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Materials Data on Ir(Br3N)2 by Materials Project

IrBr6N2 is Fluorite structured and crystallizes in the cubic Fm-3m space group. The structure is zero-dimensional and consists of eight ammonia molecules and four IrBr6 clusters. In each IrBr6 cluster, Ir4+ is bonded in an octahedral geometry to six equivalent Br1- atoms. All Ir–Br bond lengths are 2.46 Å. Br1- is bonded in a single-bond geometry to one Ir4+ atom.

36 MATERIALS SCIENCE↗