Materials Data on Mg(BrN3)2 by Materials Project
MgN6(Br)2 crystallizes in the cubic Fm-3m space group. The structure is three-dimensional and consists of eight hydrobromic acid molecules and one MgN6 framework. In the MgN6 framework, Mg2+ is bonded in an octahedral geometry to six equivalent N2- atoms. All Mg–N bond lengths are 2.81 Å. N2- is bonded in a 5-coordinate geometry to one Mg2+ and four equivalent N2- atoms. All N–N bond lengths are 1.71 Å.
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