Materials Data on TlCo(BrN)6 by Materials Project
TlCo(NBr)6 is Halite, Rock Salt structured and crystallizes in the cubic Pa-3 space group. The structure is zero-dimensional and consists of four ramor molecules and four Co(NBr)6 clusters. In each Co(NBr)6 cluster, Co3+ is bonded in an octahedral geometry to six equivalent N+1.67- atoms. All Co–N bond lengths are 1.90 Å. N+1.67- is bonded in a distorted bent 120 degrees geometry to one Co3+ and one Br1+ atom. The N–Br bond length is 1.85 Å. Br1+ is bonded in a single-bond geometry to one N+1.67- atom.
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