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At least 19 records

Alkali metal for ultraviolet band-pass filter

An alkali metal filter having a layer of metallic bismuth deposited onto the alkali metal is provided. The metallic bismuth acts to stabilize the surface of the alkali metal to prevent substantial surface migration from occurring on the alkali metal, which may degrade optical characteristics of the filter. To this end, a layer of metallic bismuth is deposited by vapor deposition over the alkali metal to a depth of approximately 5 to 10 A. A complete alkali metal filter is described along with a method for fabricating the alkali metal filter.

Mardesich, Nick↗

Improvements to a Flow Sensor for Liquid Bismuth-Fed Hall Thrusters

Recently, there has been significant interest in using bismuth metal as a propellant in Hall Thrusters [1, 2]. Bismuth offers some considerable cost, weight, and space savings over the traditional propellant--xenon. Quantifying the performance of liquid metal-fed Hall thrusters requires a very precise measure of the low propellant flow rates [1, 2]. The low flow rates (~10 mg/sec) and the temperature at which free flowing liquid bismuth exists (above 300 C) preclude the use of off-the-shelf flow sensing equipment [3]. Therefore a new type of sensor is required. The hotspot bismuth flow sensor, described in Refs. [1-5] is designed to perform a flow rate measurement by measuring the velocity at which a thermal feature moves through a flow chamber. The mass flow rate can be determined from the time of flight of the thermal peak, [4, 5]. Previous research and testing has been concerned mainly with the generation of the thermal peak and it's subsequent detection. In this paper, we present design improvements to the sensor concept; and the results of testing conducted to verify the functionality of these improvements. A ceramic material is required for the sensor body (see Fig. 1), which must allow for active heating of the bismuth flow channel to keep the propellant in a liquid state. The material must be compatible with bismuth and must be bonded to conductive elements to allow for conduction of current into the liquid metal and measurement of the temperature in the flow. The new sensor requires fabrication techniques that will allow for a very small diameter flow chamber, which is required to produce useful measurements. Testing of various materials has revealed several that are potentially compatible with liquid bismuth. Of primary concern in the fabrication and testing of a robust, working prototype, is the compatibility of the selected materials with one another. Specifically, the thermal expansion rates of the materials relative to the ceramic body cannot expand so much as to cause cracks in the body or cause the bond between parts to delaminate. Those parts that will carry the current pulse must be electrically conductive while the sensor body must be an electrical insulator. Generally, the material choices as well as the sensor design must aid to preserve the integrity of the thermal feature to obtain accurate measurements. The present aim is to also incorporate, into the sensor body, an active heating arrangement based on ceramic heater technology similar to that used in semiconductor manufacturing.

Bonds, Kevin↗

Method of Creating Micro-scale Silver Telluride Grains Covered with Bismuth Nanoparticles

Provided is a method of enhancing thermoelectric performance by surrounding crystalline semiconductors with nanoparticles by contacting a bismuth telluride material with a silver salt under a substantially inert atmosphere and a temperature approximately near the silver salt decomposition temperature; and recovering a metallic bismuth decorated material comprising silver telluride crystal grains.

Kim, Hyun-Jung↗

Search for new high temperature thermoelectric materials

Although important efforts are actually devoted to improve Si-Ge materials, their thermoelectric energy conversion efficiency remains relatively low and the nondimensional ZT value does not exceed 1. Higher values can be obtained by investigating new materials. A search for new high temperature thermoelectric materials identified a certain number of compounds between transition metals and bismuth, antimony and germanium as potential candidates. Results of the preliminary synthesis of samples by a variety of techniques (Bridgman, mechanical alloying) are presented as well as some electrical measurements. Some compounds showed interesting properties and need to be investigated in more details.

Caillat, Thierry↗

Stabilized Alkali-Metal Ultraviolet-Band-Pass Filters

Layers of bismuth 5 to 10 angstrom thick incorporated into alkali-metal ultraviolet-band-pass optical filters by use of advanced fabrication techniques. In new filters layer of bismuth helps to reduce surface migration of sodium. Sodium layer made more stable and decreased tendency to form pinholes by migration.

Mardesich, Nick↗

Thermoelectric Performance Enhancement by Surrounding Crystalline Semiconductors with Metallic Nanoparticles

Direct conversion of thermal energy to electricity by thermoelectric (TE) devices may play a key role in future energy production and utilization. However, relatively poor performance of current TE materials has slowed development of new energy conversion applications. Recent reports have shown that the dimensionless Figure of Merit, ZT, for TE devices can be increased beyond the state-of-the-art level by nanoscale structuring of materials to reduce their thermal conductivity. New morphologically designed TE materials have been fabricated at the NASA Langley Research Center, and their characterization is underway. These newly designed materials are based on semiconductor crystal grains whose surfaces are surrounded by metallic nanoparticles. The nanoscale particles are used to tailor the thermal and electrical conduction properties for TE applications by altering the phonon and electron transport pathways. A sample of bismuth telluride decorated with metallic nanoparticles showed less thermal conductivity and twice the electrical conductivity at room temperature as compared to pure Bi2Te3. Apparently, electrons cross easily between semiconductor crystal grains via the intervening metallic nanoparticle bridges, but phonons are scattered at the interfacing gaps. Hence, if the interfacing gap is larger than the mean free path of the phonon, thermal energy transmission from one grain to others is reduced. Here we describe the design and analysis of these new materials that offer substantial improvements in thermoelectric performance.

Kim, Hyun-Jung↗

Bismuth Propellant Feed System Development at NASA-MSFC

NASA-MSFC has been developing liquid metal propellant feed systems capable of delivering molten bismuth at a prescribed mass flow rate to the vaporizer of an electric thruster. The first such system was delivered to NASA-JPL as part of the Very High Isp Thruster with Anode Layer (VHITAL) program. In this system, the components pictured were placed in a vacuum chamber and heated while the control electronics were located outside the chamber. The system was successfully operated at JPL in conjunction with a propellant vaporizer, and data was obtained demonstrating a new liquid bismuth flow sensing technique developed at MSFC. The present effort is aimed at producing a feed-system for use in conjunction with a bismuth-fed Hall thruster developed by Busek Co. Developing this system is more ambitious, however, in that it is designed to self-contain all the control electronics inside the same vacuum chamber as an operating bismuth-fed thruster. Consequently, the entire system, including an on-board computer, DC-output power supplies, and a gas-pressurization electro-pneumatic regulator, must be designed to survive a vacuum environment and shielded to keep bismuth plasma from intruding on the electronics and causing a shortcircuit. In addition, the hot portions of the feed system must be thermally isolated from the electronics to avoid failure due to high heat loads. This is accomplished using a thermal protection system (TPS) consisting of multiple layers of aluminum foil. The only penetrations into the vacuum chamber are an electrically isolated (floating) 48 VDC line and a fiberoptic line. The 48 VDC provides power for operation of the power supplies and electronics co-located with the system in the vacuum chamber. The fiberoptic Ethernet connection is used to communicate user-input control commands to the on-board computer and transmit real-time data back to the external computer. The partially assembled second-generation system is shown. Before testing at Busek, a more detailed flow sensor calibration will be performed to accurately quantify the flow monitoring capabilities. This effort is funded under a Technology Innovation Program (TIP) award from NASA-MSFC's Technology Transfer office and performed under SAA8-061060.

Polzin, Kurt A.↗

Liquid Metals for Aerospace Electric-Power Systems

Liquid metals and their properties, as applied to space electric-power systems, are discussed as possible heat-transfer and thermodynamic working fluids. Representative liquid metals—lithium, sodium, potassium, NaK-78, lead, and bismuth — tare discussed and compared. Space power requirements are listed and used as a basis for evaluating the potentialities of the liquid metals.

Heat transfer↗

Composites of immiscible metals

Process aids development of composites of metals that are immiscible in liquid plase. Aligned uniformly dispersed spheres or rods of bismuth in aluminum, lead in aluminum, bismuth in zinc, and other systems have been prepared. Dispersed and matrix metal are selected according to desired electrical or mechanical properties.

Johnston, M. H.↗

Rubber and alumina gaskets retain vacuum seal in high temperature EMF cell

Silicone rubber gasket and an alumina gasket retain a vacuum inside a high temperature EMF cell in which higher and lower density liquid metal electrodes are separated by an intermediate density fused salt electrolyte. This innovation is in use on a sodium bismuth regenerable EMF cell in which the fused salts and metals are at about 500 deg to 600 deg C.

Hesson, J. C.↗

Small particle melting of pure metals

Submicron-sized crystallites of lead, tin, indium and bismuth were melted in situ in the modified specimen chamber of a Siemens transmission e lectron microscope. Melting point and size determinations were made directly from the dark field images of the crystallites. Particles exhibited melting points that decreased with decreasing particle size. A near-linear relationship was observed for the melting point as a function of the reciprocal of the radius. Thermodynamnic expressions based on the significant contributions of the surface energy to the free energy of the system also suggest a linear relation. Other factors, such as shape and surface contamination, were also observed to affect the size-dependent melting of particles. Crystallites of extended platelet shape did not exhibit a significant depression in melting point. Elevated residual gas pressures were found to lessen the melting point depression of spherical particles.

Allen, G. L.↗

Interaction of Au, Ag, and Bi ions with Ba2YCu3O(7-y) - Implications for superconductor applications

Results are presented on the reactions of Au, Ag, and Bi ions with Ba2YCu3O(7-y) oxides and on the properties of the resultant materials. The results indicate that Au(3+) structural chemistry makes gold an excellent candidate for multiphase structures of the Ba2Y(Cu/1-x/Au/x/)3O(7-y)-type substituted superconductors. Silver is structurally and chemically compatible with the perovskite structure, but when it forms a second phase, it does so without the destruction of the superconducting phase, making silver a useful metal for metal/ceramic applications. On the other hand, bismuth was shown to degrade Tc phase or to form other phases, indicating that it may not be useful in applications with rare-earth-based superconductors.

Hepp, A. F.↗

Composite superconducting wires obtained by high-rate tinning in molten Bi-Pb-Sr-Ca-Cu-O system

Long lengths of metal superconductor composites were prepared by passing a copper wire through the bismuth based molten oxide system at a constant speed. The key to successful composite preparation is the high pulling speed involved, which permits minimization of the severe interaction between the unbuffered metal surface and the oxide melt. Depending on the temperature of the melt and the pulling speed, a coating with different thickness and microstructure appeared. The nonannealed thick coatings contained a Bi2(Sr,Ca)2Cu1O6 phase as a major component. After relatively short time annealing at 800 C, both resistivity and initial magnetization versus temperature measurements show superconducting transitions beginning in the 110 to 115 K region. The effects of annealing and composition on obtained results are discussed. This method of manufacture led to the fabrication of wire with a copper core in a dense covering with uniform thickness of about h approximately equal to 5 to 50 microns. Composite wires with h approximately equal to 10 microns (h/d approximately equal to 0.1) sustained bending on a 15 mm radius frame without cracking during flexing.

Grosav, A. D.↗

Electromagnetic Pumps for Conductive-Propellant Feed Systems

There has been a recent, renewed interest in high-power electric thrusters for application in nuclear-electric propulsion systems. Two of the most promising thrusters utilize liquid metal propellants: the lithium-fed magnetoplasmadynamic thruster and the bismuth-fed Hall thruster. An important element of part of the maturation of these thrusters will be the development of compact, reliable conductive-propellant feed system components. In the present paper we provide design considerations and experimental calibration data for electromagnetic (EM) pumps. The role of an electromagnetic pump in a liquid metal feed system is to establish a pressure gradient between the propellant reservoir and the thruster - to establish the requisite mass flow rate. While EM pumps have previously been used to a limited extent in nuclear reactor cooling loops, they have never been implemented in electric propulsion (EP) systems. The potential benefit of using EM pumps for EP are reliability (no moving parts) and the ability to precisely meter the propellant flow rate. We have constructed and tested EM pumps that use gallium, lithium, and bismuth propellants. Design details, test results (pressure developed versus current), and material compatibility issues are reported. It is concluded that EM pumps are a viable technology for application in both laboratory and flight EP conductive-propellant feed systems.

Markusic, T. E.↗

2-.mu.m fiber amplified spontaneous emission (ASE) source

A 2-.mu.m fiber Amplified Spontaneous Emission (ASE) source provides a wide emission bandwidth and improved spectral stability/purity for a given output power. The fiber ASE source is formed from a heavy metal oxide multicomponent glass selected from germanate, tellurite and bismuth oxides and doped with high concentrations, 0.5-15 wt. %, thulium oxides (Tm.sub.2O.sub.3) or 0.1-5 wt% holmium oxides (Ho.sub.2O.sub.3) or mixtures thereof. The high concentration of thulium dopants provide highly efficient pump absorption and high quantum efficiency. Co-doping of Tm and Ho can broaden the ASE spectrum.

Jiang, Shibin↗