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Evidence for Surface and Subsurface Ice Inside Micro Cold-Traps on Mercury's North Pole

The small obliquity of Mercury causes topographic depressions located near its poles to cast persistent shadows. Many [1, 9, 15] have shown these permanently shadowed regions (PSRs) may trap water ice for geologic time periods inside cold-traps. More recently, direct evidence for the presence of water ice deposits inside craters was remotely sensed in RADAR [5] and visible imagery [3]. Albedo measurements (reflectence at 1064 nm) obtained by the MErcury Space ENviroment GEochemistry and Ranging Laser Altimeter (MLA) found unusually bright and dark areas next to Mercury's north pole [7]. Using a thermal illumination model, Paige et al. [8] found the bright deposits are correlated with surface cold-traps, and the dark deposits are correlated with subsurface cold-traps. They suggested these anomalous deposits were brought to the surface by comets and were processed by the magnetospheric radiation flux, removing hydrogen and mixing C-N-O-S atoms to form a variety of molecules which will darken with time. Here we use a thermal illumination model to find the link between the cold-trap area fraction of a rough surface and its albedo. Using this link and the measurements obtained by MESSENGER we derive a surface and a subsurface ice distribution map on Mercury's north pole below the MESSENGER spatial resolution, approximately 500 m. We find a large fraction of the polar ice on Mercury resides inside micro cold-traps (of scales 10 - 100 m) distributed along the inter-crater terrain.

Laser Altimeter↗

Materials Data on CSNO3 by Materials Project

CNSO3 is beta Polonium structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four CNSO3 clusters. C3+ is bonded in a distorted bent 120 degrees geometry to one N5+ and one O2- atom. The C–N bond length is 1.29 Å. The C–O bond length is 1.31 Å. N5+ is bonded in a water-like geometry to one C3+ and one S2- atom. The N–S bond length is 1.65 Å. S2- is bonded in a distorted tetrahedral geometry to one N5+ and three O2- atoms. There are a spread of S–O bond distances ranging from 1.42–1.84 Å. There are three inequivalent O2- sites. In the first O2- site, O2- is bonded in a water-like geometry to one C3+ and one S2- atom. In the second O2- site, O2- is bonded in a single-bond geometry to one S2- atom. In the third O2- site, O2- is bonded in a single-bond geometry to one S2- atom.

36 MATERIALS SCIENCE↗

Materials Data on CS2N2O by Materials Project

CO(NS)2 crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four 1,3,5,7,2,4,6,8-tetrathiatetrazocane molecules and eight formaldehyde molecules.

36 MATERIALS SCIENCE↗

Materials Data on CS(NO)2 by Materials Project

CN2SO2 crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four cyanamide molecules and four sulfur dioxide molecules.

36 MATERIALS SCIENCE↗