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At least 19 records
All sourcesNASA NTRSDOE OSTI
NASA NTRS1993

C-O volatiles in Apollo 15 and Apollo 17 picritic glasses

A15 and A17 primitive picritic glasses have been examined by FTIR for the presence of dissolved C-O species to determine the role of C-O gasses on driving lunar fire-fountains. A15 green and yellow glasses were extensively studied and found to be free of dissolved C species down to FTIR detection limits (10-100 ppm; species and sample specific). Preliminary data on A17 orange glasses are similarly devoid of FTIR detectable C-O species. Re-analyses of the C-O driving mechanism theory for mare volcanism demonstrates the need to determine the fO2 of the lunar interior; the factor that most critically determined the role of C gasses in the fire-fountaining events. Oxygen fugacities equivalent to IW-0.5 and above imply dissolved CO3(=) in the primitive glasses at levels above FTIR detection. The f02's below IW-0.5 imply concentrations of CO3(=) below FTIR detection. Recent data suggesting lunar mantle fO2's of IW-2 or less, strongly mitigate against finding FTIR measurable dissolved CO3(=) consistent with the findings of this study.

Rutherford, Malcolm J.↗
NASA NTRS1983

Condensation of solids in space. Isotope fractionation in the model system C-O

The reported chemical fractionation of a single isotope O-16 under simulated space conditions provides the first experimental proof for the hypothesis that the oxygen isotopic anomaly (and other similar anomalies) seen in meteorites is a product of chemical fractionation in interstellar or circumstellar space. Work proposed on this subject was discontinued because a peer review determined that such effects could not possibly exist and that continued support of this project would be a wasted effort. A bibliography is included of articles generated during research in this area.

Arrhenius, G.↗
NASA NTRS1978

Solid state photochemistry of polycarbonates

The quantum yield of photoFries rearrangement in a polycarbonate film has been analyzed as a function of temperature and humidity on the basis of previously reported (Koyler and Mann, 1977) experimental data. Results indicate that in the homogeneous amorphous phase, photoFries rearrangement is a concerted process proceeding either from the pi star reversed arrow n singlet, in which case it must be subject to considerable self quenching, or from a triplet, presumably the first triplet since the lifetime of higher triplets is expected to be very short in the solid phase. If the parent excited state is the first triplet, chain scission is possibly an independent process, probably occurring from the pi star reversed arrow n singlet. Evidence of chain scission on photodegradation in the solid state includes loss of C-O and C-C bond intensities revealed in the Fourier transform infrared spectra, gel permeation chromotography elution profiles of degraded film samples dissolved in CHCl3, and a decrease in tensile strength and T sub g as photodegradation proceeds. Chain scission is apparently inhibited as photoFries products accumulate.

Gupta, A.↗
NASA NTRS1984

Numerical simulation of the tip vortex off a low-aspect-ratio wing at transonic speed

The viscous transonic flow around a low aspect ratio wing was computed by an implicit, three dimensional, thin-layer Navier-Stokes solver. The grid around the geometry of interest is obtained numerically as a solution to a Dirichlet problem for the cube. A low aspect ratio wing with large sweep, twist, taper, and camber is the chosen geometry. The topology chosen to wrap the mesh around the wing with good tip resolution is a C-O type mesh. The flow around the wing was computed for a free stream Mach number of 0.82 at an angle of attack of 5 deg. At this Mach number, an oblique shock forms on the upper surface of the wing, and a tip vortex and three dimensional flow separation off the wind surface are observed. Particle path lines indicate that the three dimensional flow separation on the wing surface is part of the roots of the tip vortex formation. The lifting of the tip vortex before the wing trailing edge is observed by following the trajectory of particles release around the wing tip.

Mansour, N. N.↗
NASA NTRS1984

Numerical simulation of the tip vortex off a low-aspect-ratio wing at transonic speed

The viscous transonic flow around a low-aspect-ratio wing has been computed using an implicit, three-dimensional, 'thin-layer' Navier-Stokes solver. The grid around the geometry of interest is obtained numerically as a solution to a Dirichlet problem for the cube. The geometry chosen for this study is a low-aspect-ratio wing with large sweep, twist, taper, and camber. The topology chosen to wrap the mesh around the wing with good tip resolution is a C-O type mesh. Using this grid, the flow around the wing was computed for a free-stream Mach number of 0.82 at an angle of attack of 5 deg. At this Mach number, an oblique shock forms on the upper surface of the wing, and a tip vortex and three-dimensional flow separation off the wing surface are observed. Particle path lines indicate that the three-dimensional flow separation on the wing surface is part of the roots of the tip-vortex formation. The lifting of the tip vortex before the wing trailing edge is clearly observed by following the trajectory of particles released around the wing tip.

Mansour, N. N.↗
NASA NTRS1985

Ultraviolet spectral evolution and heavy element abundances in Nova Austrinae 1981

Nova CrA 1981, a moderately fast galactic nova, was systematically observed over a period of seven months with the IUE satellite. The initial evolution of the UV spectrum was similar to that of previously observed novae; however, several months after maximum, weak emission due to very high ionizating forbidden lines of Na, Mg, Al, and Si appeared, eventually decreasing in strength over the next two months. The spectral development of the lines is consistent with the photoionization of an expanding shell; a high-temperature 'coronal' origin is ruled out. Abundances deduced from the spectra show that most of the observed heavy elements in the ejected material are enhanced with respect to helium, with neon the most abundant of these. In addition, there are substantial deviations of the Na/Mg/Al/Si abundance ratios from solar values. This is interpreted as evidence for the mixing of core material with the accreted envelope on a massive O-Ne-Mg (as opposed to a C-O) white dwarf. Furthermore, the proportion of core material in the ejecta implies that the mass of the white dwarf decreased as a consequence of the outburst.

Williams, R. E.↗
NASA NTRS1985

On the similarity and differences for N2 and CO on Ni

The computed dipole derivatives for the N-N and C-O stretches are found to be quite similar, while the Ni-N derivative is much larger than for the corresponding Ni-C stretch; this is in agreement with experiment. A constrained space orbital variation (CSOV) analysis shows shows that the NiN2 bonding is more similar to that in NiCO than was concluded based upon the experimental dipole derivatives and binding energy shifts.

Bauschlicher, C. W., Jr.↗
NASA NTRS1989

A multigrid and upwind viscous flow solver on 3-D embedded and overlapped grids

A numerically efficient method is presented for solving the three-dimensional governing equations of the viscous compressible flow about complex configurations with topologically different components. The physical domain is decomposed into regions for which the grid generation is relatively simple and virtually with no significant restrictions. The Navier-Stokes equations are solved by an implicit, approximately factored, upwind, finite-volume scheme. The block inversions and the diagonalized scalar inversions of the coefficient matrices are modified to allow the holes created in the computational domain by the embedded and overlapped grids. The convergence is accelerated by a multigrid algorithm despite the existence of such holes. The solution for s supersonic flow past a blunt-nose-cylinder at high angle-of-attack is obtained using a C-O grid embedded in a global Cartesian grid.

Baysal, Oktay↗
NASA NTRS1990

Relative efficiency and accuracy of two Navier-Stokes codes for simulating attached transonic flow over wings

In the present study, two codes which solve the three-dimensional Thin-Layer Navier-Stokes (TLNS) equations are used to compute the steady-state flow for two test cases representing typical finite wings at transonic conditions. Several grids of C-O topology and varying point densities are used. After a description of each code and test case, standards for determining code efficiency and accuracy are defined and applied to determine the relative performance of the two codes in predicting turbulent transonic wing flows. Comparisons of computed surface pressure distributions with experimental data are made.

Bonhaus, Daryl L.↗
NASA NTRS1991

Relative efficiency and accuracy of two Navier-Stokes codes for simulating attached transonic flow over wings

Two codes which solve the 3-D Thin Layer Navier-Stokes (TLNS) equations are used to compute the steady state flow for two test cases representing typical finite wings at transonic conditions. Several grids of C-O topology and varying point densities are used to determine the effects of grid refinement. After a description of each code and test case, standards for determining code efficiency and accuracy are defined and applied to determine the relative performance of the two codes in predicting turbulent transonic wing flows. Comparisons of computed surface pressure distributions with experimental data are made.

Bonhaus, Daryl L.↗
NASA NTRS1991

Transonic Navier-Stokes flow computations over wing-fuselage geometries

The steady-state transonic viscous flows over two wing-fuselage configurations are solved numerically. The 3D compressible thin-layer Navier-Stokes equations are solved by means of multistage timestepping similar to the Runge-Kutta method. The timestepping technique is applied with a multigrid scheme to make the transonic Navier-Stokes computations using the Baldwin-Lomax turbulence for closure and converging the solution on a grid of 1.52 million grid points with a C-O topology. Both generic and fighter wing-fuselage geometries are solved, and the results are compared to experimental studies. Solution convergence is found to be fast, and the fine grid generates accurate results for both configurations by means of the Baldwin-Lomax turbulence model. Results from the Johnson-King model calculations produce results that are more consistent with experimental results for the fighter configuration.

Agrawal, S.↗
NASA NTRS1991

10 micron spectra of protostars and the solid methanol abundance

A search has been made for the strong C-O stretching absorption of solid methanol near 9.8 microns toward the heavily obscured protostars AFGL 961, AFGL 2591, the BN object and Mon R2 IRS 3. There is no clear evidence for this feature in the spectra, resulting in very conservative upper limits to the methanol abundance of 6 percent to 17 percent relative to solid H2O toward these objects. This is well below previous estimates of 50-80 percent obtained toward W33 A, NGC 7538 IRS 9, AFGL 2136, and W3 IRS 5, which were based on the assignment of the interstellar 6.85 microns absorption feature to the methanol C-H bending mode. This study shows that such high methanol abundances are not a characteristic of all interstellar ices.

Schutte, W. A.↗
NASA NTRS1992

Theoretical study of the bond dissociation energies of methanol

A theoretical study of the bond dissociation energies for H2O and CH3OH is presented. The C-H and O-H bond energies are computed accurately with the modified coupled-pair functional method using a large basis set. For these bonds, an accuracy of +/- 2 kcal/mol is achieved, which is consistent with the C-H and C-C single bond energies of other molecules. The C-O bond is much more difficult to compute accurately because it requires higher levels of correlation treatment and more extensive one-particle basis sets.

Bauschlicher, Charles W., Jr.↗
NASA NTRS1992

Computation of vortex wake flows and control of their effects on trailing wings

The near-vortex-wake flow of a large aspect-ratio rectangular wing is accurately computed by using the thin-layer and full Navier-Stokes (NS) equations. The chordwise section of the wing is a NACA-0012 airfoil and its tip is round. The computations have been carried out on a fine C-O grid using an implicit, upwind, flux-difference splitting, finite-volume scheme. The thin-layer NS results have been obtained with and without flux limiters, and the full NS results have been obtained without flux limiters. Flow transition from laminar to turbulent is mimicked by turning-on the Baldwin-Lomax algebraic model at an experimentally prescribed chord-station location of 0.05. Comparison of computed results and experimental data shows that the full NS results give the best resolution of the near-vortex-wake flow. Next, the strength of the wing-tip vortex has been reduced substantially without reducing the lift coefficient by using flow-injection from a slot along a portion of the wing tip. The flow injection is directed in the wing plane at 45 deg with the wing-tip chord.

Wong, Tin-Chee↗
NASA NTRS1993

Identification and yield of carbonic acid and formaldehyde in irradiated ices

Carbonic acid, (OH)2CO, was tentatively identified in the IR spectrum of a proton irradiated CO2 + H2O ice mixture. In this report, we present additional evidence for a more definitive identification of (OH)2CO with (1) the infrared spectrum of a residue obtained by proton irradiation of CO2 + D2O ice mixture, and (2) the IR spectra of solid phases of formaldehyde (H2CO), acetone (CH3)2CO, and dimethyl carbonate (OCH3)2CO, which are structurally similar to (OH)2CO. IR characteristics (peak frequencies and complex refractive indices of the compounds in point 2) are also reported. In particular, the integrated absorption coefficients for the C-O band for the compounds in point 2 do not vary by more than 20 percent. Based on these values, we estimate the yields of H2CO and (OH)2CO by proton irradiation or ice mixtures. Both H2CO and (OH)2CO are possible irradiation products of cometary and planetary ices.

Dellorusso, Neil↗
NASA NTRS1994

Experimental study of lunar and SNC (Mars) magmas

The overall objectives of this research were to evaluate the role of C-O-S-Cl degassing processes in explaining vesiculation, oxidation state and fire-fountaining of lunar magmas by analysis of individual lunar glass spherules, and by experimental determination of equilibrium abundances and diffusion rates of C, S and Cl melt species in lunar glass compositions; and to determine possible primitive SNC magma compositions and the mineralogy of the mantle from which they were derived, and to evaluate P, T, XH2O etc. conditions at which they crystallize to form the SNC meteorites. After funding for one year, a project on the A15 volcanic green glass has been completed to the point of writing a first manuscript. Carbon-oxygen species C-O and CO2 are below detection limits (20 ppm) in these glasses, but there is up to 500 ppm S with concentrations both increasing and decreasing toward the spherule margins. Calculations and modeling indicate that C species could have been present in the volcanic gases, however. In a second project, experiments with low PH2O have resulted in refined estimates of the early intercumulus melt composition in the Chassigny meteorite which is generally accepted as a sample from Mars.

Rutherford, Malcolm J.↗