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PdN2(Br)4 crystallizes in the tetragonal P4/mmm space group. The structure is zero-dimensional and consists of two ammonia molecules, four hydrobromic acid molecules, and one palladium molecule.
PdBr6N2 is Fluorite structured and crystallizes in the cubic Fm-3m space group. The structure is zero-dimensional and consists of eight ammonia molecules and four PdBr6 clusters. In each PdBr6 cluster, Pd4+ is bonded in an octahedral geometry to six equivalent Br1- atoms. All Pd–Br bond lengths are 2.47 Å. Br1- is bonded in a single-bond geometry to one Pd4+ atom.