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BaC2 crystallizes in the tetragonal I4/mmm space group. The structure is three-dimensional. Ba2+ is bonded in a distorted q4 geometry to ten equivalent C1- atoms. There are two shorter (3.00 Å) and eight longer (3.18 Å) Ba–C bond lengths. C1- is bonded in a 6-coordinate geometry to five equivalent Ba2+ and one C1- atom. The C–C bond length is 1.26 Å.
BaC2 crystallizes in the trigonal R-3m space group. The structure is three-dimensional. Ba2+ is bonded in a body-centered cubic geometry to eight equivalent C1- atoms. There are six shorter (3.08 Å) and two longer (3.10 Å) Ba–C bond lengths. C1- is bonded to four equivalent Ba2+ and one C1- atom to form a mixture of distorted corner and edge-sharing CBa4C trigonal bipyramids. The C–C bond length is 1.27 Å.
Ba(SCN)2 crystallizes in the monoclinic C2/c space group. The structure is three-dimensional. Ba2+ is bonded in a 8-coordinate geometry to four equivalent N3- and four equivalent S2- atoms. All Ba–N bond lengths are 2.87 Å. There are two shorter (3.34 Å) and two longer (3.41 Å) Ba–S bond lengths. C4+ is bonded in a distorted linear geometry to one N3- and one S2- atom. The C–N bond length is 1.19 Å. The C–S bond length is 1.63 Å. N3- is bonded in a distorted single-bond geometry to two equivalent Ba2+ and one C4+ atom. S2- is bonded in a 3-coordinate geometry to two equivalent Ba2+ and one C4+ atom.