Materials Data on PrCo(CN)6 by Materials Project
PrCo(CN)6 crystallizes in the hexagonal P6_3/mmc space group. The structure is three-dimensional. Pr3+ is bonded in a distorted pentagonal pyramidal geometry to six equivalent N3- atoms. All Pr–N bond lengths are 2.49 Å. Co1+ is bonded in a distorted octahedral geometry to six equivalent C+2.33+ atoms. All Co–C bond lengths are 1.86 Å. C+2.33+ is bonded in a distorted linear geometry to one Co1+ and one N3- atom. The C–N bond length is 1.17 Å. N3- is bonded in a linear geometry to one Pr3+ and one C+2.33+ atom.
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