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Results for “C-Cl-Sn”

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All sourcesNASA NTRSDOE OSTI
DOE OSTI2020

Materials Data on SnCCl3 by Materials Project

SnCCl3 crystallizes in the monoclinic Cm space group. The structure is one-dimensional and consists of two SnCCl3 ribbons oriented in the (0, 0, 1) direction. Sn is bonded in a 5-coordinate geometry to two equivalent C and three Cl atoms. There are one shorter (2.13 Å) and one longer (2.18 Å) Sn–C bond lengths. There are one shorter (2.34 Å) and two longer (2.59 Å) Sn–Cl bond lengths. C is bonded in a 4-coordinate geometry to two equivalent Sn and two equivalent Cl atoms. Both C–Cl bond lengths are 2.39 Å. There are two inequivalent Cl sites. In the first Cl site, Cl is bonded in a 1-coordinate geometry to one Sn and one C atom. In the second Cl site, Cl is bonded in a single-bond geometry to one Sn atom.

36 MATERIALS SCIENCE↗
DOE OSTI2020

Materials Data on SnCCl3 by Materials Project

SnCCl3 crystallizes in the trigonal R3m space group. The structure is zero-dimensional and consists of three chloroform molecules and three tin powder molecules.

36 MATERIALS SCIENCE↗
DOE OSTI2020

Materials Data on Sn(CCl)2 by Materials Project

Sn(CCl)2 crystallizes in the orthorhombic Imma space group. The structure is one-dimensional and consists of two Sn(CCl)2 ribbons oriented in the (0, 1, 0) direction. Sn2+ is bonded in a tetrahedral geometry to two equivalent C and two equivalent Cl1- atoms. Both Sn–C bond lengths are 2.08 Å. Both Sn–Cl bond lengths are 2.34 Å. C is bonded in a linear geometry to one Sn2+ and one C atom. The C–C bond length is 1.23 Å. Cl1- is bonded in a single-bond geometry to one Sn2+ atom.

36 MATERIALS SCIENCE↗
DOE OSTI2020

Materials Data on Sn(CCl)2 by Materials Project

(C)2SnCl2 crystallizes in the orthorhombic Imma space group. The structure is one-dimensional and consists of four 7772-99-8 molecules and two C ribbons oriented in the (1, 0, 0) direction. In each C ribbon, C is bonded in a linear geometry to two equivalent C atoms. Both C–C bond lengths are 1.32 Å.

36 MATERIALS SCIENCE↗
DOE OSTI2020

Materials Data on SnCCl3 by Materials Project

CSnCl3 is (Cubic) Perovskite structured and crystallizes in the cubic Pm-3m space group. The structure is three-dimensional and consists of one methane molecule and one SnCl3 framework. In the SnCl3 framework, Sn is bonded to six equivalent Cl atoms to form corner-sharing SnCl6 octahedra. The corner-sharing octahedral tilt angles are 0°. All Sn–Cl bond lengths are 2.63 Å. Cl is bonded in a linear geometry to two equivalent Sn atoms.

36 MATERIALS SCIENCE↗