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PdCl4(N(CH3)4)2 is Silicon tetrafluoride-derived structured and crystallizes in the tetragonal P4_2/mnm space group. The structure is zero-dimensional and consists of two ac1l8io8 molecules and four tetramethylammonium molecules.
PdCl3(CH3)2NH2 crystallizes in the monoclinic C2/c space group. The structure is one-dimensional and consists of four dimethylazanium molecules and two PdCl3 ribbons oriented in the (0, 0, 1) direction. In each PdCl3 ribbon, Pd2+ is bonded in a square co-planar geometry to four Cl1- atoms. There are two shorter (2.33 Å) and two longer (2.34 Å) Pd–Cl bond lengths. There are two inequivalent Cl1- sites. In the first Cl1- site, Cl1- is bonded in a single-bond geometry to one Pd2+ atom. In the second Cl1- site, Cl1- is bonded in a water-like geometry to two equivalent Pd2+ atoms.
PdCl4(CN3H6)2 crystallizes in the tetragonal P4_2/n space group. The structure is zero-dimensional and consists of four ac1l8io8 molecules and eight guanidinium molecules.