Materials Data on Ho2Re2Si2C by Materials Project
Ho2Re2Si2C crystallizes in the monoclinic C2/m space group. The structure is three-dimensional. Ho3+ is bonded in a 2-coordinate geometry to five equivalent Si4- and two equivalent C4- atoms. There are a spread of Ho–Si bond distances ranging from 3.01–3.14 Å. Both Ho–C bond lengths are 2.62 Å. Re3+ is bonded in a single-bond geometry to three equivalent Si4- and one C4- atom. There are two shorter (2.45 Å) and one longer (2.48 Å) Re–Si bond lengths. The Re–C bond length is 1.94 Å. Si4- is bonded in a 9-coordinate geometry to five equivalent Ho3+, three equivalent Re3+, and one Si4- atom. The Si–Si bond length is 2.53 Å. C4- is bonded to four equivalent Ho3+ and two equivalent Re3+ atoms to form edge-sharing CHo4Re2 octahedra.
36 MATERIALS SCIENCE↗