Materials Data on SnH16C4(NCl3)2 by Materials Project
((CH3)2NH2)2SnCl6 is Silicon tetrafluoride-derived structured and crystallizes in the orthorhombic Pnnm space group. The structure is zero-dimensional and consists of four dimethylazanium molecules and two SnCl6 clusters. In each SnCl6 cluster, Sn4+ is bonded in an octahedral geometry to six Cl1- atoms. All Sn–Cl bond lengths are 2.48 Å. There are two inequivalent Cl1- sites. In the first Cl1- site, Cl1- is bonded in a single-bond geometry to one Sn4+ atom. In the second Cl1- site, Cl1- is bonded in a single-bond geometry to one Sn4+ atom.