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ClCCN crystallizes in the orthorhombic Ibam space group. The structure is zero-dimensional and consists of eight akos006376967 molecules. C2+ is bonded in a water-like geometry to one N3- and one Cl1- atom. The C–N bond length is 1.31 Å. The C–Cl bond length is 2.15 Å. N3- is bonded in a water-like geometry to two equivalent C2+ atoms. Cl1- is bonded in a 2-coordinate geometry to two equivalent C2+ atoms.
ClCCN crystallizes in the orthorhombic Ibam space group. The structure is two-dimensional and consists of two ClCCN sheets oriented in the (0, 1, 0) direction. C2+ is bonded in a single-bond geometry to one N3- atom. The C–N bond length is 1.25 Å. N3- is bonded in a linear geometry to two equivalent C2+ and four equivalent Cl1- atoms. There are a spread of N–Cl bond distances ranging from 3.07–3.16 Å. Cl1- is bonded in a rectangular see-saw-like geometry to four equivalent N3- atoms.