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BrN crystallizes in the tetragonal P4/nmm space group. The structure is two-dimensional and consists of one BrN sheet oriented in the (0, 0, 1) direction. N1+ is bonded in a distorted square co-planar geometry to four equivalent Br1- atoms. All N–Br bond lengths are 2.21 Å. Br1- is bonded in a distorted square co-planar geometry to four equivalent N1+ atoms.
BrN is Tetraauricupride structured and crystallizes in the tetragonal P4/mmm space group. The structure is three-dimensional. N1+ is bonded in a body-centered cubic geometry to eight equivalent Br1- atoms. All N–Br bond lengths are 2.64 Å. Br1- is bonded in a body-centered cubic geometry to eight equivalent N1+ atoms.
BrN is Halite, Rock Salt structured and crystallizes in the cubic Fm-3m space group. The structure is three-dimensional. N1+ is bonded to six equivalent Br1- atoms to form a mixture of edge and corner-sharing NBr6 octahedra. The corner-sharing octahedral tilt angles are 0°. All N–Br bond lengths are 2.44 Å. Br1- is bonded to six equivalent N1+ atoms to form a mixture of edge and corner-sharing BrN6 octahedra. The corner-sharing octahedral tilt angles are 0°.
N3S4Br(Br)2 crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of eight hydrobromic acid molecules and four N3S4Br clusters. In each N3S4Br cluster, there are three inequivalent N+0.33- sites. In the first N+0.33- site, N+0.33- is bonded in a bent 150 degrees geometry to two S2- atoms. There is one shorter (1.55 Å) and one longer (1.57 Å) N–S bond length. In the second N+0.33- site, N+0.33- is bonded in a bent 150 degrees geometry to two S2- atoms. There is one shorter (1.55 Å) and one longer (1.57 Å) N–S bond length. In the third N+0.33- site, N+0.33- is bonded in a distorted bent 150 degrees geometry to two S2- atoms. There is one shorter (1.58 Å) and one longer (1.59 Å) N–S bond length. There are four inequivalent S2- sites. In the first S2- site, S2- is bonded in a distorted single-bond geometry to one N+0.33- and one Br3+ atom. The S–Br bond length is 3.08 Å. In the second S2- site, S2- is bonded in a distorted single-bond geometry to one N+0.33- and one Br3+ atom. The S–Br bond length is 3.08 Å. In the third S2- site, S2- is bonded in a bent 120 degrees geometry to two N+0.33- atoms. In the fourth S2- site, S2- is bonded in a bent 120 degrees geometry to two N+0.33- atoms. Br3+ is bonded in a 1-coordinate geometry to two S2- atoms.
NOOBrF4 crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four nitroxyl molecules and four OBrF4 clusters. In each OBrF4 cluster, O2- is bonded in a single-bond geometry to one Br5+ atom. The O–Br bond length is 1.60 Å. Br5+ is bonded in a square pyramidal geometry to one O2- and four F1- atoms. There is two shorter (1.93 Å) and two longer (1.97 Å) Br–F bond length. There are two inequivalent F1- sites. In the first F1- site, F1- is bonded in a single-bond geometry to one Br5+ atom. In the second F1- site, F1- is bonded in a single-bond geometry to one Br5+ atom.
K2HgC2S2(NBr)2 crystallizes in the hexagonal P6_3/m space group. The structure is three-dimensional. there are three inequivalent K1+ sites. In the first K1+ site, K1+ is bonded in a 6-coordinate geometry to four equivalent N3- and two Br1- atoms. There are two shorter (2.97 Å) and two longer (2.98 Å) K–N bond lengths. There are one shorter (3.30 Å) and one longer (3.33 Å) K–Br bond lengths. In the second K1+ site, K1+ is bonded in a 6-coordinate geometry to three equivalent N3- and three equivalent Br1- atoms. All K–N bond lengths are 2.94 Å. All K–Br bond lengths are 3.35 Å. In the third K1+ site, K1+ is bonded in a hexagonal planar geometry to six equivalent Br1- atoms. All K–Br bond lengths are 3.66 Å. Hg2+ is bonded in a tetrahedral geometry to two equivalent S2- and two Br1- atoms. Both Hg–S bond lengths are 2.60 Å. There are one shorter (2.68 Å) and one longer (2.73 Å) Hg–Br bond lengths. C4+ is bonded in a distorted linear geometry to one N3- and one S2- atom. The C–N bond length is 1.18 Å. The C–S bond length is 1.65 Å. N3- is bonded in a distorted rectangular see-saw-like geometry to three K1+ and one C4+ atom. S2- is bonded in a water-like geometry to one Hg2+ and one C4+ atom. There are two inequivalent Br1- sites. In the first Br1- site, Br1- is bonded to three K1+ and one Hg2+ atom to form edge-sharing BrK3Hg trigonal pyramids. In the second Br1- site, Br1- is bonded in a 4-coordinate geometry to three K1+ and one Hg2+ atom.
CdBr3CN3H6 crystallizes in the monoclinic C2/c space group. The structure is one-dimensional and consists of four guanidinium molecules and two CdBr3 ribbons oriented in the (0, 0, 1) direction. In each CdBr3 ribbon, Cd2+ is bonded to five Br1- atoms to form edge-sharing CdBr5 trigonal bipyramids. There are a spread of Cd–Br bond distances ranging from 2.63–2.93 Å. There are two inequivalent Br1- sites. In the first Br1- site, Br1- is bonded in an L-shaped geometry to two equivalent Cd2+ atoms. In the second Br1- site, Br1- is bonded in a single-bond geometry to one Cd2+ atom.
MgH6(NBr)2 crystallizes in the orthorhombic Pnma space group. The structure is one-dimensional and consists of two MgH6(NBr)2 ribbons oriented in the (0, 1, 0) direction. Mg2+ is bonded to two N3- and four equivalent Br1- atoms to form edge-sharing MgBr4N2 octahedra. Both Mg–N bond lengths are 2.16 Å. There are two shorter (2.76 Å) and two longer (2.78 Å) Mg–Br bond lengths. There are two inequivalent N3- sites. In the first N3- site, N3- is bonded to one Mg2+ and three H1+ atoms to form distorted corner-sharing NMgH3 tetrahedra. All N–H bond lengths are 1.03 Å. In the second N3- site, N3- is bonded to one Mg2+ and three H1+ atoms to form distorted corner-sharing NMgH3 tetrahedra. All N–H bond lengths are 1.03 Å. There are four inequivalent H1+ sites. In the first H1+ site, H1+ is bonded in a single-bond geometry to one N3- atom. In the second H1+ site, H1+ is bonded in a single-bond geometry to one N3- atom. In the third H1+ site, H1+ is bonded in a single-bond geometry to one N3- atom. In the fourth H1+ site, H1+ is bonded in a single-bond geometry to one N3- atom. Br1- is bonded in an L-shaped geometry to two equivalent Mg2+ atoms.
CrH6(NBr2)2CrH12(N2Br)2 is Protactinium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one CrH12(N2Br)2 cluster and one CrH6(NBr2)2 cluster. In the CrH12(N2Br)2 cluster, Cr3+ is bonded in an octahedral geometry to four N3- and two equivalent Br1- atoms. There are two shorter (2.13 Å) and two longer (2.14 Å) Cr–N bond lengths. Both Cr–Br bond lengths are 2.49 Å. There are two inequivalent N3- sites. In the first N3- site, N3- is bonded in a distorted trigonal non-coplanar geometry to one Cr3+ and three H1+ atoms. There is one shorter (1.02 Å) and two longer (1.03 Å) N–H bond length. In the second N3- site, N3- is bonded in a distorted trigonal non-coplanar geometry to one Cr3+ and three H1+ atoms. All N–H bond lengths are 1.03 Å. There are six inequivalent H1+ sites. In the first H1+ site, H1+ is bonded in a single-bond geometry to one N3- atom. In the second H1+ site, H1+ is bonded in a single-bond geometry to one N3- atom. In the third H1+ site, H1+ is bonded in a single-bond geometry to one N3- atom. In the fourth H1+ site, H1+ is bonded in a single-bond geometry to one N3- atom. In the fifth H1+ site, H1+ is bonded in a single-bond geometry to one N3- atom. In the sixth H1+ site, H1+ is bonded in a single-bond geometry to one N3- atom. Br1- is bonded in a single-bond geometry to one Cr3+ atom. In the CrH6(NBr2)2 cluster, Cr3+ is bonded in an octahedral geometry to two equivalent N3- and four Br1- atoms. Both Cr–N bond lengths are 2.12 Å. There are two shorter (2.51 Å) and two longer (2.53 Å) Cr–Br bond lengths. N3- is bonded to one Cr3+ and three H1+ atoms to form distorted corner-sharing NCrH3 tetrahedra. There is one shorter (1.02 Å) and two longer (1.03 Å) N–H bond length. There are three inequivalent H1+ sites. In the first H1+ site, H1+ is bonded in a single-bond geometry to one N3- atom. In the second H1+ site, H1+ is bonded in a single-bond geometry to one N3- atom. In the third H1+ site, H1+ is bonded in a single-bond geometry to one N3- atom. There are two inequivalent Br1- sites. In the first Br1- site, Br1- is bonded in a single-bond geometry to one Cr3+ atom. In the second Br1- site, Br1- is bonded in a single-bond geometry to one Cr3+ atom.
SrCa3(NBr)2 is Caswellsilverite-derived structured and crystallizes in the monoclinic Pm space group. The structure is three-dimensional. Sr2+ is bonded to three N3- and three Br1- atoms to form distorted SrBr3N3 octahedra that share corners with six equivalent CaBr3N3 octahedra, edges with two equivalent SrBr3N3 octahedra, and edges with six CaBr3N3 octahedra. The corner-sharing octahedra tilt angles range from 1–3°. There are two shorter (2.59 Å) and one longer (2.61 Å) Sr–N bond lengths. There are one shorter (3.15 Å) and two longer (3.18 Å) Sr–Br bond lengths. There are three inequivalent Ca2+ sites. In the first Ca2+ site, Ca2+ is bonded in a 6-coordinate geometry to three N3- and three Br1- atoms. There are one shorter (2.46 Å) and two longer (2.48 Å) Ca–N bond lengths. There are two shorter (3.23 Å) and one longer (3.26 Å) Ca–Br bond lengths. In the second Ca2+ site, Ca2+ is bonded to three N3- and three Br1- atoms to form distorted CaBr3N3 octahedra that share corners with six equivalent SrBr3N3 octahedra, edges with two equivalent SrBr3N3 octahedra, and edges with six CaBr3N3 octahedra. The corner-sharing octahedra tilt angles range from 1–3°. There are one shorter (2.47 Å) and two longer (2.48 Å) Ca–N bond lengths. There are two shorter (3.09 Å) and one longer (3.11 Å) Ca–Br bond lengths. In the third Ca2+ site, Ca2+ is bonded to three N3- and three Br1- atoms to form distorted CaBr3N3 octahedra that share edges with four equivalent SrBr3N3 octahedra and edges with six CaBr3N3 octahedra. There are two shorter (2.51 Å) and one longer (2.53 Å) Ca–N bond lengths. There are one shorter (3.13 Å) and two longer (3.15 Å) Ca–Br bond lengths. There are two inequivalent N3- sites. In the first N3- site, N3- is bonded to two equivalent Sr2+ and four Ca2+ atoms to form edge-sharing NSr2Ca4 octahedra. In the second N3- site, N3- is bonded to one Sr2+ and five Ca2+ atoms to form edge-sharing NSrCa5 octahedra. There are two inequivalent Br1- sites. In the first Br1- site, Br1- is bonded in a 6-coordinate geometry to two equivalent Sr2+ and four Ca2+ atoms. In the second Br1- site, Br1- is bonded in a 6-coordinate geometry to one Sr2+ and five Ca2+ atoms.
CN3C2Bi2(N2Br3)3 crystallizes in the monoclinic P2_1/m space group. The structure is zero-dimensional and consists of two diaziridinimine molecules and two C2Bi2(N2Br3)3 clusters. In each C2Bi2(N2Br3)3 cluster, C4+ is bonded in a trigonal planar geometry to three N+1.22- atoms. There is two shorter (1.34 Å) and one longer (1.41 Å) C–N bond length. Bi4+ is bonded to six Br1- atoms to form distorted face-sharing BiBr6 octahedra. There are a spread of Bi–Br bond distances ranging from 2.67–3.50 Å. There are three inequivalent N+1.22- sites. In the first N+1.22- site, N+1.22- is bonded in a single-bond geometry to one C4+ atom. In the second N+1.22- site, N+1.22- is bonded in a single-bond geometry to one C4+ atom. In the third N+1.22- site, N+1.22- is bonded in a distorted bent 120 degrees geometry to one C4+ and one Br1- atom. The N–Br bond length is 1.88 Å. There are six inequivalent Br1- sites. In the first Br1- site, Br1- is bonded in a 2-coordinate geometry to two equivalent Bi4+ atoms. In the second Br1- site, Br1- is bonded in a 2-coordinate geometry to two equivalent Bi4+ atoms. In the third Br1- site, Br1- is bonded in a single-bond geometry to one Bi4+ atom. In the fourth Br1- site, Br1- is bonded in a distorted single-bond geometry to one Bi4+ and one N+1.22- atom. In the fifth Br1- site, Br1- is bonded in a single-bond geometry to one Bi4+ atom. In the sixth Br1- site, Br1- is bonded in a distorted L-shaped geometry to two equivalent Bi4+ atoms.
NCdN(Br)2 crystallizes in the orthorhombic Cmmm space group. The structure is zero-dimensional and consists of four hydrobromic acid molecules and two NCdN clusters. In each NCdN cluster, Cd2+ is bonded in a linear geometry to two equivalent N3- atoms. Both Cd–N bond lengths are 2.57 Å. N3- is bonded in a single-bond geometry to one Cd2+ atom.
CuN2Br2 is Cyanogen Chloride-like structured and crystallizes in the monoclinic C2/m space group. The structure is zero-dimensional and consists of two copper;azanide molecules and four hydrobromic acid molecules.
FeN2(Br)2 crystallizes in the orthorhombic Pbam space group. The structure is zero-dimensional and consists of four hydrobromic acid molecules and two FeN2 clusters. In each FeN2 cluster, Fe2+ is bonded in a linear geometry to two equivalent N3- atoms. Both Fe–N bond lengths are 1.70 Å. N3- is bonded in a single-bond geometry to one Fe2+ atom.
TlCo(NBr)6 is Halite, Rock Salt structured and crystallizes in the cubic Pa-3 space group. The structure is zero-dimensional and consists of four ramor molecules and four Co(NBr)6 clusters. In each Co(NBr)6 cluster, Co3+ is bonded in an octahedral geometry to six equivalent N+1.67- atoms. All Co–N bond lengths are 1.90 Å. N+1.67- is bonded in a distorted bent 120 degrees geometry to one Co3+ and one Br1+ atom. The N–Br bond length is 1.85 Å. Br1+ is bonded in a single-bond geometry to one N+1.67- atom.
(C5H14N3)3Sb2Br9 crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of six schembl668226 molecules and two Sb2Br9 clusters. In each Sb2Br9 cluster, there are two inequivalent Sb3+ sites. In the first Sb3+ site, Sb3+ is bonded to six Br1- atoms to form face-sharing SbBr6 octahedra. There are a spread of Sb–Br bond distances ranging from 2.64–3.13 Å. In the second Sb3+ site, Sb3+ is bonded to six Br1- atoms to form face-sharing SbBr6 octahedra. There are a spread of Sb–Br bond distances ranging from 2.70–3.04 Å. There are nine inequivalent Br1- sites. In the first Br1- site, Br1- is bonded in an L-shaped geometry to two Sb3+ atoms. In the second Br1- site, Br1- is bonded in a single-bond geometry to one Sb3+ atom. In the third Br1- site, Br1- is bonded in a single-bond geometry to one Sb3+ atom. In the fourth Br1- site, Br1- is bonded in a single-bond geometry to one Sb3+ atom. In the fifth Br1- site, Br1- is bonded in a single-bond geometry to one Sb3+ atom. In the sixth Br1- site, Br1- is bonded in a distorted L-shaped geometry to two Sb3+ atoms. In the seventh Br1- site, Br1- is bonded in a single-bond geometry to one Sb3+ atom. In the eighth Br1- site, Br1- is bonded in an L-shaped geometry to two Sb3+ atoms. In the ninth Br1- site, Br1- is bonded in a single-bond geometry to one Sb3+ atom.
(Cu)2CuN4(Br)4 crystallizes in the tetragonal I4/mmm space group. The structure is zero-dimensional and consists of four cuprum molecules, eight hydrobromic acid molecules, and two nsc1302 molecules.
(N2)Zn(Br)2 crystallizes in the orthorhombic Imma space group. The structure is zero-dimensional and consists of four diaminozinc molecules and eight hydrobromic acid molecules.