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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 19 records
All sourcesNASA NTRSDOE OSTI
DOE OSTI2016

ASSESSMENT OF SYSTEMATIC CHROMATIC ERRORS THAT IMPACT SUB-1% PHOTOMETRIC PRECISION IN LARGE-AREA SKY SURVEYS

Meeting the science goals for many current and future ground-based optical large-area sky surveys requires that the calibrated broadband photometry is both stable in time and uniform over the sky to 1% precision or better. Past and current surveys have achieved photometric precision of 1%–2% by calibrating the survey’s stellar photometry with repeated measurements of a large number of stars observed in multiple epochs. The calibration techniques employed by these surveys only consider the relative frame-by-frame photometric zeropoint offset and the focal plane position-dependent illumination corrections, which are independent of the source color. However, variations in the wavelength dependence of the atmospheric transmission and the instrumental throughput induce source color-dependent systematic errors. These systematic errors must also be considered to achieve the most precise photometric measurements. In this paper, we examine such systematic chromatic errors (SCEs) using photometry from the Dark Energy Survey (DES) as an example. We first define a natural magnitude system for DES and calculate the systematic errors on stellar magnitudes when the atmospheric transmission and instrumental throughput deviate from the natural system. We conclude that the SCEs caused by the change of airmass in each exposure, the change of the precipitable water vapor and aerosol in the atmosphere over time, and the non-uniformity of instrumental throughput over the focal plane can be up to 2% in some bandpasses. We then compare the calculated SCEs with the observed DES data. For the test sample data, we correct these errors using measurements of the atmospheric transmission and instrumental throughput from auxiliary calibration systems. The residual after correction is less than 0.3%. Moreover, we calculate such SCEs for Type Ia supernovae and elliptical galaxies and find that the chromatic errors for non-stellar objects are redshift-dependent and can be larger than those for stars at certain redshifts.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2011

Chromatic analysis and possible local chromatic correction in RHIC

In this article we will answer the following questions for the RHIC polarized proton (p-p) and Au-Au run lattices: (1) what are the sources of second order chromaticities? (2) what is the dependence of second order chromaticity on the on-momentum {beta}-beat? (3) what is the dependence of second order chromaticity on {beta}* at IP6 and IP8? To answer these questions, we use the perturbation theory to numerically calculate the contributions of each quadrupole and sextupole to the first, second, and third order chromaticities. Possible local methods to reduce chromatic effects in RHIC ring are shortly discussed.

43 PARTICLE ACCELERATORS↗
DOE OSTI2012

Syntheses and crystal structures of two novel alkaline uranyl chromates A{sub 2}(UO{sub 2})(CrO{sub 4}){sub 2} (A=Rb, Cs) with bidentate coordination mode of uranyl ions by chromate anions

Single crystals of Cs{sub 2}(UO{sub 2})(CrO{sub 4}){sub 2} and Rb{sub 2}(UO{sub 2})(CrO{sub 4}){sub 2} were prepared by solid state reactions. The structures are based upon the [(UO{sub 2})(CrO{sub 4}){sub 2}]{sup 2-} chains. Within the chains, UrO{sub 5} pentagonal bipyramids (Ur=uranyl) form Ur{sub 2}O{sub 8} dimers, which are linked via CrO{sub 4} tetrahedra into one-dimensional chains. The CrO{sub 4} tetrahedra coordinate uranyl ions in both mono- and bidentate fashion, which is unusual for uranyl chromates. The bidentate coordination has a strong influence upon geometrical parameters of both U and Cr coordination polyhedra. The conformation of the chains in 1 and 2 is different due to the different size of the Cs{sup +} and Rb{sup +} cations. - Graphical abstract: Uranyl chromate chain with monodentate and bidentate coordination mode of uranyl cations by CrO{sub 4} tetrahedra in Cs{sub 2}(UO{sub 2})(CrO{sub 4}){sub 2}. Highlights: Black-Right-Pointing-Pointer Single crystals of novel uranyl chromates were prepared by solid state reactions. Black-Right-Pointing-Pointer The CrO{sub 4} tetrahedra coordinate uranyl ions in both mono- and bidentate fashion. Black-Right-Pointing-Pointer The bidentate coordination has a strong influence upon geometrical parameters.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2010

Crystal chemistry of thorium nitrates and chromates

The structures and infrared spectra of six novel thorium compounds are reported. Th(NO{sub 3}){sub 2}(OH){sub 2}(H{sub 2}O){sub 2} (1) crystallizes in space group C2/c, a=14.050(1), b=8.992(7), c=5.954(5) A, {beta}=101.014(2){sup o}. K{sub 2}Th(NO{sub 3}){sub 6} (2), P-3, a=13.606(1), c=6.641(6) A. (C{sub 12}H{sub 28}N){sub 2}Th(NO{sub 3}){sub 6} (3), P2{sub 1}/c, a=14.643(4), b=15.772(5), c=22.316(5) A, {beta}=131.01(1){sup o}. KTh(NO{sub 3}){sub 5}(H{sub 2}O){sub 2} (4), P2{sub 1}/c, a=10.070(8), b=12.731(9), c=13.231(8) A, {beta}=128.647(4){sup o}. Th(CrO{sub 4}){sub 2}(H{sub 2}O){sub 2} (5), P2{sub 1}/n, a=12.731(1), b=9.469(8), c=12.972(1) A, {beta}=91.793(2){sup o}. K{sub 2}Th{sub 3}(CrO{sub 4}){sub 7}(H{sub 2}O){sub 10} (6), Ama2, a=19.302(8), b=15.580(6), c=11.318(6) A. The coordination polyhedra about Th in these structures are diverse. Th is coordinated by 9 O atoms in 5 and 6, seven of which are from monodentate (CrO{sub 4}) tetrahedra and two are (H{sub 2}O). The Th in compound 1 is coordinated by ten O atoms, four of which are O atoms of two bidentate (NO{sub 3}) triangles and six of which are (OH) and (H{sub 2}O). In compounds 2, 3 and 4 the Th is coordinate by 12 O atoms. In 2 and 3 there are six bidentate (NO{sub 3}) triangles, and in 4 ten of the O atoms are part of five bidentate (NO{sub 3}) triangles and the others are (H{sub 2}O) groups. The structural units of these compounds consist of a chain of thorium and nitrate polyhedra (1), isolated thorium hexanitrate clusters (2, 3), an isolated thorium pentanitrate dihydrate cluster (4), and a sheet (6) and framework (5) of thorium and chromate polyhedra. These structures illustrate the complexity inherent in the crystal chemistry of Th. - Graphical Abstract: The structures and infrared spectra of four new Th nitrates and two Th chromates are reported. The coordination numbers of the Th cations range from nine to 12 in these compounds. Structural units consist of isolated clusters, chains, sheets and frameworks.

36 MATERIALS SCIENCE↗
DOE OSTI2015

Scattered hard X-ray and γ-ray generation from a chromatic electron beam

An array of photon diagnostics has been deployed on a high power relativistic electron beam diode. Electrons are extracted through a 17.8 cm diode from the surface discharge of a carbon fiber velvet cathode with a nominal diode voltage of 3.8 MV. <10% of the 100 ns electron pulse is composed of off energy electrons (1–3 MeV) accelerated during the rise and fall of the pulse that impact the stainless steel beam pipe and generate a Bremsstrahlung spectrum of 0.1–3 MeV photons with a total count of 10{sup 11}. The principal objective of these experiments is to quantify the electron beam dynamics and spatial dynamics of the hard X-ray and γ-ray flux generated in the diode region. A qualitative comparison of experimental and calculated results are presented, including time and energy resolved electron beam propagation and scattered photon measurements with X-ray PIN diodes and a photomultiplier tube indicating a dose dependence on the diode voltage >V{sup 4} and detected photon counts of nearly 10{sup 6} at a radial distance of 1 m which corresponds to dose ∼40 μrad at 1 m.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2019

Chromate Effect on Iodate Incorporation into Calcite

Incorporation of iodate into calcite (CaCO3) may be used as an in situ treatment strategy for radioiodine in contaminated soils and groundwater, but the presence of other contaminants can inhibit its efficiency. To this end, the potential for chromate to interfere with iodate incorporation into CaCO3 was investigated as an example of how co-located contaminants can impact in situ remediation efficacy. Here, batch precipitation experiments were periodically sub-sampled over 21 days to determine the kinetic effects of chromate on iodate removal and incorporation into calcite. From these experiments, a decrease in iodate removal from >60% to <40% was observed upon chromate addition (1 - 100 ppm chromate) and =11% of chromate was removed with a minor dependence on the initial chromate concentration. Analysis of the solid phase using extended X-ray absorption fine structure (EXAFS) spectroscopy informed by ab initio molecular dynamics simulations revealed that the iodate incorporation mode remains unchanged by the presence of chromate. Iodate readily substitutes for carbonate (CO32-) and the calcite structure is charge balanced primarily by substituting H+ for Ca2+. Furthermore, chromate incorporated as a nearest neighbor to iodate did not contribute to the EXAFS fit, therefore, iodate and chromate clustering is unlikely when co-incorporated into calcite.

Saslow, Sarah A.↗
DOE OSTI2020

NfoR: Chromate Reductase or Flavin Mononucleotide Reductase?

Soil bacteria can detoxify Cr(VI) ions by reduction. Within the last 2 decades, numerous reports of chromate reductase enzymes have been published. These reports describe catalytic reduction of chromate ions by specific enzymes. These enzymes each have sequence similarity to known redox-active flavoproteins. We investigated the enzyme NfoR from Staphylococcus aureus, which was reported to be upregulated in chromate-rich soils and to have chromate reductase activity (H. Han, Z. Ling, T. Zhou, R. Xu, et al., Sci Rep 7:15481, 2017, https://doi.org/10.1038/s41598-017-15588-y). We show that NfoR has structural similarity to known flavin mononucleotide (FMN) reductases and reduces FMN as a substrate. NfoR binds FMN with a dissociation constant of 0.4 μM. The enzyme then binds NADPH with a dissociation constant of 140 μM and reduces the flavin at a rate of 1,350 s -1 . Turnover of the enzyme is apparently limited by the rate of product release that occurs, with a net rate constant of 0.45 s -1 . The rate of product release limits the rate of observed chromate reduction, so the net rate of chromate reduction by NfoR is orders of magnitude lower than when this process occurs in solution. We propose that NfoR is an FMN reductase and that the criterion required to define chromate reduction as enzymatic has not been met. That NfoR expression is increased in the presence of chromate suggests that the survival adaption was to increase the net rate of chromate reduction by facile, adventitious redox processes.

59 BASIC BIOLOGICAL SCIENCES↗