Materials Data on CsCo(CO)4 by Materials Project
CsCo(CO)4 crystallizes in the tetragonal I-4 space group. The structure is three-dimensional. Cs1+ is bonded in a 4-coordinate geometry to four equivalent O2- atoms. All Cs–O bond lengths are 3.24 Å. Co1+ is bonded in a tetrahedral geometry to four equivalent C+1.50+ atoms. All Co–C bond lengths are 1.74 Å. C+1.50+ is bonded in a linear geometry to one Co1+ and one O2- atom. The C–O bond length is 1.18 Å. O2- is bonded in a distorted single-bond geometry to one Cs1+ and one C+1.50+ atom.
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