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(Bi)4(N2)3(Br)18 crystallizes in the hexagonal P6_3/mmc space group. The structure is zero-dimensional and consists of six ammonia molecules, four bismuth molecules, and eighteen hydrobromic acid molecules.
(Bi)4(N2)3(Br)18 crystallizes in the monoclinic C2/m space group. The structure is zero-dimensional and consists of six ammonia molecules; four bismuth, elemental molecules; and eighteen hydrobromic acid molecules.