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Effect of pore pressure on the velocity of compressional waves in low-porosity rocks.

The velocity V sub p of compressional waves has been measured in rock samples of low porosity to confining pressures P sub c of 2 kb for a number of different constant pore pressures P sub p. An effective pressure defined by P sub e = P sub c-nP sub p, n less than or equal to 1, is found to be the determining factor in the behavior of V sub p rather than an effective pressure defined simply by the differential pressure Delta P = P sub c-P sub p. As pore pressure increases at constant effective pressure, the value of n increases and approaches 1, but as effective pressure increases at constant pore pressure, the value of n decreases. These observations are consistent with Biot's theory of the propagation of elastic waves in a fluid-saturated porous solid.

Todd, T.↗

Materials Data on NpC by Materials Project

NpC is Halite, Rock Salt structured and crystallizes in the cubic Fm-3m space group. The structure is three-dimensional. Np4+ is bonded to six equivalent C4- atoms to form a mixture of edge and corner-sharing NpC6 octahedra. The corner-sharing octahedral tilt angles are 0°. All Np–C bond lengths are 2.48 Å. C4- is bonded to six equivalent Np4+ atoms to form a mixture of edge and corner-sharing CNp6 octahedra. The corner-sharing octahedral tilt angles are 0°.

36 MATERIALS SCIENCE↗

Materials Data on Np2C3 by Materials Project

Np2C3 is Plutonium carbide structured and crystallizes in the cubic I-43d space group. The structure is three-dimensional. Np3+ is bonded in a 6-coordinate geometry to six equivalent C2- atoms. There are three shorter (2.44 Å) and three longer (2.53 Å) Np–C bond lengths. C2- is bonded to four equivalent Np3+ and one C2- atom to form a mixture of distorted corner and edge-sharing CNp4C trigonal bipyramids. The C–C bond length is 1.42 Å.

36 MATERIALS SCIENCE↗