Materials Data on BiWO2 by Materials Project
WBiO2 crystallizes in the tetragonal I4_1/a space group. The structure is three-dimensional. W2+ is bonded in a distorted rectangular see-saw-like geometry to four equivalent O2- atoms. There are two shorter (2.19 Å) and two longer (2.22 Å) W–O bond lengths. Bi2+ is bonded to six equivalent O2- atoms to form edge-sharing BiO6 octahedra. There are a spread of Bi–O bond distances ranging from 2.43–2.68 Å. O2- is bonded in a 5-coordinate geometry to two equivalent W2+ and three equivalent Bi2+ atoms.
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