activity at pH 7. Comparison with related systems shows that CoMC6*a maintains the advantages of biomolecular catalysts, while exceeding other cobalt porphyrins in terms of total TON and longevity of catalysis. Herein, we lay groundwork for future study, where the synthetic nature of CoMC6*a will provide a unique opportunity to tailor proton reduction chemistry and expand to new reactivity.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Nanoporous Co/Mn-Mixed Metal Oxides Templated via Polysulfones for Amine Oxidation

Herein, we report syntheses of microporous and mesoporous mixed metal oxides templated via an anionic surfactant. The effects of acid treatment, solvent type, and the amount of metal incorporation were investigated. Two different cobalt–manganese oxide spinels that were synthesized with surface areas as high as 137 m 2 /g were obtained. These nanomaterials indicate 3.8 nm monomodal pore sizes with crystallite sizes of 2.4–3.6 nm. 59 Co MASNMR studies have shown that quadrupole coupling values from 1500 to 5000 kHz with asymmetry values ranging from 0.1 to 1 have been used to identify cobalt oxidation states. Amine oxidation was used as a model reaction, which allowed for imide yields of above 90% from benzylamine homocoupling. Finally, the use of these nanoporous oxides allows for a high-yielding homocoupling of benzylamine.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

The influence of cobalt on the microstructure of the nickel-base superalloy MAR-M247

Nickel was substituted for Co to produce 0, 5, and the standard 10% versions of MAR-M247, a cast nickel-base superalloy. The microstructures of the alloys were examined in as-cast, heat treated, aged, and stress-rupture tested conditions using a variety of metallographic techniques and differential thermal analysis. As cobalt concentration was reduced from 10 to 0 wt %, the gamma-prime weight fraction decreased from 59 to 41%; W and Ti concentrations in the gamma-prime phase increased from 5 to 8 and 2 to 3 at.%, respectively; the mean gamma-prime particle size increased from 0.6 to 0.8 micron; Cr and Al concentrations in the gamma matrix decreased from 17 to 13 and 15 to 12 at.%, respectively; and the weight fraction of carbides increased by approximately 1%.

Nathal, M. V.↗

Thermal Decomposition of Bulk K-CoMoSx Mixed Alcohol Catalyst Precursors and Effects on Catalyst Morphology and Performance

Cobalt molybdenum sulfide-type mixed alcohol catalysts were synthesized via calcination of precipitated bulk sulfides and studied with temperature programmed decomposition analysis. Precursors containing aqueous potassium were also considered. Precipitates thermally decomposed in unique events which released ammonia, carbon dioxide, and sulfur. Higher temperature treatments led to more crystalline and less active catalysts in general with ethanol productivity falling from 203 to 97 g (kg cat){sup -1} h{sup -1} when the calcination temperature was increased from 375 to 500 C. The addition of potassium to the precursor led to materials with crystalline potassium sulfides and good catalytic performance. In general, less potassium was required to promote alcohol selectivity when added before calcination. At calcination temperatures above 350 C, segregated cobalt sulfides were observed, suggesting that thermally decomposed sulfide precursors may contain a mixture of molybdenum and cobalt sulfides instead of a dispersed CoMoS type of material. When dimethyl disulfide was fed to the precursor during calcination, crystalline cobalt sulfides were not detected, suggesting an important role of free sulfur during decomposition.

09 BIOMASS FUELS↗