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Materials Data on BeCl2 by Materials Project

BeCl2 is Silicon Disuphide structured and crystallizes in the orthorhombic Ibam space group. The structure is one-dimensional and consists of two BeCl2 ribbons oriented in the (1, 0, 0) direction. Be2+ is bonded to four equivalent Cl1- atoms to form edge-sharing BeCl4 tetrahedra. All Be–Cl bond lengths are 2.04 Å. Cl1- is bonded in an L-shaped geometry to two equivalent Be2+ atoms.

36 MATERIALS SCIENCE↗

Materials Data on BeCl2 by Materials Project

BeCl2 crystallizes in the tetragonal I4_1/acd space group. The structure is three-dimensional and consists of two BeCl2 frameworks. Be2+ is bonded to four Cl1- atoms to form corner-sharing BeCl4 tetrahedra. There are a spread of Be–Cl bond distances ranging from 2.03–2.05 Å. There are three inequivalent Cl1- sites. In the first Cl1- site, Cl1- is bonded in a bent 120 degrees geometry to two equivalent Be2+ atoms. In the second Cl1- site, Cl1- is bonded in a water-like geometry to two equivalent Be2+ atoms. In the third Cl1- site, Cl1- is bonded in a water-like geometry to two equivalent Be2+ atoms.

36 MATERIALS SCIENCE↗

Materials Data on BeCl2 by Materials Project

BeCl2 crystallizes in the trigonal P3_221 space group. The structure is three-dimensional. there are two inequivalent Be2+ sites. In the first Be2+ site, Be2+ is bonded to four Cl1- atoms to form corner-sharing BeCl4 tetrahedra. There are two shorter (2.03 Å) and two longer (2.05 Å) Be–Cl bond lengths. In the second Be2+ site, Be2+ is bonded to four Cl1- atoms to form corner-sharing BeCl4 tetrahedra. There are two shorter (2.03 Å) and two longer (2.04 Å) Be–Cl bond lengths. There are three inequivalent Cl1- sites. In the first Cl1- site, Cl1- is bonded in a bent 120 degrees geometry to two Be2+ atoms. In the second Cl1- site, Cl1- is bonded in a water-like geometry to two Be2+ atoms. In the third Cl1- site, Cl1- is bonded in a bent 120 degrees geometry to two equivalent Be2+ atoms.

36 MATERIALS SCIENCE↗

Materials Data on BeCl2 by Materials Project

BeCl2 crystallizes in the cubic I-43m space group. The structure is three-dimensional. Be2+ is bonded to four Cl1- atoms to form corner-sharing BeCl4 tetrahedra. There are one shorter (2.03 Å) and three longer (2.04 Å) Be–Cl bond lengths. There are three inequivalent Cl1- sites. In the first Cl1- site, Cl1- is bonded in a water-like geometry to two equivalent Be2+ atoms. In the second Cl1- site, Cl1- is bonded in a water-like geometry to two equivalent Be2+ atoms. In the third Cl1- site, Cl1- is bonded in a bent 120 degrees geometry to two equivalent Be2+ atoms.

36 MATERIALS SCIENCE↗

Materials Data on BeCl2 by Materials Project

BeCl2 crystallizes in the cubic I-43m space group. The structure is three-dimensional. Be2+ is bonded to four equivalent Cl1- atoms to form corner-sharing BeCl4 tetrahedra. All Be–Cl bond lengths are 2.05 Å. Cl1- is bonded in a bent 120 degrees geometry to two equivalent Be2+ atoms.

36 MATERIALS SCIENCE↗