Materials Data on MgC2S2(OF3)2 by Materials Project
Mg(SO)2(CF3)2 crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four fluoroform molecules and two Mg(SO)2 clusters. In each Mg(SO)2 cluster, Mg2+ is bonded in a linear geometry to two equivalent O2- atoms. Both Mg–O bond lengths are 1.91 Å. S is bonded in a distorted single-bond geometry to one O2- atom. The S–O bond length is 1.56 Å. O2- is bonded in a bent 150 degrees geometry to one Mg2+ and one S atom.
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