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All sourcesNASA NTRSDOE OSTI
DOE OSTI2024

Observation of χ c J → p p ¯ K S 0 K − π + + c . c .

By analyzing ( 27.12 ± 0.14 ) × 10 8 ψ ( 3686 ) events collected with the BESIII detector operating at the BEPCII collider, the decays χ c J → p p ¯ K S 0 K − π + + c . c . ( J = 0 , 1 , 2 ) are observed for the first time with statistical significances greater than 10 σ . The branching fractions of these decays are determined to be B ( χ c 0 → p p ¯ K S 0 K − π + + c . c . ) = ( 2.61 ± 0.27 ± 0.32 ) × 10 − 5 , B ( χ c 1 → p p ¯ K S 0 K − π + + c . c . ) = ( 4.16 ± 0.24 ± 0.46 ) × 10 − 5 , and B ( χ c 2 → p p ¯ K S 0 K − π + + c . c . ) = ( 5.63 ± 0.28 ± 0.46 ) × 10 − 5 , respectively. The processes χ c 1 , 2 → p ¯ Λ ( 1520 ) K S 0 π + + c . c . are also observed, with statistical significances of 5.7 σ and 7.0 σ , respectively. Evidence for χ c 0 → p ¯ Λ ( 1520 ) K S 0 π + + c . c . is found with statistical significances of 3.3 σ . The corresponding branching fractions are determined to be B ( χ c 0 → p ¯ Λ ( 1520 ) K S 0 π + + c . c . ) = ( 1.6 1 − 0.64 + 0.68 ± 0.23 ) × 10 − 5 , B ( χ c 1 → p ¯ Λ ( 1520 ) K S 0 π + + c . c . ) = ( 4.06 − 0.76 + 0.80 ± 0.52 ) × 10 − 5 , and B ( χ c 2 → p ¯ Λ ( 1520 ) K S 0 π + + c . c . ) = ( 4.0 9 − 0.84 + 0.87 ± 0.42 ) × 10 − 5 . Here, the first uncertainties are statistical and the second ones are systematic. Published by the American Physical Society 2024

Ablikim, M.↗
DOE OSTI2025

Measurements of the branching fractions of ${\Xi }_{c}^{+}\to {\Sigma }^{+}{K}_{S}^{0}$, ${\Xi }_{c}^{+}\to {\Xi }^{0}{\pi }^{+}$, and ${\Xi }_{c}^{+}\to {\Xi }^{0}{K}+$ at Belle and Belle II

Using 983.0 fb −1 and 427.9 fb −1 data samples collected with the Belle and Belle II detectors at the KEKB and SuperKEKB asymmetric energy e + e − colliders, respectively, we present studies of the Cabibbo-favored ${\Xi }_{c}^{+}$ decays ${\Xi }_{c}^{+}\to {\Sigma }^{+}{K}_{S}^{0}$ and ${\Xi }_{c}^{+}\to {\Xi }^{0}{\pi }^{+}$, and the singly Cabibbo-suppressed decay ${\Xi }_{c}^{+}\to {\Xi }^{0}{K}^{+}$. The ratios of branching fractions of ${\Xi }_{c}^{+}\to {\Sigma }^{+}{K}_{S}^{0}$ and ${\Xi }_{c}^{+}\to {\Xi }^{0}{K}^{+}$ relative to that of ${\Xi }_{c}^{+}\to {\Xi }^{-}{\pi }^{+}{\pi }^{+}$ are measured for the first time, while the ratio $\mathcal{B}({\Xi }_{c}^{+}\to {\Xi }^{0}{\pi }^{+})/\mathcal{B}({\Xi }_{c}^{+}\to {\Xi }^{-}{\pi }^{+}{\pi }^{+})$ is also determined and improved by an order of magnitude in precision. The measured branching fraction ratios are $\begin{array}{c}\frac{\mathcal{B}\left({\Xi }_{c}^{+}\to {\Sigma }^{+}{K}_{S}^{0}\right)}{\mathcal{B}\left({\Xi }_{c}^{+}\to {\Xi }^{-}{\pi }^{+}{\pi }^{+}\right)}=0.067\pm 0.007\pm 0.003,\\ \frac{\mathcal{B}\left({\Xi }_{c}^{+}\to {\Xi }^{0}{\pi }^{+}\right)}{\mathcal{B}\left({\Xi }_{c}^{+}\to {\Xi }^{-}{\pi }^{+}{\pi }^{+}\right)}=0.251\pm 0.005\pm 0.010,\\ \frac{\mathcal{B}\left({\Xi }_{c}^{+}\to {\Xi }^{0}{K}^{+}\right)}{\mathcal{B}\left({\Xi }_{c}^{+}\to {\Xi }^{-}{\pi }^{+}{\pi }^{+}\right)}=0.017\pm 0.003\pm 0.001.\end{array}$ Additionally, the ratio $\mathcal{B}({\Xi }_{c}^{+}\to {\Xi }^{0}{K}^{+})/\mathcal{B}({\Xi }_{c}^{+}\to {\Xi }^{0}{\pi }^{+})$ is measured to be 0.068 ± 0.010 ± 0.004. Here, the first and second uncertainties are statistical and systematic, respectively. Multiplying the ratios by the branching fraction of the normalization mode, $\mathcal{B}({\Xi }_{c}^{+}\to {\Xi }^{-}{\pi }^{+}{\pi }^{+})=(2.9\pm 1.3)%$, we obtain the following absolute branching fractions $\begin{array}{c}\mathcal{B}({\Xi }_{c}^{+}\to {\Sigma }^{+}{K}_{S}^{0})=(0.194\pm 0.021\pm 0.009\pm 0.087)\text{%},\\ \mathcal{B}({\Xi }_{c}^{+}\to {\Xi }^{0}{\pi }^{+})=(0.728\pm 0.014\pm 0.027\pm 0.326)\text{%},\\ \mathcal{B}({\Xi }_{c}^{+}\to {\Xi }^{0}{K}^{+})=(0.049\pm 0.007\pm 0.003\pm 0.022)\text{%},\end{array}$ where the third uncertainties are from $\mathcal{B}({\Xi }_{c}^{+}\to {\Xi }^{-}{\pi }^{+}{\pi }^{+})$.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
DOE OSTI2025

Measurement of the branching fractions of the decays Λ c + → Λ K S 0 K + , Λ c + → Λ K S 0 π + , and Λ c + → Λ K * +

Studies are performed of the Cabibbo-favored decay Λ c + → Λ K S 0 K + and the singly Cabibbo-suppressed decay Λ c + → Λ K S 0 π + , based on a sample of e + e − collision data, corresponding to an integrated luminosity of 4.5 fb − 1 , accumulated at center-of-mass energies between 4599.53 MeV and 4698.82 MeV with the BESIII detector. The decay Λ c + → Λ K S 0 π + is observed for the first time. The branching fractions of Λ c + → Λ K S 0 K + and Λ c + → Λ K S 0 π + are measured to be ( 3.04 ± 0.30 ± 0.16 ) × 10 − 3 and ( 1.73 ± 0.27 ± 0.10 ) × 10 − 3 , respectively, where the first uncertainties are statistical and the second are systematic. These results correspond to the most precise measurement of these quantities for both decays. Evidence of a K * + contribution in the Λ c + → Λ K S 0 π + decay is found with a statistical significance of 4.71 σ . The branching fraction of Λ c + → Λ K * + is calculated under three possible interference scenarios, with the significance increasing to 5.03 σ when interference is taken into account. Published by the American Physical Society 2025

Ablikim, M.↗
DOE OSTI2025

A Combined Crossed Molecular Beam and Theoretical Investigation of the Elementary Reaction of Tricarbon (C 3 (X 1 Σ g + )) with Diacetylene (C 4 H 2 (X 1 Σ g + )): Gas Phase Formation of the Heptatriynylidyne Radical ( l -C 7 H(X 2 Π))

An elucidation of the underlying formation pathways to acyclic hydrocarbons such as polyynes (C n H 2 ), cumulenes (C n H 2 ), and linear resonantly stabilized linear radicals (l-C n H) is indispensable to understand the hydrocarbon chemistry in extreme low and high temperature environments. In this study, we exploited the crossed molecular beam technique to investigate the reaction of tricarbon C 3 (X 1 Σ g + ) with diacetylene (butadiyne; HCCCCH; X 1 Σ g + ) at a collision energy of 47 ± 1 kJ mol ⁻1 . The experimental data were merged with ab initio calculations of the singlet C 7 H 2 potential energy surface (PES) revealing that the reaction is initiated via the formation of an initial van der Waals reactant complex in the entrance channel. Subsequent rearrangements lead to various carbene-type and cyclic intermediates via ring-opening, ring-closure, and hydrogen migration processes eventually forming acyclic C 7 H 2 isomers prior to their barrierless unimolecular decomposition to the most stable linear isomer, heptatriynylidyne (C 7 H, X 2 Π) in an overall endoergic reaction (+57 kJ mol ⁻1 ). The reaction exhibits strong similarities to the tricarbon – acetylene (C 3 – C 2 H 2 ). Furthermore, the significant energy threshold suggests that the tricarbon reaction with (poly)acetylenes forming resonantly stabilized linear radicals are open in high-temperature environments such as combustion flames and circumstellar envelopes of carbon stars and planetary nebulae as their descendants; however, these reactions are closed in low-temperature environments as in cold molecular clouds and hydrocarbon-rich atmospheres of planets and their moons such as in Titan.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2025

Cleavage of C-O and C-C Bonds in Lignin-Derived Compounds to Produce Aromatics Using Molybdenum-Containing MFI Zeolites

Lignin, the most abundant source of renewable arenes, is a viable feedstock for the production of aromatic compounds. However, the prevalence of resilient C-C bonded oligomeric fragments in lignin-derived streams can compromise monomer yields during reductive catalytic fractionation (RCF). To address this issue, we developed a bifunctional molybdenum-containing MFI (Mo/H-MFI) zeolite catalyst capable of cleaving both C-O and C-C bonds in lignin-derived molecules to produce aromatic monomers. Using propylguaiacol as a model compound, we demonstrated the importance of proximity between metallic molybdenum carbide sites and the Bronsted acid sites in the zeolite in achieving high carbon yields (~80%) of benzene, toluene, propylbenzene, and phenol while maintaining catalyst stability (>98% stable conversion for 20 h). A reaction network involving both C-O and C-C bond cleavage pathways was proposed based on kinetic studies using key intermediates as feeds. Finally, we successfully depolymerized partially deoxygenated lignin oil obtained from the RCF of poplar using a continuous, two-pass catalytic process. This work highlights the potential of the bifunctional Mo/H-MFI catalyst in upgrading complex lignin feedstocks and provides a methodological approach for converting lignin-derived compounds into platform aromatic chemicals.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2025

Measurement of the mass-changing, charge-changing, and production cross sections of C 11 , B 11 , and B 10 nuclei in C 12 + p interactions at 13.5 GeV / c per nucleon

A good knowledge of nuclear fragmentation cross sections is important to interpret the fluxes of secondary cosmic rays from the Galaxy. Here we report new measurements of nuclear fragmentation with the NA61/SHINE experiment at the CERN SPS. The specific focus is on cross sections important for the production of boron in the Galaxy from the interactions of C 12 nuclei with hydrogen in the interstellar medium, including the contribution from the decay of the short-lived C 11 fragments. The data were taken with the secondary C 12 beam at beam momentum of 13.5 GeV / c per nucleon and two fixed targets, polyethylene ( CH 2 ) and graphite (C), from which we derive the cross sections of carbon on hydrogen. We present the measurement of the fragmentation cross sections of C 11 , B 11 , and B 10 as well as the mass- and charge-changing cross sections.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗
DOE OSTI2026

The Hidden Path to the Resonance-Stabilized Fulvenallenyl Radical (C 7 H 5 ) via the Bimolecular Reaction of Tricarbon (C 3 , X 1 Σ g + ) with 1,3-Butadiene (C 4 H 6 ; X 1 A g )

Here, we report a novel bimolecular reaction pathway forming the resonance-stabilized fulvenallenyl radical (C 7 H 5 ) via the gas-phase reaction of tricarbon (C 3 , X 1 Σ g + ) with 1,3-butadiene (C 4 H 6 , X 1 A g ). Crossed molecular beam experiments combined with high-level electronic structures and statistical calculations reveal a rich potential energy surface. The reaction proceeds via tricarbon addition to a double bond of 1,3-butadiene, overcoming a 30 kJ mol –1 barrier, followed by ring closure, isomerizations (ring opening/closures, hydrogen shifts), and eventual hydrogen atom loss, yielding the fulvenallenyl radical (p1) almost exclusively via two dominant pathways. Considering the entrance barrier, this reaction may occur in high-temperature environments, like circumstellar envelopes of carbon stars, but is suppressed in colder regions such as molecular clouds and Titan’s atmosphere. These findings highlight the unexpected reactivity of small carbon clusters in shaping the molecular complexity of our universe, from the flicker of a flame to the death of a star.

Aromatic compounds↗
DOE OSTI2025

From the laboratory to space: unveiling isomeric diversity of C 5 H 2 in the reaction of tricarbon (C 3 , X 1 Σ g + ) with the vinyl radical (C 2 H 3 , X 2 A′)

By connecting laboratory dynamics with cosmic observables, this work highlights the critical role of reactions between highly reactive species in shaping the molecular inventory of the interstellar medium and opens new windows into the spectroscopically elusive corners of astrochemical complexity. The gas phase formation of distinct C 5 H 2 isomers is explored through the bimolecular reaction of tricarbon (C 3 , X 1 Σ + g ) with the vinyl radical (C 2 H 3 , X 2 A′) at a collision energy of 44 ± 1 kJ mol −1 employing the crossed molecular beam technique augmented by electronic structure and Rice–Ramsperger–Kassel–Marcus (RRKM) calculations. This barrierless and exoergic reaction follows indirect dynamics and is initiated by the addition of tricarbon to the radical center of the vinyl radical forming a Cs symmetric doublet collisional complex (CCCCHCH 2 ). Subsequent low-barrier isomerization steps culminate in the resonantly stabilized 2,4-pentadiynyl-1 radical (CHCCCCH 2 ), which decomposes via atomic hydrogen loss. Statistical calculations identify linear, triplet pentadiynylidene (p2, X 3 Σ − g ) as the dominant product, while singlet carbenes ethynylcyclopropenylidene (p1, X 1 A′), pentatetraenylidene (p3, X 1 A 1 ), and ethynylpropadienylidene (p4, X 1 A′) are formed with lower branching ratios. The least stable isomer, 2-cyclopropen-1-ylidenethenylidene (‘eiffelene’; p5, X 1 A 1 ), remains thermodynamically feasible, but exhibits negligible branching ratios. Two isomers detected in TMC-1 to date (p1 and p3) possess significant dipole moments making them amenable to radio telescopic observations, whereas linear pentadiynylidene (p2; D ∞h ) is only traceable via infrared spectroscopy or through its cyanopentadiynylidene derivative (HCCCCCCN). This study highlights the isomer diversity accessed in the low temperature hydrocarbon chemistry of barrierless and exoergic bimolecular reactions involving two unstable, reactants in cold molecular clouds.

Medvedkov, Iakov A. [University of Hawai'i at Mano↗
DOE OSTI2025

Search for η c ( 2 S ) → ω ω and ω ϕ and measurements of χ c J → ω ω and ω ϕ in ψ ( 2 S ) radiative processes

Using ( 2712 ± 14 ) × 10 6 ψ ( 2 S ) events collected with the BESIII detector at the BEPCII collider, we search for the decays η c ( 2 S ) → ω ω and η c ( 2 S ) → ω ϕ via the process ψ ( 2 S ) → γ η c ( 2 S ) . No statistically significant signals are observed. The upper limits of their product branching fractions at the 90% confidence level are determined to be B ( ψ ( 2 S ) → γ η c ( 2 S ) , η c ( 2 S ) → ω ω ) < 1.04 × 10 − 6 and B ( ψ ( 2 S ) → γ η c ( 2 S ) , η c ( 2 S ) → ω ϕ ) < 1.85 × 10 − 7 , respectively. We also update the branching fractions of χ c J → ω ω and χ c J → ω ϕ via the ψ ( 2 S ) → γ χ c J transition. Their branching fractions are determined to be B ( χ c 0 → ω ω ) = ( 10.66 ± 0.11 ± 0.57 ) × 10 − 4 , B ( χ c 1 → ω ω ) = ( 6.43 ± 0.07 ± 0.31 ) × 10 − 4 , B ( χ c 2 → ω ω ) = ( 8.75 ± 0.08 ± 0.42 ) × 10 − 4 , B ( χ c 0 → ω ϕ ) = ( 1.18 ± 0.03 ± 0.07 ) × 10 − 4 , B ( χ c 1 → ω ϕ ) = ( 2.04 ± 0.15 ± 0.11 ) × 10 − 5 , and B ( χ c 2 → ω ϕ ) = ( 9.58 ± 1.07 ± 0.76 ) × 10 − 6 , where the first uncertainties are statistical and the second are systematic. Published by the American Physical Society 2025

Ablikim, M.↗
DOE OSTI2025

Enhanced Selectivity for C 2 H 4 Production from C 2 H 6 on Partially Chlorinated IrO 2 (110) Surfaces

Modifying metal oxide surfaces to limit their oxidizing activity can provide a means of improving catalytic selectivity toward the partial oxidation of light alkanes. Here, in this study, we investigated the oxidation of C 2 H 6 on Cl-modified IrO 2 (110) surfaces using temperature-programmed reaction spectroscopy (TPRS) and first-principles microkinetic modeling. We find that substituting Cl for O in the IrO 2 (110) surface enhances the selectivity for C 2 H 6 conversion to C 2 H 4 during TPRS by suppressing extensive oxidation to CO x products, while also either enhancing C 2 H 4 production or altering it to a lesser extent, depending on the initial C 2 H 6 coverage. The C 2 H 4 selectivity increased with increasing C 2 H 6 and Cl coverage, but reached a limiting value below 50%. The Cl coverage changed negligibly during C 2 H 6 oxidation, and the surface reactivity decreased only marginally for Cl coverages up to 0.5 ML (monolayer). TPRS simulations using a microkinetic model predict C 2 H 4 and CO x product yields as a function of the Cl coverage that agree closely with the experimental results. According to the simulations, C 2 H 6 conversion to C 2 H 4 occurs on Cl-IrO 2 (110) by the hydrogenation of C 2 H 3 * species adsorbed in blocked states, in which neighboring sites are occupied only by unreactive HO and Cl species. The microkinetic modeling shows that H-hopping away from surface HO groups provides a relatively efficient route for C 2 H 3 * to escape blocked configurations and dehydrogenate, and that this process can limit the C 2 H 4 selectivity on Cl-IrO 2 (110) under the conditions studied. Overall, our results demonstrate that Cl-substitution into IrO 2 (110) enhances the selectivity for C 2 H 4 production from C 2 H 6 and provides insights into the reaction mechanism that can guide strategies to further improve the C 2 H 4 selectivity.

IrO2↗
DOE OSTI2024

Charm fragmentation fractions and $\mathbf {c\overline{c}}$ cross section in p–Pb collisions at $\mathbf {\sqrt{s _{NN}}=5.02 TeV}$

The total charm-quark production cross section per unit of rapidity dσ($\mathbf {c\overline{c}}$)/dy, and the fragmentation fractions of charm quarks to different charm-hadron species f(c → h c ), are measured for the first time in p–Pb collisions at $\sqrt{s_{NN}}$ = 5.02 TeV at midrapidity (–0.96 < y < 0.04 in the centre-of-mass frame) using data collected by ALICE at the CERN LHC. The results are obtained based on all the available measurements of prompt production of ground-state charm-hadron species: D 0 , D + , D$^{+}_{s}$, and J/ψ mesons, and Λ$^{+}_{c}$ and $Ξ$$^{0}_{c}$ baryons. The resulting cross section is dσ($\mathbf {c\overline{c}}$)/dy = 219.6 ± 6.3 (stat.) $^{+10.5}_{–11.8}$ (syst.) $^{+8.3}_{–2.9}$ (extr.) ± 5.4 (BR) ± 4.6 (lumi.) ± 19.5 (rapidity shape) + 15.0 (Ω$^{0}_{c}$) mb, which is consistent with a binary scaling of pQCD calculations from pp collisions. The measured fragmentation fractions are compatible with those measured in pp collisions at $\sqrt{s_{NN}}$ = 5.02 and 13 TeV, showing an increase in the relative production rates of charm baryons with respect to charm mesons in pp and p–Pb collisions compared with e + e – and e – p collisions. The p T -integrated nuclear modification factor of charm quarks, R pPb ($\mathbf {c\overline{c}}$) = 0.91 ± 0.04 (stat.) $^{+0.08}_{–0.09}$ (syst.) $^{+0.05}_{–0.03}$ (extr.) ± 0.03 (lumi.), is found to be consistent with unity and with theoretical predictions including nuclear modifications of the parton distribution functions.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
DOE OSTI2025

Search for η c ( 2 S ) → p p ¯ K + K − and measurement of χ c J → p p ¯ K + K − in ψ ( 3686 ) radiative decays

A search for η c ( 2 S ) → p p ¯ K + K − , together with measurement of branching fractions of χ c J ( J = 0 , 1 , 2 ) → p p ¯ K + K − in the ψ ( 3686 ) → γ η c ( 2 S ) and the ψ ( 3686 ) → γ χ c J radiative decays, is performed with ( 2712.4 ± 14.3 ) × 10 6 ψ ( 3686 ) events collected with the BESIII detector at the BEPCII collider. An evidence for η c ( 2 S ) → p p ¯ K + K − is found, with a significance of 3.3 σ . The product branching fraction of B [ ψ ( 3686 ) → γ η c ( 2 S ) ] · B [ η c ( 2 S ) → p p ¯ K + K − ] is determined to be ( 1.98 ± 0.4 1 stat ± 0.9 9 syst ) × 10 − 7 . The product branching fractions of B [ ψ ( 3686 ) → γ χ c J ] · B [ χ c J → p p ¯ K + K − ] are measured to be ( 2.49 ± 0.0 3 stat ± 0.1 5 syst ) × 10 − 5 , ( 1.83 ± 0.0 2 stat ± 0.1 1 syst ) × 10 − 5 , and ( 2.43 ± 0.0 2 stat ± 0.1 5 syst ) × 10 − 5 , for J = 0 , 1, and 2, respectively. Published by the American Physical Society 2025

Ablikim, M.↗
DOE OSTI2025

Observation of η c ( 1 S , 2 S ) and χ c J decays to 2 ( π + π − ) η via ψ ( 3686 ) radiative transitions

Based on ( 2712.4 ± 14.1 ) × 10 6 ψ ( 3686 ) decays collected with the BESIII detector, we have observed, for the first time, the hadronic decays of S- and P-wave charmonium states into 2 ( π + π − ) η via radiative transitions from ψ ( 3686 ) . The branching fraction of the decay η c ( 1 S ) → 2 ( π + π − ) η has a significant dependence on the interference pattern between η c ( 1 S ) and non- η c ( 1 S ) processes. We measure it in both the destructive and constructive interference scenarios for the first time. The mass and width of the η c ( 1 S ) are measured to be M = ( 2984.14 ± 0.13 ± 0.38 ) MeV / c 2 and Γ = ( 28.82 ± 0.11 ± 0.82 ) MeV , respectively. Clear signals for the decays of the χ c J ( J = 0 , 1 , 2 ) and the η c ( 2 S ) to 2 ( π + π − ) η are also observed for the first time, and the corresponding branching fractions are measured. The ratio of the branching fractions between the η c ( 2 S ) and η c ( 1 S ) decays is significantly lower than the theoretical prediction, which might suggest different dynamics in their decays. Published by the American Physical Society 2025

Ablikim, M.↗
DOE OSTI2025

Multiplicity dependence of ${\Xi }_{\text{c}}^{+}$ and ${\Xi }_{\text{c}}^{0}$ production in pp collisions at $\sqrt{s}=13$ TeV

The first measurement at midrapidity (|y| < 0.5) of the production yield of the strange-charm baryons $Ξ$$^{+}_{c}$ and $Ξ$$^{0}_{c}$ as a function of transverse momentum (p T ) in different charged-particle multiplicity classes in proton-proton collisions at $\sqrt{s}$ = 13 TeV with the ALICE experiment at the LHC is reported. The $Ξ$$^{+}_{c}$ baryon is reconstructed via the $Ξ$$^{+}_{c}$ → $Ξ$ – π + π + decay channel in the range 4 < p T < 12 GeV/c, while the $Ξ$$^{0}_{c}$ baryon is reconstructed via both the $Ξ$$^{0}_{c}$ → $Ξ$ – π + and $Ξ$$^{0}_{c}$ → $Ξ$ – e + ν e decay channels in the range 2 < p T < 12 GeV/c. The baryon-to-meson ($Ξ$$^{0}_{c}$ + /D 0 ) and the baryon-to-baryon ($Ξ$$^{0}_{c}$ + /Λ$^{+}_{c}$) production yield ratios show no significant dependence on multiplicity. In addition, the observed yield ratios are not described by theoretical predictions that model charm-quark fragmentation based on measurements at e + e − and e − p colliders, indicating differences in the charm-baryon production mechanism in pp collisions. A comparison with different event generators and tunings, including different modelling of the hadronisation process, is also discussed.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗
DOE OSTI2025

Light-Promoted C(sp 3 )–C(sp 3 ) Reductive Elimination from Dialkyl NiII Complexes

Ni-catalyzed cross-coupling is a powerful strategy to forge C(sp 3 )–C(sp 3 ) bonds. Typically, to do so requires overcoming a challenging C–C bond-forming reductive elimination, often enabled by the intermediacy of highly oxidized Ni species or outer-sphere processes. While direct C(sp 3 )–C(sp 3 ) reductive elimination from the Ni II base oxidation state is normally thermally inaccessible, light-activation provides an avenue to affect such transformations. Here, we investigate the mechanism of light-induced C(sp 3 )–C(sp 3 ) bond formation from dialkyl bipyridine Ni II complexes through a variety of organometallic, spectroscopic, and computational studies. Wavelength-dependent quantum yields, ligand electronics–reactivity relationships, excited-state lifetimes, computed barriers, and product distributions from crossover studies support a photolysis/radical rebound mechanism. Furthermore, this reactivity paradigm complements existing strategies in the literature to promote reductive elimination from Ni II , such as the use of destabilizing, sterically hindered ligands and reduction of electron density at Ni through the binding of electron-deficient olefins. Hence, we envision that light-induced reductive elimination may enable the development of challenging C(sp 3 )–C(sp 3 ) couplings.

Alkyls↗
DOE OSTI2025

Observation of the Charmonium Decay η c → γ γ in J / ψ → γ η c

Using ( 2712.4 ± 14.3 ) × 10 6 ψ ( 3686 ) events collected with the BESIII detector at the BEPCII collider, the decay η c → γ γ in J / ψ → γ η c is observed. We determine the product branching fraction B ( J / ψ → γ η c ) × B ( η c → γ γ ) = ( 5.23 ± 0.2 6 stat ± 0.3 0 syst ) × 10 − 6 . This result is consistent with the lattice QCD calculation ( 5.34 ± 0.16 ) × 10 − 6 from HPQCD in 2023. By using the world-average values of B ( J / ψ → γ η c ) and the total decay width of η c , the partial decay width Γ ( η c → γ γ ) is determined to be ( 11.30 ± 0.5 6 stat ± 0.6 6 syst ± 1.1 4 ref ) keV , which deviates from the corresponding world-average value by 3.4 σ . Published by the American Physical Society 2025

Ablikim, M.↗
DOE OSTI2025

Search for resonance-enhanced C P and angular asymmetries in the Λ c + → p μ + μ − decay at LHCb

The first measurement of the C P asymmetry of the decay rate ( A C P ) and the C P average ( Σ A FB ) and C P asymmetry ( Δ A FB ) of the forward-backward asymmetry in the muon system of Λ c + → p μ + μ − decays is reported. The measurement is performed using a data sample of proton-proton collisions, recorded by the LHCb experiment from 2016 to 2018 at a center-of-mass energy of 13 TeV, which corresponds to an integrated luminosity of 5.4 fb − 1 . The asymmetries are measured in two regions of dimuon mass near the ϕ -meson mass peak. The dimuon-mass integrated results are A C P = ( − 1.1 ± 4.0 ± 0.5 ) % , Σ A FB = ( 3.9 ± 4.0 ± 0.6 ) % , Δ A FB = ( 3.1 ± 4.0 ± 0.4 ) % , where the first uncertainty is statistical and the second systematic. The results are consistent with the conservation of C P symmetry and the Standard Model expectations. © 2025 CERN, for the LHCb Collaboration 2025 CERN

Aaij, R. (ORCID:0000000305331952)↗