Results for “Bi-Ge-O-Zn”

Materials Data on Zn3Ge3(BiO6)2 by Materials Project

Zn3Ge3(BiO6)2 crystallizes in the cubic Ia-3d space group. The structure is three-dimensional. Zn2+ is bonded in a distorted body-centered cubic geometry to eight equivalent O2- atoms. There are four shorter (2.40 Å) and four longer (2.49 Å) Zn–O bond lengths. Ge4+ is bonded to four equivalent O2- atoms to form GeO4 tetrahedra that share corners with four equivalent BiO6 octahedra. The corner-sharing octahedral tilt angles are 59°. All Ge–O bond lengths are 1.79 Å. Bi3+ is bonded to six equivalent O2- atoms to form BiO6 octahedra that share corners with six equivalent GeO4 tetrahedra. All Bi–O bond lengths are 2.32 Å. O2- is bonded in a 4-coordinate geometry to two equivalent Zn2+, one Ge4+, and one Bi3+ atom.