Materials Data on PCF3 by Materials Project
F3CP crystallizes in the tetragonal P4_2/nmc space group. The structure is zero-dimensional and consists of eight schembl16016218 molecules. C2- is bonded in a distorted bent 120 degrees geometry to one P5+ and one F1- atom. The C–P bond length is 1.81 Å. The C–F bond length is 1.32 Å. P5+ is bonded in a 3-coordinate geometry to one C2- and two equivalent F1- atoms. Both P–F bond lengths are 1.61 Å. There are two inequivalent F1- sites. In the first F1- site, F1- is bonded in a single-bond geometry to one P5+ atom. In the second F1- site, F1- is bonded in a single-bond geometry to one C2- atom.
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