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NH4Br is Iron carbide-derived structured and crystallizes in the tetragonal P4/nmm space group. The structure is zero-dimensional and consists of two ammonium molecules and two hydrobromic acid molecules.
NH4Br is Silicon tetrafluoride-derived structured and crystallizes in the cubic P-43m space group. The structure is zero-dimensional and consists of one ammonium molecule and one hydrobromic acid molecule.