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Determination of accurte rate constants for OH abstraction is of great importance for the calculation of lifetimes for HCFC and their impact on the atmosphere.
Physiological responses of animals exposed to ozone, carbon tetrafluoride, and nitrogen oxide
Aircraft sampling has provided extensive in situ and flask measurements of organic chlorine species in the lower stratosphere. The recent Airborne Arctic Stratospheric Expedition 2 (AASE 2) included two independent measurements of organic chlorine species using whole air sample and real-time techniques. From the whole air sample measurements we derive directly the burden of total organic chlorine (CCl(y)) in the lower stratosphere. From the more limited real-time measurements we estimate the CCl(y) burden using mixing ratios and growth rates of the principal CCl(y) species in the troposphere in conjunction with results from a two-dimensional photochemical model. Since stratospheric chlorine is tropospheric in origin and tropospheric mixing ratios are increasing, it is necessary to establish the average age of a stratospheric air parcel to assess its total chlorine (Cl(sub Total)) abundance. Total inorganic chlorine (Cl(y)) in the parcel is then estimated by the simple difference, Cl(y) = Cl(sub Total) - CCl(y). The consistency of the results from these two quite different techniques suggests that we can determine the CCl(y) and Cl(y) in the lower stratosphere with confidence. Such estimates of organic and inorganic chlorine are crucial in evaluating the photochemistry controlling chlorine partitioning and hence ozone loss processes in the lower stratosphere.
A theoretical analysis for estimating the extent of intestinal peptide and peptide analogue absorption was developed on the basis of a mass balance approach that incorporates convection, permeability, and reaction. The macroscopic mass balance analysis (MMBA) was extended to include chemical and enzymatic degradation. A microscopic mass balance analysis, a numerical approach, was also developed and the results compared to the MMBA. The mass balance equations for the fraction of a drug absorbed and reacted in the tube were derived from the general steady state mass balance in a tube: [formula: see text] where M is mass, z is the length of the tube, R is the tube radius, Pw is the intestinal wall permeability, kr is the reaction rate constant, C is the concentration of drug in the volume element over which the mass balance is taken, VL is the volume of the tube, and vz is the axial velocity of drug. The theory was first applied to the oral absorption of two tripeptide analogues, cefaclor (CCL) and cefatrizine (CZN), which degrade and dimerize in the intestine. Simulations using the mass balance equations, the experimental absorption parameters, and the literature stability rate constants yielded a mean estimated extent of CCL (250-mg dose) and CZN (1000-mg dose) absorption of 89 and 51%, respectively, which was similar to the mean extent of absorption reported in humans (90 and 50%). It was proposed previously that 15% of the CCL dose spontaneously degraded systematically; however, our simulations suggest that significant CCL degradation occurs (8 to 17%) presystemically in the intestinal lumen.(ABSTRACT TRUNCATED AT 250 WORDS).
Methods have been developed to identify and track tornado-producing mesoscale convective systems (MCSs) automatically over the continental United States, in order to facilitate systematic studies of these powerful and often destructive events. Several data sources were combined to ensure event identification accuracy. Records of watches and warnings issued by National Weather Service (NWS), and tornado locations and tracks from the Tornado History Project (THP) were used to locate MCSs in high-resolution precipitation observations and GOES infrared (11-micron) Rapid Scan Operation (RSO) imagery. Thresholds are then applied to the latter two data sets to define MCS events and track their developments. MCSs produce a broad range of severe convective weather events that are significantly affecting the living conditions of the populations exposed to them. Understanding how MCSs grow and develop could help scientists improve their weather prediction models, and also provide tools to decision-makers whose goals are to protect populations and their property. Associating storm cells across frames of remotely sensed images poses a difficult problem because storms evolve, split, and merge. Any storm-tracking method should include the following processes: storm identification, storm tracking, and quantification of storm intensity and activity. The spatiotemporal coordinates of the tracks will enable researchers to obtain other coincident observations to conduct more thorough studies of these events. In addition to their tracked locations, their areal extents, precipitation intensities, and accumulations all as functions of their evolutions in time were also obtained and recorded for these events. All parameters so derived can be catalogued into a moving object database (MODB) for custom queries. The purpose of this software is to provide a generalized, cross-platform, pluggable tool for identifying events within a set of scientific data based upon specified criteria with the possibility of storing identified events into a searchable database. The core of the application uses an implementation of the connected component labeling (CCL) algorithm to identify areas of interest, then uses a set of criteria to establish spatial and temporal relationships between identified components. The CCL algorithm is used for identifying objects within images for computer vision. This application applies it to scientific data sets using arbitrary criteria. The most novel concept was applying a generalized CCL implementation to scientific data sets for establishing events both spatially and temporally. The combination of several existing concepts (pluggable components, generalized CCL algorithm, etc.) into one application is also novel. In addition, how the system is designed, i.e., its extensibility with pluggable components, and its configurability with a simple configuration file, is innovative. This allows the system to be applied to new scenarios with ease.
Volume mixing ratio profiles of HCl, HOCl, ClNO3, CH3Cl, CFC-12, and CFC-11, CCl4, HCFC-22, and CFC-113 were measured simultaneously from 9 to 38 km by the Jet Propulsion Laboratory MkIV Fourier Transform Infrared solar absorption spectrometer during two balloon flights from Fairbanks, Alaska (64.8 N), on May 8 and July 8, 1997. The altitude variation of total organic chlorine (CCl(sub y)), total inorganic chlorine (Cl(sub y)), and the nearly constant value (3.7 +/- 0.2 ppbv) of their sum (Cl(sub TOT)) demonstrates that the stratospheric chlorine species available to react with O3 are supplied by the decomposition of organic chlorinated compounds whose abundances are well quantified. Measured profiles of HCl and ClNO3 agree well with profiles found by photochemical model (differences < 10% for altitudes below 35 km) constrained by various other constituents measured by MkIV. The production of HCl by ClO + OH plays a relatively small role in the partitioning of HCl and ClNO3 for the sampled air masses. However, better agreement with the measured profiles of HCl and ClNO3 is obtained when this source of HCl is included in the model. Both the measured and calculated [ClNO3]/[HCl] ratios exhibit the expected near linear variation with [O3](sup 2)/[CH4] over a broad range of altitudes. MkIV measurements of HCl, ClNO3, and CCl(sub y) agree well with ER-2 in situ observations of these quantities for directly comparable air masses. These results demonstrate good understanding of the budget of stratospheric chlorine and that the partitioning of inorganic chlorine is accurately described by photochemical models that employ JPL97 reaction rates and production of HCl from ClO + OH for the environmental conditions encountered: relatively warm temperatures, long periods of solar illumination, and relatively low aerosol surface areas.
Community-based Cooperative Separation Management (CSM) is expected to provide separation services in Upper Class E airspace (near and above FL600). Under CSM, operators are responsible for maintaining separation. The CSM concept is enabled by sharing Operational Intent (OI) among the operators to ensure common situation awareness. The OI is represented as four-dimensional (time and space) information that indicates where an aircraft would be contained within the space and time, with a known level of confidence. However, each vehicle’s ability to stay within its region of OI may differ based on each vehicle’s performance characteristics, resulting in varying OI sizes among the vehicles. Such varying OI size could adversely affect efficient and fair access to the airspace. In this paper, an OI-generation algorithm under varying OI size restriction with Containment Confidence Level (CCL) is presented. High-Altitude Long Endurance (HALE) balloon operations are used as an example application. A framework is presented by which CCL information is used in the deconfliction process. A fast-time simulation experiment is conducted to evaluate the feasibility of the proposed framework. The simulation results show a reduced number of unnecessary deconfliction actions.
Community-based Cooperative Separation Management (CSM) is expected to provide separation services in Upper Class E airspace (near and above FL600). Under CSM, operators are responsible for maintaining separation. The CSM concept is enabled by sharing Operational Intent (OI) among the operators to ensure common situation awareness. The OI is represented as four-dimensional (time and space) information that indicates where an aircraft would be contained within the space and time, with a known level of confidence. However, each vehicle’s ability to stay within its region of OI may differ based on each vehicle’s performance characteristics, resulting in varying OI sizes among the vehicles. Such varying OI size could adversely affect efficient and fair access to the airspace. In this paper, an OI-generation algorithm under varying OI size restriction with Containment Confidence Level (CCL) is presented. High-Altitude Long Endurance (HALE) balloon operations are used as an example application. A framework is presented by which CCL information is used in the deconfliction process. A fast-time simulation experiment is conducted to evaluate the feasibility of the proposed framework. The simulation results show a reduced number of unnecessary deconfliction actions.
The objective of this program is to observe the interface shape in single and multicomponent systems at the onset of critical wetting in microgravity using the MSFC drop tower and KC-135 aircraft. Test cells for the drop facility were built and tested up to critical point of CCl. Low temperature drops were conducted for two-component systems near the critical consolute point. Contact angle seems to approach 90 deg near the critical consolute temperature contrary to expectations. It is suspected that since the interfacial energy becomes vanishingly small at the critical consolute temperature, the interface shape has not reached equilibrium in the available low-gravity time.
This study is concerned with the difficulties encountered by casual users wishing to employ Information Storage and Retrieval Systems. A casual user is defined as a professional who has neither time nor desire to pursue in depth the study of the numerous and varied retrieval systems. His needs for on-line search are only occasional, and not limited to any particular system. The paper takes a close look at the state of the art of research concerned with aiding casual users of Information Storage and Retrieval Systems. Current experiments such as LEXIS, CONIT, IIDA, CITE, and CCL are presented and discussed. Comments and proposals are offered, specifically in the areas of training, learning and cost as experienced by the casual user. An extensive bibliography of recent works on the subject follows the text.
The NASA Lewis Research Center, located in Cleveland, Ohio has a number of space chemical propulsion test facilities which constitute a significant national space testing resource. The purpose of this paper is to make more users aware of these test facilities and to encourage their use through cooperative agreements between the government, industry, and universities. Research which is of interest to the government is especiallly encouraged and often can be done in a cooperative manner that best uses the resources of all parties. This paper presents an overview of the Lewis test facilities. These facilities are clustered into three test areas: the Rocket Engine Test Facilities (RETF), the Rocket Laboratory (RL), and the Cryogenic Components Laboratory (CCL).
It has been about six years since any cryogenic seal tests were run at NASA GRC (Glenn Research Center). The Cryogenic Components Lab, where the cryogenic seal test rigs are located, has been shutdown due to the impending expansion of the Cleveland Hopkins International Airport. The current plan is to move the Cryogenic Components Lab (CCL), Cells I and 2 to NASA Plumbrook in Sandusky, Ohio. The purpose of this presentation is to inform the seal community of the cryogenic seal test rig capabilities available at NASA GRC for planning of future programs.
This paper will explore the ability of printed circuit boards laminated with a Carbon Core Laminate to transfer heat vs. standard printed circuit boards that use only thick layers of copper. The paper will compare the differences in heat transfer performance of printed circuit boards with and without CCL.
The presentation includes general description on the following test facilities: Fuel Cell Testing Lab, Structural Dynamics Lab, Thermal Vacuum Test Facilities - including a description of the proposed Kinetic High Altitude Simulator concept, EMI Test Lab, and the Creek Road Cryogenic Complex - specifically the Small Multi-purpose Research Facility (SMiRF) and the Cryogenics Components Lab 7 (CCL-7).